ANNEX CLASSIFICATION AND LABELLING SUMMARY TABLES
ANNEX CLASSIFICATION AND LABELLING SUMMARY TABLES NOTE: The codifiction of hzrd s is further explined in Annex 3 (Section ). The hzrd re intended to be used for reference purposes only. They re not prt of the hzrd text nd should not be used to replce it. A. Explosives (see Chpter. for ifiction criteri) Clssifiction Lbelling Unstble explosive (Trnsport not llowed) Unstble explosive H00 Division.. Explosive; mss explosion hzrd H0 Dnger Division.. Explosive; severe projection hzrd H0 Explosives Division.3.3 Explosive; fire, blst or projection hzrd H03 Division. Wrning Fire or projection hzrd H0 Division.5 pictogrm Dnger My mss explode in fire H05 Division.6 pictogrm signl hzrd ne (*) Plce for comptibility group. The pictogrm for Divisions.,. nd.3 is lso ssigned to substnces which hve n explosive subsidiry risk, but without the indiction of the division number nd the comptibility group (see lso Self-rective substnces nd mixtures nd Orgnic peroxides ). - 9 -
A. Flmmble gses (see Chpter. for ifiction criteri) Clssifiction Lbelling Flmmble gs Dnger Extremely flmmble gs H0 Extremely flmmble gs H0 Pyrophoric gs Dnger My ignite spontneously if exposed to ir H3 A Extremely flmmble gs H0 Flmmble gses C unstble gs A Dnger My rect explosively even in the bsence of ir Extremely flmmble gs H30 H0 B Dnger My rect explosively even in the bsence of ir t elevted pressure nd/or temperture H3 B Dnger Flmmble gs H pictogrm t required Wrning Flmmble gs H Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck insted of white. The bckground colour stys red in both cses. A.3 Aerosols (see Chpter.3 for ifiction criteri) Clssifiction Lbelling Extremely flmmble erosol H Dnger Pressurized continer: my burst if heted H9 Flmmble erosol H3 Aerosols Wrning Pressurized continer: my burst if heted H9 3 pictogrm Wrning Pressurized continer: my burst if heted H9 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck or white. The bckground colour stys red in the first two cses nd green in the third cse. - 50 -
A. Oxidizing gses (see Chpter. for ifiction criteri) Clssifiction Lbelling code Oxidizing gses Dnger My cuse or intensify fire; oxidizer H70 5. A.5 Gses under pressure (see Chpter.5 for ifiction criteri) Clssifiction Lbelling Compressed gs Wrning Contins gs under pressure; my explode if heted H80 Gses under pressure Liquefied gs Refrigerted liquefied gs Wrning Wrning Contins gs under pressure; my explode if heted Contins refrigerted gs; my cuse cryogenic burns or injury H80 H8 Dissolved gs Wrning Contins gs under pressure; my explode if heted H80 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in white insted of blck. The bckground colour stys green in both cses. This pictogrm is not required for toxic or flmmble gses (see lso note to tbles A.8 nd A.). - 5 -
A.6 Flmmble liquids (see Chpter.6 for ifiction criteri) Clssifiction Lbelling Dnger Extremely flmmble liquid nd vpour H 3 Flmmble liquids Dnger Highly flmmble liquid nd vpour H5 3 3 Wrning Flmmble liquid nd vpour H6 3 pictogrm t required Wrning Combustible liquid H7 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck insted of white. The bckground colour stys red in both cses. A.7 Flmmble solids (see Chpter.7 for ifiction criteri) Clssifiction Lbelling Dnger Flmmble solid H8 Flmmble solids Wrning Flmmble solid H8-5 -
A.8 Self-rective substnces nd mixtures (see Chpter.8 for ifiction criteri) Clssifiction Lbelling Type A (Trnsport my not be llowed) b Dnger Heting my cuse n explosion H0 Type B Selfrective substnces nd mixtures Types C nd D Dnger Heting my cuse fire or explosion H Dnger Heting my cuse fire H Types E nd F Wrning Heting my cuse fire H Type G pictogrm t required signl hzrd ne b For Type B, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, specil provision 8 my pply (Exemption of explosive lbel with competent uthority pprovl. See Chpter 3.3 of the for more detils). My not be cceptble for trnsport in the pckging in which it is tested (See Chpter.5, pr..5.3.. of the ). A.9 Pyrophoric liquids (see Chpter.9 for ifiction criteri) Clssifiction Lbelling code Pyrophoric liquids Dnger Ctches fire spontneously if exposed to ir H50-53 -
