Manual Ultra Pure Water System Ultra Clear Basic Rev.: 060905 Subject to alternations Catalog No.: 2 0 0 1 - B Serial No.: Fahrenberg 8 * 22885 Barsbüttel Germany Tel.: +49(0)40/670868-6 * Fax: +49(0)40/670868-44 www.sgwater.de * e-mail: info@sgwater.de
Table of Contents 1 General... 1 1.1 Used Symbols... 1 1.2 Safety Information... 2 2 System Features... 3 2.1 Water Purification Process... 4 3 Installation and Start Up... 5 3.1 Delivered parts... 5 3.2 Feed Water Requirements... 6 3.3 Pretreatment methods for the feed water... 6 3.4 Closing Plugs... 7 3.5 Connections... 7 3.6 Sterile Filter Attachment... 8 3.7 Disinfectant Filling... 9 3.8 Disinfectant Washout... 9 3.9 Start Up... 10 4 System Control... 11 4.1 Display and function keys... 11 4.2 Start Selection Screen Normal Operation... 11 4.3 Start Selection Screen Flushing... 12 4.4 Start Selection Screen Main Menu... 12 4.5 Main Menu Settings Interval Mode... 16 4.6 Main Menu Maintenance... 18 4.7 Main Menu Maintenance Disinfection Procedure... 19 5 Troubles and Corrections... 22 6 Maintenance and Servicing... 22 6.1 Interval... 22 6.2 Replacement of the modules... 23 6.3 Disinfection and Replacement of the Sterile Filter... 24 6.4 Adjustment of the contrast... 25 6.5 Disinfection of the System... 26 7 Technical Data... 27 7.1 Feed Water Requirements... 27 7.2 System Data... 27 8 Appendix... I 8.1 Flow Sheet... I 8.2 Circuit Diagram... II 8.3 Consumables and spare parts... III 8.4 Disinfectant Safety Data Sheet...IV Content
1 General 1.1 Used Symbols!! This symbol signals a direct danger. If not observed injury may occur! In case of this symbol do not continue with operation until you have completely understood the conditions of its occurrence and have acted according to the instructions. This symbol signals a damaging situation. If not observed system damage may occur! In case of this symbol do not continue with operation until you have completely understood the conditions of its occurrence and have acted according to the instructions.! i This symbol signals a reduction in performance of the system. Follow the directions of these operating instructions and where appropriate the texts on the screen of the system for the removal of the interference. If required inform the customer service department of the supplier! This symbol points to important information. General Page 1 of 27
1.2 Safety Information The water purification system corresponds to the latest developments in technology and safety rules. The manufacturer has taken all steps for granting a safe operation. It is the users responsibility to take care, that the system is installed in such a way, that its safe use won t be affected. The system is factory approved and is fulfilling our safety conditions. This manual contains information and warnings, which have to be observed by the user in order to grant a safe operation of the system.! The following safety precautions must be followed before starting up and during operation of the system. The system must only to be operated by introduced staff. All users working with the system first have to read this manual. The user is only permitted to effect maintenance works as described in the manual. For maintenance works please use only indicated parts Service work must only be undertaken by authorized staff approve by the manufacturer Spare fuses must have the values given by the manufacturer of the system. A shorting or manipulation at fuses and/or the wires cancels any guarantee The system must only by connected to a fused and earthed power supply If any evidence of leaks in the system occurs the unit must be isolated immediately from the electrical supply and the fault rectified. If required inform the customer services department of the supplier! For user s safety and to maintain the performance of the system the maintenance and inspections recommended by the manufacturer have to be carried out in the correc t intervals. The manufacturer doesn t take any responsibility either for injuries of third persons caused by improper use of the system. General Page 2 of 27
