Ministry of Defence Defence Standard Identification Marking of Transportable Containers, Compressed Gas

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Ministry of Defence Defence Standard 81-24 Issue 5 Publication Date 19 March 2004 Identification Marking of Transportable Containers, Compressed Gas

AMENDMENT RECORD Amd No Date Text Affected Signature and Date REVISION NOTE This standard is raised to Issue 5 to update its content. HISTORICAL RECORD This standard supersedes the following: Defence Standard (Def Stan) 81-24 Issue 4 dated 8 November 2002. Defence Standard (Def Stan) 81-24 Issue 3 dated 15 June 1990. Defence Standard (Def Stan) 81-24 Issue 2 and the following documents: a. Def Stan 65-4, Issue 1, dated 28 February 1969. b. Def Stan 65-1, Issue 1, dated 20 March 1967 (In respect of colour code only for containers, gas, medical). Defence Standard (Def Stan) 81-24 Issue 1 and the following additional documents: a. Specification AM2, Issue 6, dated January 1969. b. Specification 0.261, Issue 3, dated May 1958. c. SDM(A) IS 356, dated 30 August 1960.

CONTENT Description Page Content 1 Index of Tables 3 Preface 4 Main Text 5 SECTION 1 GENERAL REQUIREMENTS 0 Introduction 5 1 Scope 5 2 Warning 6 3 Related Documents 6 4 Definitions 8 5 Abbreviations 11 6 General Information 11 7 Hazard Warnings 12 SECTION 2 GROUND CONTAINERS 8 General requirements 14 9 Stamp marking 14 10 Colour Coding 18 11 Reference to Next Test Date 18 12 Stencilling 18 SECTION 3 AIRBORNE CONTAINERS 13 General requirements 28 14 Stamp marking 28 15 Marking colours 31 16 Precautionary labels 31 SECTION 4 DIVING CONTAINERS 17 General requirements 37 18 Stamp marking 37 19 Marking colours 39 20 Reference to Next Test Date 39 21 Stencilling Requirements 39 22 Transit Cases 44 SECTION 5 MEDICAL CONTAINERS 23 General requirements 45 24 Precautionary labels 45 1

CONTENT SECTION 6 NOTES APPLICABLE TO SECTIONS TWO, THREE, FOUR AND FIVE 48 SECTION 7 FIGURES - TYPICAL STAMP MARKING LAYOUTS Figure 1 Permanent Gases Containers for Ground, Diving and Medical Use 51 Figure 2 Liquefiable Gases Containers for Ground and Medical Use 52 Figure 3 Permanent Gases Containers for Airborne Use 53 Figure 4 Liquefiable Gases Containers for Airborne Use 54 SECTION 8 ANNEXES Annex A Stamp Marking: Restructured ADR 55 Figure A.1 Pi Mark 56 Annex B Summary of Hazard Warning Requirements 57 Annex C Engineering Authorities 58 Annex D Table D-1 Stencil Character Sizes in Millimetres 59 Annex E NATO code numbers and names for gases used in aircraft Cross-servicing 60 Annex F Next Test Date Disk 61 Annex G Substance of International Military Agreements 62 2