A.0 Pyrophoric solids (see Chpter.0 for ifiction criteri) Clssifiction Lbelling code Pyrophoric solids Dnger Ctches fire spontneously if exposed to ir H50 A. Self-heting substnces nd mixtures (see Chpter. for ifiction criteri) Clssifiction Lbelling Selfsubstnces nd mixtures Dnger Self-heting; my ctch fire H5 Wrning Self-heting in lrge quntities; my ctch fire H5 A. Substnces nd mixtures, which in contct with wter, emit flmmble gses (see Chpter. for ifiction criteri) Clssifiction Lbelling Substnces nd mixtures, which in contct with wter, emit flmmble gses Dnger Dnger 3 Wrning In contct with wter releses flmmble gses which my ignite spontneously In contct with wter releses flmmble gses In contct with wter releses flmmble gses H60 H6 H6 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck insted of white. The bckground colour stys blue in both cses. - 5 -
A.3 Oxidizing liquids (see Chpter.3 for ifiction criteri) Clssifiction Lbelling Dnger 5. My cuse fire or explosion; strong oxidizer H7 Oxidizing liquids Dnger My intensify fire; oxidizer H7 5. 3 Wrning My intensify fire; oxidizer H7 5. A. Oxidizing solids (see Chpter. for ifiction criteri) Clssifiction Lbelling Dnger 5. My cuse fire or explosion; strong oxidizer H7 Oxidizing solids Dnger My intensify fire; oxidizer H7 5. 3 Wrning My intensify fire; oxidizer H7 5. - 55 -
A.5 Orgnic peroxides (see Chpter.5 for ifiction criteri) Clssifiction Lbelling Type A (Trnsport my not be llowed) b Dnger Heting my cuse n explosion H0 Type B Dnger Heting my cuse fire or explosion H Orgnic peroxides 5. nd D 5. Dnger Heting my cuse fire H Types E nd F 5. Wrning Heting my cuse fire H Type G pictogrm t required signl hzrd ne b For Type B, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, specil provision 8 my pply (Exemption of explosive lbel with competent uthority pprovl. See Chpter 3.3 of for more detils). My not be cceptble for trnsport in the pckging in which it is tested (See Chpter.5, pr..5.3.. of the ). A.6 Corrosive to metls (see Chpter.6 for ifiction criteri) Clssifiction Lbelling code Corrosive to metls Wrning My be corrosive to metls H90 8-56 -
A.7 Desensitized explosives (see Chpter.7 for ifiction criteri) Clssifiction Lbelling t pplicble Dnger Fire, blst projection hzrd; incresed risk of explosion if desensitizing gent is reduced H06 Desensitized explosives t pplicble Dnger 3 t pplicble Wrning Fire or projection hzrd; incresed risk of explosion if desensitizing gent is reduced Fire or projection hzrd; incresed risk of explosion if desensitizing gent is reduced H07 H07 t pplicble Wrning Fire hzrd; incresed risk of explosion if desensitizing gent is reduced H08 Clssifiction nd lbelling of desensitized explosives re ddressed in trnsport regultions in different wy. In trnsport, solid desensitized explosives re ified in Division. (flmmble solids) nd shll ber Division. lbel (see Chpter., section... of the UN Recommendtions on the Trnsport of Dngerous Goods, Model ). Liquid desensitized explosives re ified in Clss 3 (flmmble liquids) for trnsport purposes nd shll ber Clss 3 lbel (see, Chpter.3, section.3.. of the Model ). - 57 -
A.8 Acute toxicity (see Chpter 3. for ifiction criteri) Clssifiction Lbelling Orl Ftl if swllowed H300 Derml Dnger Ftl in contct with skin H30 Inhltion 6 Ftl if inhled H330 Acute toxicity 3 Orl Ftl if swllowed H300 Derml Dnger Ftl in contct with skin H30 Inhltion 6 Ftl if inhled H330 Orl Toxic if swllowed H30 Derml Dnger Toxic in contct with skin H3 Inhltion 6 Toxic if inhled H33 5 Orl Hrmful if swllowed H30 Derml t required Wrning Hrmful in contct with skin H3 Inhltion Hrmful if inhled H33 Orl Derml pictogrm t required Wrning My be hrmful if swllowed My be hrmful in contct with skin H303 H33 Inhltion My be hrmful if inhled H333 For gses, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, replce the number 6 in the bottom corner of the pictogrm by. A.9 Skin corrosion/irrittion (see Chpter 3. for ifiction criteri) Clssifiction Lbelling 8 Dnger Cuses severe skin burns nd eye dmge H3 Skin corrosion/irrittion t required Wrning Cuses skin irrittion H35 3 pictogrm t required Wrning Cuses mild skin irrittion H36 Applies to some uthorities. - 58 -
A.0 Serious eye dmge/eye irrittion (see Chpter 3.3 for ifiction criteri) Clssifiction Lbelling t required Dnger Cuses serious eye dmge H38 Serious eye irrittion /A t required Wrning Cuses serious eye irrittion H39 B pictogrm t required Wrning Cuses eye irrittion H30 A. Respirtory sensitizer (see Chpter 3. for ifiction criteri) Clssifiction Lbelling t required Dnger My cuse llergy or sthm symptoms or brething difficulties if inhled H33 Respirtory sensitiztion A t required Dnger My cuse llergy or sthm symptoms or brething difficulties if inhled H33 B t required Dnger My cuse llergy or sthm symptoms or brething difficulties if inhled H33 Sub-ctegories my be pplied where dt re sufficient nd where required by competent uthority. - 59 -