2 System Features This system is dedicated for the production of analytical grade water out of deionized feed water or Permeate. All components correspond to the latest technology. In a purification circulation ultra pure water with permanent highest quality is produced, supplied with the dispenser at the front side of the unit. The product water can be drawn in a rate of 1.2 liters per minute. Typical characteristics are: Conductivity 0.055 µs/cm (resistivity 18.2 MΩ-cm), TOC value (total Organic carbon) below 20 ppb, bacteria less than 1 KbE/ml and less as 1 particle per ml bigger than 0.2 µm. Water quality and temperature are indicated on the system monitor. All components of the system are assembled in a designed plastic housing, which can be used either as bench device or wall mounted. The front door can easily be opened for the access of the modules. The system corresponds to recent safety regulations and can be installed and put into operation without the help of customer service. Dispenser System Control Sterile Filter MF-III-D module VMD module System Features Page 3 of 27
2.1 Water Purification Process The process flow with all components is illustrated on the flow sheet, see the appendix. System parameters and maintenance tasks can be adjusted in the system control. When the system is started in Normal Operation, the circulation pump (P3.1) starts to feed the water into the system. The pump will be stopped, if the system is switched off. The VMD module (F4.1) is filled with mixed-bed resin. This module reduces the salt content of the feed water to protect the high grade MF-III-D module. The MF-III-D module (F4.2) is filled with high grade activated carbon and mixed bed resins in semiconductor quality. The activated carbon removes last organic materials and last particles out of the water. The resin extracts the remaining salt content of the water for Ultra Pure Water quality. If the flushing program has been selected in the start menu, the flushing valve (V4.6) opens to wash out the modules after installation or replacement. Product water quality is controlled with a sensor (QIA Q1). The value is indicated as quality Q1 in the unit µs/cm or MΩ-cm. If the adjusted limit is exceeded, the warning message values exceed will be displayed. The sterile filter (F4.3) removes still remaining bacteria over a size of 0.2 microns and protects the system against germs formation. The product water is supplied with the dispenser (V4.3). If no product water is consumed, it circulates in a cleaning process. Thus the product water will be supplied in permanent best quality. For an economic use the system can be operated in interval mode. In this mode 2 separate intervals can be used. System Features Page 4 of 27
3 Installation and Start Up 3.1 Delivered parts 1 x Ultra Clear Basic (Art. No.: 2004-B) 0.2µm Sterile filter (Art. No.: 2064) Option: 0.1µm sterile filter (Art. No.: 2065) 1 x Elbow connections ¼ (Art. No.: 04861-2) 1 x Elbow connections 5 / 16 (Art. No.: 04983-2) 1 x VMD module (Art. No.: 2050) 1x MF-III-D module (Art. No.: 2051) 1 x Feed water tube 5 / 16 blue (Art. No.: 08635-1) with ¾ union nut 1 x Power cable (Art. No. D: 70033, CH: 80703, UK: 80704, USA: 80705) 1 x Tap adapter ¾ ½ (Art. No.: 06843) 1x Flushing tube ¼ (Art. No.: 02577-2) Disinfection tube (Art. No.: 20007) Added tools: Inlet Pressure Regulator (Art.No. 2066), Screwdriver, wall dowels and screws, spare fuses Installation and Start Up Page 5 of 27
3.2 Feed Water Requirements The feed water has to be pre-treated and has to fulfil the following specifications: In the feed pressures is over 2 bar, the enclosed pressure reducer has to be attached on the feed water inlet. Inlet pressure bar 0.01 2 Conductivity µs/cm < 10 Resistivity MΩ-cm > 0.1 TOC ppb < 50 Silica ppm < 2 CO2 ppm < 30 Temperature C 5 35 3.3 Pretreatment methods for the feed water Pre-treatment with one or two deionizers Deionizer Conductivity meter Deionizer Ultra Clear Basic Pre-treatment with Reverse-Osmosis system euro system Storage tank Ultra Clear Basic Pre-treatment with Reverse-Osmosis system and the deionizer in series euro system Storage tank Conductivity meter Deionizer Ultra Clear Basic Installation and Start Up Page 6 of 27
3.4 Closing Plugs To loosen the closing plugs the fastening ring must be pressed in slightly Fastening ring Closing plug 3.5 Connections Remove closing plugs after pressing in the fastening ring Caution: Disinfectant might flow out! Attention! Plug in the tubes until stop position Connect the power cable to the mains Flushing tube must be led with a downward gradient toward the waste water disposal. Any reduction of the diameter, loops, siphons or breaks in the line are to be avoided. Between the line end and the entrance into the waste water disposal a minimum safety distance of at least 2 cm must be provided (distance more than the double of tube inside diameter). Flushing out Feed water in Power Supply in back side In the feed pressures is over 2 bar, the enclosed pressure reducer has to be attached on the feed water inlet. Installation and Start Up Page 7 of 27