INDEX OF TABLES Table 1 Stamp marking Information Permanent Gases Page 16 Table 2 Stamp marking Information Liquefiable Gases and Liquefiable Page 17 Gases used with a Permanent Gas as a Discharging Agent (Padded) Table 3 Gas Abbreviations with Container, Band, Sector and Page 19 Stencilling Colours for Ground Containers (ADR: BS EN 1089-3). Table 3 ----- Cont. from Page 19 ----- Page 20 Table 4 Gas Abbreviations with Container, Band, Sector and Page 21 Stencilling Colours for Ground Containers (Pre 2003: BS 349). Table 4 ----- Cont. from Page 21 ----- Page 22 Table 5 Stencilling Information Permanent Gases Page 23 Table 6 Stencilling Information Liquefiable Gases (except Page 24 Refrigerants and Padded Gases) Table 7 Stencilling Information Refrigerants Page 25 Table 8 Stencilling Information Mixed Gases (Permanent) Page 26 Table 9 Stencilling Information Liquefiable Gases (Padded) Page 27 Table 10 Stamp marking Information Permanent Gases Page 29 Table 11 Stamp marking Information Liquefiable Gases and Liquefiable Page 30 Gases (Padded) Table 12 Stencilling / Marking Information Permanent Gases Page 32 Table 13 Stencilling / Marking Information Liquefiable Gases (Except Page 33 Padded Gases) Table 14 Stencilling / Marking Information Liquefiable Gases (Padded) Page 34 Table 15 Gas Abbreviations with Container, Sector and Stencilling Page 35 Colours for Airborne Containers (ADR: BS 1089-3) Table 16 Gas Abbreviations with Container, Sector and Stencilling Page 36 Colours for Airborne Containers (Pre 2003: BS 349. Table 17 Stamp marking Information Permanent Gases Page 38 Table 18 Stencilling Information Permanent Gases Page 40 Table 19 Gas Abbreviations with Container Band, Sector and Stencilling Page 41 Colours for Diving Containers (ADR: BS EN 1089-3). Table 20 Gas Abbreviations with Container Band, Sector and Stencilling Page 42 Colours for Diving Containers (Pre 2003: BS 349). Table 21 Stencilling Information Mixed Gases (Permanent) Page 43 Table B-1 Summary of Hazard Warning requirements Page 57 Table D-1 Stencil Character Sizes Page 59 Table E-1 NATO Code Numbers and Names for Gases used in Aircraft Cross-servicing Page 60 Table F-1 Recommended Test Date Discs Page 61 3

PREFACE Standards for Defence Identification marking of Transportable Containers, Compressed Gas a. This standard provides requirements for the identification marking of MOD owned and hired Transportable Containers, Compressed Gas. It does not apply to containers used in portable fire extinguishers, certain HPPA containers and US DOT standard containers. b. This standard has been produced on behalf of the Defence Materiel Standardization Committee (DMSC) by the Standard Advisory Group E/6. c. This standard has been agreed by the authorities concerned with its use and is intended to be used whenever relevant in all future designs, contracts, orders etc. and whenever practicable by amendment to those already in existence. If any difficulty arises which prevents application of the Defence Standard, the Directorate of Standardization (DStan) shall be informed so that a remedy may be sought. d. Any enquiries regarding this standard in relation to an invitation to tender or a contract in which it is incorporated are to be addressed to the responsible technical or supervising authority named in the invitation to tender or contract. e. Compliance with this Defence Standard shall not in itself relieve any person from any legal obligations imposed upon them. f. This standard has been devised solely for the use of the Ministry of Defence (MOD) and its contractors in the execution of contracts for the MOD. To the extent permitted by law, the MOD hereby excludes all liability whatsoever and howsoever arising (including, but without limitation, liability resulting from negligence) for any loss or damage however caused when the standard is used for any other purpose. 4

TEXT Standards for Defence Identification marking of Transportable Containers, Compressed Gas SECTION 1 GENERAL REQUIREMENTS 0 INTRODUCTION This standard is concerned with the identification marking and colour coding of transportable gas containers owned and hired by the MOD and medical gas containers hired by the MOD. It gives details of the stamp marking, labelling, stencilling and the colours to be applied to the containers to identify various gases and gas mixtures. This Defence Standard has been updated to reflect the continuing trend for the MOD to lease gas containers instead of owning them; and, changes in European and International requirements for gas container identification marking. In particular: the withdrawal of parts or all of the BS 5045 and BS 5430 series of gas container standards and their replacement by new European standards; new European and ISO standards for marking and colour coding of gas containers; and the requirements of the Restructured ADR and the UN Model Regulations on the Transport of Dangerous Goods. To reflect these changes, this standard provides dual requirements: markings for existing MOD containers, obtained prior to 1 st July 2003, that need to be maintained in service use, albeit with some changes when next serviced; and the markings for new containers that comply with the EN and ISO standards. Any queries or any discrepancies found between this document and legislation or Industry Standard Codes of Practice shall be referred to the Engineering Authority concerned. 1 SCOPE This standard aims to: facilitate the purchase of new transportable gas containers; assist in the maintenance and refurbishment of the MOD s existing stock of transportable gas containers; act as the UK implementing document for a number of NATO Cross-Servicing agreements; and to help ensure the MOD s transportable gas containers comply with the requirements of UK, European and International legislation. It specifies requirements for the identification marking and colour coding of transportable gas containers owned and hired by the MOD for the storage, transport and use applications of compressed permanent, liquefiable and dissolved gases. It is divided into separate sections covering General Requirements for all applications, Ground containers, Airborne containers, Diving containers and Medical containers. This division reflects the different operational requirements that each type of container may be exposed to. It does not apply to containers used in portable fire extinguishers, as these are covered by European Standards. It does not apply to special to type 0.33 litre, 0.60 litre and 2.40 litre HPPA containers as these are covered by Def Stan 81-91. 5