A. Skin sensitizer (see Chpter 3. for ifiction criteri) Clssifiction Lbelling t required Wrning My cuse n llergic skin rection H37 Skin sensitiztion A t required Wrning My cuse n llergic skin rection H37 B t required Wrning My cuse n llergic skin rection H37 Sub-ctegories my be pplied where dt re sufficient nd where required by competent uthority. A.3 Germ cell mutgenicity (see Chpter 3.5 for ifiction criteri) Clssifiction Lbelling Germ cell mutgenicity (both A nd B) t required Dnger t required Wrning A. Crcinogenicity (see Chpter 3.6 for ifiction criteri) My cuse genetic defects (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) Suspected of cusing genetic defects (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H30 H3 Clssifiction Lbelling Crcinogenicity (both A nd B) t required Dnger t required Wrning My cuse cncer (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) Suspected of cusing cncer (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H350 H35-60 -
A.5 Toxic to reproduction (see Chpter 3.7 for ifiction criteri) Reproductive toxicity Clssifiction Lbelling (both A nd B) t required Dnger t required Wrning Additionl for effects on or vi lcttion pictogrm t required signl My dmge fertility or the unborn child (stte specific effect if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) Suspected of dmging fertility or the unborn child (stte specific effect if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse hrm to brest-fed children A.6 Specific trget orgn toxicity following single exposure (see Chpter 3.8 for ifiction criteri) H360 H36 H36 Clssifiction Lbelling Specific trget orgn toxicity single exposure t required Dnger t required Wrning 3 t required Wrning Cuses dmge to orgns (or stte ll orgns ffected, if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse dmge to orgns (or stte ll orgns ffected, if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse respirtory irrittion or My cuse drowsiness or dizziness H370 H37 H335 H336-6 -
A.7 Specific trget orgn toxicity following repeted exposure (see Chpter 3.9 for ifiction criteri) Clssifiction Lbelling Specific trget orgn toxicity repeted exposure t required Dnger t required Wrning A.8 Aspirtion hzrd (See chpter 3.0 for ifiction criteri) Cuses dmge to orgns (stte ll orgns ffected, if known) through prolonged or repeted exposure (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse dmge to orgns (stte ll orgns ffected, if known) through prolonged or repeted exposure(stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H37 H373 Clssifiction Lbelling Aspirtion hzrd t required Dnger t required Wrning My be ftl if swllowed nd enters irwys My be hrmful if swllowed nd enters irwys H30 H305 A.9 () ous to the qutic environment, short-term (cute) (see Chpter. for ifiction criteri) Clssifiction Lbelling ous to the qutic environment, short-term (Acute) Acute Wrning Very toxic to qutic life H00 Acute Acute 3 pictogrm pictogrm t required t required signl signl Toxic to qutic life Hrmful to qutic life For Ctegory, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the pictogrm is not required if the substnce presents ny other hzrds covered by. If no other hzrd is presented, this pictogrm is required s mrk in ddition to the Clss 9 lbel. H0 H0-6 -
A.9 (b) ous to the qutic environment, long-term (chronic) (see Chpter. for ifiction criteri) Clssifiction Lbelling Chronic Wrning Very toxic to qutic life with long lsting effects H0 ous to the qutic environment, long-term (Chronic) Chronic Chronic 3 Chronic pictogrm pictogrm t required t required signl signl signl Toxic to qutic life with long lsting effects Hrmful to qutic life with long lsting effects My cuse long lsting hrmful effects to qutic life For ctegories nd, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the pictogrm is not required if the substnce presents ny other hzrds covered by. If no other hzrd is presented, this pictogrm is required s mrk in ddition to the Clss 9 lbel. A.30 to the ozone lyer (see Chpter. for ifiction criteri) H H H3 Clssifiction Lbelling code ous to the ozone lyer t required Wrning Hrms public helth nd the environment by destroying ozone in the upper tmosphere H0-63 -