3.6 Sterile Filter Attachment Dispenser Small ring to the dispenser Detacher Sterile filter Large ring to the filter Locate detacher large ring Put the detacher large ring on the sterile filter tube Insert the sterile filter with the detacher into the dispenser Installation and Start Up Page 8 of 27
3.7 Disinfectant Filling Attention! The system is delivered with a disinfectant solution filling! The disinfection tube is attached on the position of the MF-III-D module. Before normal operation the disinfectant must be rinsed out! Safety precautions in handling with the disinfection solution have to be observed. For the safety data sheet see the appendix! 3.8 Disinfectant Washout Disinfection Tube Coupler Disinfectant inlet Flushing Tube Coupler Opened Front Door Plug the coupler into the Flushing Tube and the Disinfectant Tube connectors Attention: A click for the snap in must be heard! Open water supply, start the system with the ON function key Move to the disinfection program (see paragraph disinfection: Main menu maintenance disinfection) Execute the disinfection program step-by-step as described without a new disinfectant, until the program is finished and the disinfectant is rinsed out Return to this instruction item again Stop the system with the OFF function key Open the dispenser for a moment over the drain to reduce the pressure Unplug the Flushing Tube and the Disinfectant Tube Installation and Start Up Page 9 of 27
3.9 Start Up Coupler VMD module MF-III-D module Coupler After the disinfectant washout the treatment modules can be connected Plug the couplers into the VMD and MF-III-D module, until the snap in can be heard Start the system with the ON function key Select the menu item Flush for a short flushing of the modules After the flushing the system automatically turns into normal operation Deaerate the system with sterile filter and Dispenser: Open sterile filter deaeration screw and Dispenser, until pure water flows out (The deaeration might be repeated form some times) Check for impermeability on all connections Close the front door System is ready for use Note! After installation, after module replacement, and after a weekend the flushing program within the start selection screen should be selected for a short flushing. If the conductivity does not reach Ultra Pure Water quality after installation or module replacement, the resin in the modules has to swell for some time to achieve the full capacity. Installation and Start Up Page 10 of 27
4 System Control 4.1 Display and function keys Display of device type, Serial Number and control version Function keys ON : System Start and Start Selection Screen : Menu selection and number input ENTER: Confirmation : Menu selection and number input Menu : Superior menu item OFF : Switch OFF key (Attention: the system is still power connected) 4.2 Start Selection Screen Normal Operation ON Start Selection Screen Operation Confirmation starts the Normal Operation display Normal Operation Display Q 1: Product water quality/ resistivity in unit MΩ-cm Temp: Water temperature Note: Parameter for each row and water quality unit can be chosen in the main menu settings System Control Page 11 of 27
4.3 Start Selection Screen Flushing ON Start selection screen Flush Confirmation starts the flushing program to wash out contaminations. This program should be used after installation, after replacement of cartridges or after a system stop for several days. Flushing Display Display of the remaining flushing time. 4.4 Start Selection Screen Main Menu ON Start selection screen Main Menu Confirmation starts the main menu Main Menu Settings: System configuration and interval mode settings Maintenance: Disinfection, Ultra-Filtration flushing, operation counter Service: Technical service configuration Main Menu Settings Parameter settings for the system, display, and interval-mode Main Menu Settings Language German English System Control Page 12 of 27