SECTION 1 GENERAL REQUIREMENTS It does not apply to US DOT standard containers. The identification marking of self-filled personal use containers which may contain various mixtures of breathing gases is not included in this standard but should be in accordance with its general principles as far as possible. 2 WARNING The Ministry of Defence (MOD), like its contractors, is subject to both United Kingdom and European laws regarding Health and Safety at Work, without exemption. All Defence Standards either directly or indirectly invoke the use of processes and procedures that could be injurious to health if adequate precautions are not taken. Defence Standards or their use in no way absolves users from complying with statutory and legal requirements relating to Health and Safety at Work. 3 RELATED DOCUMENTS 3.1 The publications shown below are referred to in the text of this standard. Publications are grouped and listed in alphanumeric order. Designation Title BS 349 BS 381C BS 1474 BS 5045 Part 1 BS 5045 Part 3 BS 5045 Part 7 BS 5045 Part 8 BS 5252 BS 5355 Specification for the Identification of the contents of industrial gas cylinders. (Superseded by BS EN 1089-3.) Specification for colours for identification, coding and special purposes. Specification for wrought aluminium and aluminium alloys for general engineering purposes: bars extruded round tubes and sections. Transportable gas containers. Part 1: Specification for seamless steel gas containers above 0.5 litre water capacity and up to 300 bar charged pressure at 15 C. (Superseded). Transportable gas containers. Part 3: Specification for seamless aluminium alloy gas containers above 0.5 litre water capacity. (Superseded). Transportable gas containers. Part 7: Specification for seamless steel gas containers of water capacity 0.5 L up to 15 L for special portable application. Transportable gas containers. Part 8: Specification for seamless aluminium alloy gas containers of water capacity 0.5 L up to 15 L and up to 300 bar charged pressure at 15 C for special portable application. Framework for colour co-ordination for building purposes. Specification for filling ratios and developed pressures for liquefiable and permanent gases. - (Current, Obsolete). 6

SECTION 1 GENERAL REQUIREMENTS BS 5430 Periodic inspection, testing and maintenance of transportable gas containers (excluding dissolved acetylene containers). Parts 1 to 6. (Withdrawn, superseded). BS 5609 Printed pressure-sensitive, adhesive-coated labels for marine use, including requirements for label base material. BS L 105 Specification for tube of aluminium-copper-magnesium-siliconmanganese alloy (solution treated and aged at room temperature) (not exceeding 10 mm wall thickness) (Cu 4.4, Mg 0.5, Si 0.7, Mn 0.8). BS L 111:1971 Specification for bars and extruded sections of aluminiummagnesium-silicon-manganese alloy (Solution treated and precipitation treated) (suitable for welding) (Mg 0.8, Mg 0.5, Si 0.7, Mn 0.8). BS EN 629-1 Transportable gas cylinders 25E taper thread for connection of valves to gas cylinders. Part 1: Specification. BS EN 850 Transportable gas cylinders. Pin-index, yoke-type valve outlet connections for medical use. BS EN 1089-1 Transportable gas cylinders. Gas cylinder identification (excluding LPG). Part 1: Stamp marking. - (Superseded by BS ISO 13769). BS EN 1089-2 Transportable gas cylinders. Gas cylinder identification (excluding LPG). Part 2: Precautionary labels. BS EN 1089-3 Transportable gas cylinders. Gas cylinder identification (excluding LPG). Part 3: Colour coding. BS EN 1964-1 Transportable gas cylinders Specification for the design and construction of refillable transportable seamless steel cylinders of water capacities from 0,5 litre up to and including 150 litres Part 1: Cylinders made of seamless steel with an R m value of less than 1100 MPa. BS EN 1968 Transportable gas cylinders Periodic inspection and testing of seamless steel gas cylinders. BS EN 1975 Transportable gas cylinders. Specification for the design and construction of refillable transportable seamless aluminium alloy gas cylinders of capacity from 0,5 litre up to 150 litre. BS EN 2326 Aluminium alloy AL-P6082-T6. Extruded bars and sections a or D mm 200 mm. BS EN ISO 3166-1 BS EN ISO 11114-1 BS ISO 13769 EIGA PP 03 Code for the representation of names of countries and the subdivisions Part 1: Country codes. Transportable gas cylinders Compatibility of cylinder and valve materials with gas contents Part 1: Metallic materials. Gas Cylinders Stamp marking. Position Paper 03. Harmonization of the Pi-Marking for Gas cylinders and valve. November 2002. 7

