1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product information Trade name : Company : Sika Österreich GmbH Dorfstrasse 23 6700 Bludenz-Bings Telephone : +4350610 Telefax : +43506101901 Emergency telephone : number : e-mail address of person responsible for this SDS 0043 1 4064343 (Giftinformationszentrale Wien) EHS@at.sika.com 2. HAZARDS IDENTIFICATION Risk advice to man and the environment Flammable. May cause sensitization by skin contact. Irritating to eyes and skin. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. EC-No. / Registration number reaction product: bisphenol-a- (epichlorhydrin) and epoxy resin (number average molecular weight 700-1100) Classification 25068-38-6 Xi; R36/38 R43 xylene 1330-20-7 215-535-7 / 01-2119488216- 32-XXXX R10 Xn; R20/21 Xi; R38 Concentration [%] >= 10 - < 20 < 10 2-methylpropan-1-ol 78-83-1 201-148-0 / 01-2119484609- 23-XXXX ethylbenzene 100-41-4 202-849-4 / 01-2119489370- 35-XXXX For the full text of the R-phrases mentioned in this Section, see Section 16. R10 Xi; R37/38- R41 R67 F; R11 Xn; R20 >= 5 - < 10 < 10 4. FIRST AID MEASURES General advice 000000004871 1 / 7 : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance.
Inhalation Skin contact Eye contact Ingestion : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Special protective equipment for fire-fighters Further information : Alcohol-resistant foam Dry chemical : High volume water jet : Do not use a solid water stream as it may scatter and spread fire. Do not allow run-off from fire fighting to enter drains or water courses. : In the event of fire, wear self-contained breathing apparatus. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up : Use personal protective equipment. Ensure adequate ventilation. : Do not flush into surface water or sanitary sewer system. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 000000004871 2 / 7
SAFETY DATA SHEET 7. HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion : Avoid contact with skin and eyes. For personal protection see section 8. Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. : Avoid formation of aerosol. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers Other data : No smoking. Keep container tightly closed in a dry and well-ventilated place. : No decomposition if stored and applied as directed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value Control parameters * xylene 1330-20-7 TWA 50 ppm 221 mg/m3 STEL 100 ppm TMW 50 ppm 221 mg/m3 100 ppm TMW 50 ppm 221 mg/m3 100 ppm 2-methylpropan-1-ol 78-83-1 TMW 50 ppm 150 mg/m3 200 ppm 600 mg/m3 ethylbenzene 100-41-4 TWA 100 ppm STEL 200 ppm 884 mg/m3 000000004871 3 / 7 Basis *
SAFETY DATA SHEET TMW 100 ppm 440 mg/m3 200 ppm 880 mg/m3 *Values in the table refer to the latest EU-OEL and to the (Grenzwerteverordnung GKV ). Personal protective equipment Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. organic vapor filter (Type A) A1: < 1000 ppm; A2: < 5000 ppm; A3: < 10000 ppm Hand protection Eye protection Skin and body protection Hygiene measures : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Reference number: EN 374. Suitable for short time use or protection against splashes: Butyl rubber/nitrile rubber gloves (0,4 mm), Contaminated gloves should be removed. Suitable for permanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min. : Eye wash bottle with pure water Tightly fitting safety goggles : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour : liquid : various : aromatic Safety data Flash point : 23 C 000000004871 4 / 7
Ignition temperature : 415 C Density Water solubility : ca.1,76 g/cm3 at 20 C : insoluble 10. STABILITY AND REACTIVITY Conditions to avoid Thermal decomposition Hazardous reactions : Heat, flames and sparks. : no data available : No decomposition if used as directed. : Vapours may form explosive mixture with air. 11. TOXICOLOGICAL INFORMATION Acute dermal toxicity xylene : Acute toxicity estimate: 1.100 mg/kg Method: Converted acute toxicity point estimate Skin irritation : May cause skin irritation in susceptible persons. Eye irritation : Vapours may cause irritation to the eyes, respiratory system and the skin. Sensitisation : Causes sensitization. Further information : Solvents may degrease the skin. 12. ECOLOGICAL INFORMATION Further information on ecology Additional ecological information : There is no data available for this product. 13. DISPOSAL CONSIDERATIONS Disposal considerations 000000004871 5 / 7 : The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Austria - Waste catalogue : 55510 European Waste Catalogue Contaminated packaging : 08 01 11* waste paint and varnish containing organic solvents or other dangerous substances : Completely emptied packagings can be given for recycling. Packaging containing remains of dangerous substances, as well as packagings disposed of remains can be unharmed eliminated in accordance with the regulations. : 15 01 10* packaging containing residues of or contaminated by dangerous substances 14. TRANSPORT INFORMATION ADR UN number : 1263 Description of the goods : PAINT Class : 3 Packing group : III Classification Code : F1 Labels : 3 : Exempted according to 2.2.3.1.5 (Viscous substance exemption) IATA UN number : 1263 Description of the goods : Paint Class : 3 Packing group : III Labels : 3 IMDG UN number : 1263 Description of the goods : PAINT Class : 3 Packing group : III Labels : 3 EmS Number 1 : F-E EmS Number 2 : S-E Marine pollutant : no 15. REGULATORY INFORMATION Labelling according to EC Directives1999/45/EC Symbol(s) : Xi Irritant 000000004871 6 / 7
R-phrase(s) : R10 Flammable. R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. S-phrase(s) : S24 Avoid contact with skin. S37 Wear suitable gloves. Hazardous components which must be listed on the label: reaction product: bisphenol-a-(epichlorhydrin) and epoxy resin (number average molecular weight 700-1100) National legislation Risk classification according to VbF Water contaminating class (Germany) : Not regulated VBF AT, for paragraph 3, 3. : WGK 2 water endangering Gemäß VwVws vom 30.Juli 2005 VOC content : 20,03 % 16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R36/38 Irritating to eyes and skin. R37/38 Irritating to respiratory system and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R43 May cause sensitization by skin contact. R67 Vapours may cause drowsiness and dizziness. The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any us Änderungen gegenüber der letzten Ausgabe!!! 000000004871 7 / 7