Main Menu Settings Date Input of the date: month / day / year (MM/DD/YY) Main Menu Settings Time Input of the time: hours : minutes (hh:mm) Main Menu Settings µs/cm MΩ-cm Display Selection of the water quality unit (conductivity / resistivity) conductivity unit: µs/cm resistivity unit: MΩ-cm Main Menu Settings Temperature compensation Compensation of temperature variations and display of the compensated temperature for 25 C automatic compensation compensation off Main Menu Settings Quality Q1 Conductivity limit for an alarm message on the screen Main Menu Settings Quality Q1 Critical Value Input of the conductivity limit. The measuring range depends on the settings. If this limit is exceeded, the alarm Values exceeded will be displayed. Alarm message Display of a warning with error indication. Example: Error 1; Permeate quality Q1; values exceeded System Control Page 13 of 27
Main Menu Settings Temperature Limit of the temperature with alarm message Limit of the temperature with product water drainage (flushing valve will be opened and product water will be drained) Main Menu Settings Temperature Alarm Input of the temperature limit for an alarm message. If this limit is exceeded, the alarm Values exceed will be displayed. Alarm message Display of a warning with error indication. Example: Error 6; temperature; values exceeded Main Menu Settings Temperature Drainage Input of the temperature limit for the drainage. If this limit is exceeded, the flushing valve will be opened and product water will be drained, until the temperature is in the limit again. After reaching normal temperature, the valve will be closed delayed. Alarm message Display of a warning with error indication. Example: Error 5; temperature; water to drain Main Menu Settings Main display Parameter selection for each row displayed in normal operation Main Menu Settings Main display Row 1 3 Parameter selection for row 1 Q1: Water quality Q3 Product water Temp: Temperature Inactive System Control Page 14 of 27
Main Menu Settings Data Port Selection of the data output signal Signal for PC connection Signal for printer connection Main Menu Settings Data Port Printer Period of the data output for the printer Main Menu Settings Data Port Printer Interval Input of the period in minutes Main Menu Settings 24hrs. Operation (Interval-mode) The circulation pump and UV-oxidizer can be run in interval mode with: 2 separate interval periods Each period with permanent day operation only Each period with different day and night operation Day and night operation with pauses, while the pump/uv is stopped System Control Page 15 of 27
4.5 Main Menu Settings Interval Mode Main Menu Settings 24hrs. Operation (Interval-mode) Interval settings for 2 different interval periods Example: 1 st Interval: Working week Only day operation from Monday to Friday, every day from 08:00 17:00 o clock, stopped pump/uv during the nights 2 nd Interval: Weekend: Saturday and Sunday without pump/uv operation Main Menu Settings 24hrs. Operation Week day 1 Display of the days from Sunday to Saturday. Selection of the days with number 1 Example: 1 st Interval, Working Week Input Monday until Friday Main Menu Settings 24hrs. Operation Start Time 1 Selection of the start moment for day-time operation Example: 1 st Interval, Working Week Input 08:00 o clock Main Menu Settings 24hrs. Operation Finish Time 1 Selection of the end for day-time operation Example: 1 st Interval, Working Week Input 17:00 o clock Main Menu Settings 24hrs. Operation Interval 1 Interval mode Operation (days and nights), pump/uv is running Pauses (days and nights), pump/uv is stopped Main Menu Settings 24hrs. Operation Interval 1 Mode Selection of the interval mode: Permanent is operation during the day-time only Interval is operation with different day and night settings Example: 1 st Interval, Working Week Input permanent operation System Control Page 16 of 27
Main Menu Settings 24hrs. Operation Interval 1 Day Operation Input of the operation time during days, valid in case of Interval-Operation mode, pump/uv is switched on. Example: 1 st Interval, Working Week Without function in case of Permanent-Operation Main Menu Settings 24hrs. Operation Interval 1 Day Pauses Input of pauses during days, valid in case of Interval-Operation mode, pump/uv is switched off. Example: 1 st Interval, Working Week Without function in case of Permanent-Operation Main Menu Settings 24hrs. Operation Interval 1 Night Operation Input of the operation time during nights, valid in case of Interval-Operation mode, pump/uv is switched on. Example: 1 st Interval, Working Week