SECTION 1 ISO 32 RAL 840 HR Def Stan 00-970 Def Stan 05-18 Def Stan 05-34 Def Stan 81-91 Def Stan 81-121 QSTAG-236 STANAG 2121 STANAG 7146 GENERAL REQUIREMENTS Gas cylinders for medical use Marking for identification of cylinder content Farbregister Colour Cards. Design and Airworthiness Requirements for Service Aircraft. Symbol markings of servicing and safety/hazard points on aircraft, ground support equipment and guided weapons systems. Marking of Service Material. High Pressure Pure Air Equipment for Detector Cooling Applications. Reconditioning of Airborne high pressure seamless steel gas containers and their fittings. Colours for medical gas containers. Colour Coding of Medical Gas Containers. Assignment of NATO code numbers to Gases used in Aircraft Cross-Servicing. Model Regulations Restructured ADR Recommendations on the Transport of Dangerous Goods. United Nations. European Agreement Concerning the International Carriage of Dangerous Good by Road. United Nations 3.2 Reference in this standard to any related document means in any invitation to tender or contract the edition and all amendments current at the date of such tender or contract unless a specific edition is indicated. 3.3 In consideration of 3.2 above, users shall be fully aware of the issue and amendment status of all related documents, particularly when forming part of an invitation to tender or contract. Responsibility for the correct application of standards rests with users. 3.4 DStan can advise regarding where related documents are obtained from. Requests for such information can be made to the DStan Helpdesk. How to contact the helpdesk is shown on the outside rear cover of Def Stans. 4 DEFINITIONS For the purpose of this standard the following definitions apply. 8

SECTION 1 GENERAL REQUIREMENTS 4.1 Certification Marks A group of Stamp Markings, defined in the Restructured ADR and UN Model Regulations: covering the UN mark, the container s technical standard, symbols identifying the Country of Approval, the Inspection Stamp and the Date of Inspection. (See Annex A and BS ISO 13769). 4.2 Colour coding Defined as, a system of colour coding Containers as a means of identifying their contents by reference to the property of the gas or gas mixture. For compliance with BS EN 1089-3, colour coding only refers to the identification colour, or colours, on the shoulder of the container. 4.3 Container Defined as, a generic term covering bottles, cylinders, etc., which are used as vessels to contain and store compressed gases. 4.4 Manufacturing Marks A group of Stamp Markings, defined in the Restructured ADR and UN Model Regulations, including the container thread Identification, the manufacturer's mark (preceded by the country of manufacture code when this is different), the serial number, the letter "H" when applicable. (See Annex A and BS ISO 13769). 4.5 Nitrogen padded The addition of a secondary gas charge (nitrogen), as a discharging agent, to a gas container holding a main charge of liquefied gas in order to minimise any changes in the outlet supply pressure of the main gas caused by changes, particularly reductions, in external temperature. 4.6 Operational Marks A group of Stamp Markings, defined in the Restructured ADR and UN Model Regulations, including: test pressure, empty mass of the pressure receptacle, minimum guaranteed wall thickness of the pressure receptacle, the water capacity (for liquefied gases). (See Annex A, BS ISO 13769 and EIGA Position Paper 03/2002). 4.7 Other Marks The term used in BS ISO 13769, the Restructured ADR and the UN Model Regulations to refer both to Stamp Marks required by regulations, such as the Inspection Body stamp and the date of the last inspection stamp(s), as well as stamp marks required by the owner, such as the MOD pheon mark and the NATO stock number. (See Annex A and BS ISO 13769). 9