Without function in case of Permanent-Operation Main Menu Settings 24hrs. Operation Interval 1 Night Pauses Input of pauses during nights, valid in case of Interval-Operation mode, pump/uv is switched off. Example: 1 st Interval, Working Week Without function in case of Permanent-Operation Main Menu Settings 24hrs. Operation Week Day 2 Display of the days from Sunday to Saturday. Selection of the days with number 1 Example: 1 st Interval, Working Week Input Sunday and Saturday Main Menu Settings 24hrs. Operation Start Time 2 Selection of start moment for day-time operation Example: 2 nd Interval, Weekend Input 00:00 o clock Main Menu Settings 24hrs. Operation Finish Time 1 Selection of the end for day-time operation Example: 2 nd Interval, Weekend Selection of 00:00 o clock System Control Page 17 of 27
Main Menu Settings 24hrs. Operation Interval 1 Selection of the interval mode: Permanent is operation during the day-time only Interval is operation with different day and night settings Example: 2 nd Interval, Weekend Selection of Permanent Operation, day-time operation is set to ZERO, pump/uv will be stopped during the weekend 4.6 Main Menu Maintenance Main Menu Maintenance Confirmation starts the maintenance menu Main Menu Maintenance Selection Disinfection: System disinfection with SG disinfectant syringes Op. hour: Display and reset of Operation hours Main Menu Maintenance Disinfection Confirmation starts a step-by-step procedure for a user-friendly disinfection Note: The disinfection procedure can be stopped with the MENU function key Alarm message Display of a warning with error indication. Example: Error 13; Maintenance by customer service System Control Page 18 of 27
4.7 Main Menu Maintenance Disinfection Procedure Main Menu Maintenance Disinfection Confirmation starts a step-by-step procedure for the system disinfection. Auxiliary components: 2 litre cup Disinfection tube SG disinfection syringes with special disinfectant solution Attention: Safety precaution advises of the disinfectant safety data sheet have to be observed! The disinfection procedure can be stopped with the MENU function key. Main Menu Maintenance Disinfection Start Confirmation starts the disinfection procedure. 1. Open Dispenser Place the cup under the dispenser Open the dispenser in permanent position 2. Remove the both cartridges (MF-III-D and VMD Module) The disinfection tube has to be connected with the couplers of the MF-III-D module, the Flushing tube has to be connected with the couplers of the VMD module Remove the couplers from the modules, plug the couplers into disinfection tube sockets and flushing tube socket (Attention: the couplers have to snap in) MF-III-D VMD Red coupler Red coupler socket Injection opening with protective cap socket System Control Page 19 of 27
3. Connect the disinfection syringe Remove the protection cap of disinfection syringe and disinfection tube, screw the disinfection syringe on the injection opening 4. Inject the disinfectant solution 5. - Finishing Injection Remove the syringe Close injection opening with protection cap Close the dispenser 6. Confirm the disinfection start 7. Circulation time and reaction time are displayed 8. Finished disinfection is displayed 9. Disinfectant flushing Confirm the clear water flushing with ENTER Close the dispenser after approx. 1 minute System Control Page 20 of 27
10. Remaining flushing time is displayed During the flushing process the disinfectant will be rinsed of the system automatically with clear water. 11. Finish the flushing process The disinfection menu will be finished automatically and moves to the prior menu item Confirm with ENTER If not automatically move to the Normal Operation menu Open the dispenser for approx. 1 minute Close the dispenser 12. End of Disinfection Procedure Stop the system with the OFF function key For pressure reduction open the dispenser a short moment Pull off the couplers from the disinfection tube and remove it Plug the couplers in the MF-III-D cartridge and hang in the module (Attention: the couplers have to snap in) Start the system with the ON function key Move to the flushing program within the start selection screen Confirm the flushing After the flushing the system automatically turns into normal operation Check for impermeability System is ready for use System Control Page 21 of 27
5 Troubles and Corrections Trouble Reason Correction Temperature too high Feed water temperature Ambient temperature System temperature Conductivity Q1 too high Feed water quality VMD module exhausted MF-III-D Module exhausted Cooling Cooling Interval-Mode Check of pre-treatment Replacement of VMD Module Replacement of MF-III-D Module 6 Maintenance and Servicing 6.1 Interval Material Time of Operation Warning Message Counter Reset VMD module replacement All 6-12 months recommended, depending on feed water quality Q1 Value exceeded NO MF-III-D module replacement All 6-12 months recommended Q1 Value exceeded NO Sterile Filter autoclaving max. 6 times none NO Sterile Filter disinfection max. 12 times none NO Sterile Filter replacement All 6 months recommended none NO System disinfection All 3 months recommended, depending on analytical requirements none NO Troubles and Corrections Page 22 of 27
6.2 Replacement of the modules Coupler VMD module MF-III-D module Coupler Attached MF-III-D module Stop the system with the OFF function key Depressurize the system by opening dispenser for a moment and open the front door Pull off the couplers from the module Insert the new cartridge and plug in the quick couplers, until a click for the snap in can be heard Start the system with the ON function key Deaerate the system with the sterile filter ventilation until pure water flows out Deaerate the system with the dispenser until pure water flows out Check for impermeability on all connections Close the front door System is ready for use Note! After installation, after module replacement, and after a weekend the flushing program within the start selection screen should be selected for a short flushing. If the conductivity does not reach Ultra Pure Water quality after installation or module replacement, the resin in the modules has to swell for some time to achieve the full capacity. Maintenance and Servicing Page 23 of 27
6.3 Disinfection and Replacement of the Sterile Filter The replacement of the sterile filter is recommended all 6 months as a minimum! The sterile filter (F4.3) protects the system against germination, as bacteria and germs over a size of 0.2 microns are filtered out of the water. Depending on feed water quality, ambient conditions and utilization germs are accumulated in the sterile filter and will contaminate the system. For disinfection the sterile filter can be autoclaved up to 6 times for 30 minutes at 121 C. After 6 times of autoclaving the sterile filter needs to be exchanged. The sterile filter can also be disinfected with the disinfection program of the system control. Another method is a separate flushing inside a disinfectant solution. Dispenser Small ring to the dispenser Detacher Sterile filter Large ring to the filter Stop the system with the OFF function key For removing the sterile filter the detacher ring must be pressed in slightly Disinfect or exchange the sterile filter Attach the sterile filter again Start the system with the ON function key Open the dispenser some time to wash out impurities after installation Deaerate the system with sterile filter and Dispenser: Open sterile filter deaeration screw and Dispenser, until pure water flows out (The deaeration might be repeated form some times) Check for impermeability on all connections System is ready for use Maintenance and Servicing Page 24 of 27
6.4 Adjustment of the contrast Attention! Conductions do not damage! Contrast screw The contrast of the display has to be adjusted during normal operation of the system Take care on the circuits Open the front door Remove the cap of the system control box, which is mounted back side of the front door Turn the regulation screw by a small screwdriver to adjust the contrast Attach the cap again Close the front side again System is ready for use Maintenance and Servicing Page 25 of 27
6.5 Disinfection of the System The disinfection of the system should be realized with SG disinfection syringes (Art.No. 2055). With these syringes a user-friendly disinfection is possible: 1) The syringes are filled with a suitable concentration of the disinfectant OXIDES L 2) Potential injuries or damages using the disinfectant are prevented 3) The disinfection procedure is easy with the programming-controlled step-by-step instruction For the disinfection a special disinfection tube (Art.No. 20007) has to be installed instead of the left cartridge module (MF-III-D module). Then one syringe has to be fixed to the tube and the disinfectant only has to be injected. Finally the disinfectant has to be rinsed out. The disinfection procedure will be done by the step-by-step instruction: See chapter Main Menu Maintenance Disinfection Maintenance and Servicing Page 26 of 27
7 Technical Data 7.1 Feed Water Requirements In the feed pressures is over 2 bar, the enclosed pressure reducer has to be attached on the feed water inlet. Inlet pressure bar 0.01 2 Conductivity µs/cm < 10 Resistivity MΩ-cm > 0.1 TOC ppb < 50 Silica ppm < 2 CO2 ppm < 30 Temperature C 5 35 7.2 System Data Product Water Performance LPM 1.2 Conductivity at 25 C µs/cm 0,055 Resistivity at 25 C MΩ cm 18,2 TOC concentration ppb < 20 Bacteria cfu/ ml < 1 Particles > 0.2 µm per ml < 1 Temperature C +5 +35 Feed water union nut R ¾ Tap adapter R ½ Flushing tube connector R ¼ Power supply V / Hz 230 / 50 Height x Width x Depth mm 535 x 340 x 320 Weight kg 25 Technical Data Page 27 of 27
8.3 Consumables and spare parts Label Description Article No. none Pressure reducer for feed pressure over 2 bar 2066 P4.1 Circulation pump 08367 TA4.1 Temperature sensor 06381 F4.1 VMD module 2050 F4.2 MF-III-D module 2051 none Plug-in connectors (for the modules) 06988 none Elbow connector for VMD-, MF III D-modules output 08678-1 V4.6 Flushing valve 00055 QIA Q1 Quality Control Q1 07524 V4.3 Dispenser with reed contact 00189 F4.3 Sterile filter 0.2 µm 2064 OPTION Sterile filter 0.1 µm 2065 none Plug in connection for sterile filter 00378-1 none Connector between tube and plug-in connection for sterile filter 00792-3 none O-ring for sterile filter 00895 V4.2 Check valve 06712 E1 System control 05697-00 none Switching Power supply 100-240 08258-2 none Switching Power supply PS-25-12 06281 Please give us always the serial number of your system when ordering consumables and spare parts. Appendix III
EU Safety Data Sheet Trade Name: Oxydes L Created: December 5, 2003 Modified: June 19, 2006 Page: 1 of 3 1. Material / Preparation Designation and Company Name Product Specifications Trade Name: Supplier Information Address: Oxydes L Fahrenberg 8 D- 22885 Barsbüttel, Germany Tel.: +49 (0)40 / 670868-6 Fax.: +49 (0)40 / 670868-44 Emergency Contact: State Advisory Board for Poisonous Symptoms and Embryonic toxicology Senate Health Administration (Landesberatungsstelle für Vergiftungserscheinungen und Embryonaltoxikologie Senatsverwaltung für Gesundheit) Spandauer Damm 130, D-14050 Berlin, Germany Tel: +49 (0)30 192 40 Fax: +49 (0)30 368 6799) 2. Composition / Component Information Ingredients Concentration CAS-No. Symbol R-Sätze Substance < 0.5 % 7647-14-5 -- -- Sodium hypochlorite in an aqueous solution, chlorine active < 0.5 % 7722-84-1 -- -- Hydrogen peroxide < 0.5 % 1310-73-2 -- -- Ozone 3. Possible Hazards Hazardous Symbols None R-Sätze: 31 Poisonous gases created upon contact with acids There is no danger to persons or the environment when used and handled correctly. Open flame is strictly forbidden in the vicinity of the liquid container. 4. First-Aid Measures General instructions: After inhalation: After skin contact: After eye contact: After swallowing: Remove contaminated clothing. Remain calm. Ensure fresh air available. Remain calm. Get to fresh air. If symptoms persist, consult a medical professional. Immediately flush the effected area thoroughly with water. If any effects remain, consult a medical professional. Keeping the eye lids open and separated, immediately flush the eye(s) thoroughly with running water. Protect the unaffected eye. Remove contact lenses. Consult a medical eye specialist. Immediately flush the mouth thoroughly with water. When the mouth is free of contaminants, drink as much water as possible. Consult a medical professional. 5. Fire-Fighting Measures Appropriate extinguishing Isolate endangered areas downwind. Warn inhabitants. The material itself is non-flammable. Fight agents the surrounding fire with an appropriate extinguishing agent. Special protective equipment for fighting the fire Helpers should protect themselves. Ensure sufficient ventilation. No additional measures are required. 6. Measures After Inadvertent Release Steps to protect persons: Avoid contact with skin, eyes and clothing. Thin the product with water and wash away. Environmental protection No special measures are required. measures: Ensure that enclosures are well ventilated and have an ample fresh air supply. Cleaning procedures: Thin thoroughly with water and wash away. Ensure sufficient ventilation.
EU Safety Data Sheet Trade Name: Oxydes L Created: December 5, 2003 Modified: June 19, 2006 Page: 2 of 3 7. Handling and Storage Instructions for safe handling: Requirements for storage areas and containers: Storage instructions: Recommended storage temperature: Open and handle the container with caution. Ensure sufficient ventilation when filling, emptying or transferring. Avoid direct contact with eyes, skin or clothing. Ventilate storage areas well. No fire or open flame around or in the container due to hydrogen presence. Store in a cool and well ventilated area. From 5 C To 25 C 8. Exposure Limitations and Personal Protective Equipment Additional instructions for the configuration of technical systems See chapter 7. No further measures are required. Components with threshold values that must be monitored within the working environment The product contains no components in relevant amounts that need monitoring within the working environment. General protective and hygienic measures Avoid direct contact with eyes, skin and clothing. General safety measures when dealing with chemicals are to be heeded. Personal protective gear Breathing protection: Hand protection: Not required when adequate ventilation is ensured. Use protective gloves. Glove material must be sufficiently impermeable and resistant for the materials being used. Inspect before use to ensure impermeability. Ensure hands are sufficiently protected. Thoroughly rinse gloves before removing, and then store them in a well ventilated area. Fabric and leather gloves are absolutely not suitable. Eye protection: Body protection: Gloves made of the following materials are suitable (resistance time >/= 8 hours): Natural rubber or latex - NR (0.5 mm), (use unpowdered and anti-allergenic products) Polychloroprene - CR (0.5 mm), nitrile rubber / Nitrile latex - NBR (0.35 mm) Butyl rubber - Butyl (0.5 mm), fluorine rubber - FKM (0.4 mm) Polyvinyl chloride - PVC (0.5 mm) Protective glasses / face protection recommended when transferring material. Not required 9. Physical and Chemical Properties Appearance: Form: Liquid Color: Colorless Odor: Odorless Density at 20 C 1.00-1.02 g/cm³ Melting temperature at NA C Boiling point / range: >100 C Flash point: Not applicable Self-immolation point: Not self-immolating Explosion hazard: With fire (detonating gas) Dissolubility in water at 20 C Mixable ph-value at 20 C 6.8-7.2 10. Stability and Reactivity Hazardous reactions: Thermal decomposition: Hazardous decomposition byproducts: Interaction with acids produces heat No decomposition when used as directed Hydrogen (detonating gas) 11. Toxicological Details Acute toxicity: Primary irritation on the skin In the eye Sensitization Additional toxicological information: No irritation No caustic effects No known sensitization effects According to the analysis of the EU General Categorization Guidelines for Preparations, the product presents the following dangers: Within the framework of the oral intake amounts for table salt, there is no toxicity. Avoid capturing the product. 12. Ecological Details Water pollution class: 1 (low water hazard) May enter waste or receiving water undiluted or neutralized.
EU Safety Data Sheet Trade Name: Oxydes L Created: December 5, 2003 Modified: June 19, 2006 Page: 3 of 3 13. Disposal Instructions Instructions for disposal Product: Dilute with plenty of water and wash away. Packaging: Contaminated packaging should be completely emptied. After being properly cleaned, it can be reused. EAK waste number: 07 06 99 14. Transportation Instructions Not a hazardous material according to transportation regulations 15. Regulations R-Sätze: 31 Poisonous gases produced upon contact with acids S-Sätze: 1/2 Store locked and inaccessible to children 20 Do not eat or drink 26 If eye contact occurs, immediately flush with water and seek medical attention 37 Wear suitable gloves 45 In case of accident or nausea, seek immediate medical attention (if possible, show this data sheet) 16. Other Information Further details The information provided is based upon our current knowledge and is meant to describe the product s safety requirements. It does not represent a guarantee of product characteristics and form no basis for a legal contractual relationship. Adherence to existing laws, regulations and guidelines is the sole responsibility of the user and/or handler of the product listed herein. Data sheet publication section Laboratory