SECTION 1 GENERAL REQUIREMENTS 4.8 Pi (P) Mark A Stamp Mark, required under TPED, certifying that the container is compliant with the Restructured ADR. Note: the style of the Pi mark is defined in TPED, the above Π mark does not conform to the required style (see Figure A.1). 4.9 Precautionary Labelling Defined as, a generic term covering the means of identifying the contents of each container; warning of principle hazards by means of a coloured hazard diamond(s) and words; and for providing other information such as the chemical name and formula of the gas or gas mixture. Specific examples of how this might be achieved include self-adhesive labels, stencil marks, or transfers, and various combinations of these. 4.10 Proper Shipping Name A means of naming Dangerous Goods. Each Proper Shipping Name is directly linked to its UN Number. (See Annex B, the Restructured ADR and the UN Model Regulations.) 4.11 Stamp marking Defined as Permanent Markings applied to the container, usually by hard stamping on a reinforced part of the container, which provide Manufacturing, Certification and Operational information. However, in the case of light-weight composite-wrapped containers, such permanent markings have been achieved by labels contained under the transparent outer layer of the resin matrix. Non-ferrous stamping rings soldered onto the neck provide an area for Stamp Marking on some Airborne containers. 4.12 UN Class Number A set of Classes and Divisions allocated by the UN to identify classes of Dangerous Goods based on their hazards. Gases fall into Class 2, Gases, and are further divided into three Divisions: i.e. Division 2.1 Flammable gases; Division 2.2 Non flammable, Non toxic gases, and Division 2.3 Toxic gases (see Annex B, the Restructured ADR and the UN Model Regulations). 4.13 UN Mark Defined as a UN Packaging symbol, of specified design, denoting that the container complies with the Restructured ADR requirements for UN certified pressure receptacles. 10

SECTION 1 GENERAL REQUIREMENTS 4.14 UN Number A number allocated by the UN to identify Dangerous Goods. It is directly linked to the Proper Shipping Name (See Annex B, the Restructured ADR and the UN Model Regulations). The number is preceded by the symbol UN. 4.15 UW Mark Defined in the Restructured ADR and UN Model Regulations as a Stamp Mark signifying that a composite cylinder intended for underwater use is compliant with the Model Regulations. 5 ABBREVIATIONS Designation Title ABCA American, British, Canadian and Australian Armies Standardization Programme ABO Aviator s Breathing Oxygen ADR European Agreement concerning the International Carriage of Dangerous Goods by Road BS British Standard BS EN European standard having the status of a British Standard BS ISO ISO Standard implemented as a British Standard Def Stan Defence Standard DOT U.S. Department of Transportation EIGA European Industrial Gases Association HPPA High Pressure Pure Air ISO International Organization for Standardization NATO North Atlantic Treaty Organisation NDT Non-destructive tests QSTAG ABCA Quadripartite Standardization Agreement STANAG NATO Standardization Agreement TPED Transportable Pressure Equipment Directive UN United Nations. 6 GENERAL INFORMATION 6.1 General The MOD has traditionally used Stencilling as a means of labelling the contents of containers and of providing a warning of the associated hazards. However, relying on stencilling alone may not provide all the precautionary information required under the Restructured ADR. 11

SECTION 1 GENERAL REQUIREMENTS The appropriate Engineering Authorities for Airborne and Ground Containers have agreed that alternative methods of marking may be used in place of, or in conjunction with, stencilling to provide the required precautionary information, e.g. transfers and adhesive labels. Where alternative methods of labelling and stencilling are proposed for identification marking of other categories of Containers, e.g. Medical Containers and Diving Containers, these changes shall not be implemented unless the appropriate Engineering Authorities agree. For further information reference may be made to the Engineering Authority responsible for that particular section of the Defence Standard (see Annex C). 6.2 Stamp marking Stamped markings shall not be less than 2.5 mm in height for containers less than 140 mm diameter and should where possible be a minimum of 5 mm in height for containers equal to or greater than 140 mm diameter. Where a UN Mark is used, it shall not be less than 5 mm in height for containers less than 140 mm diameter and a minimum of 10 mm in height for containers equal to or greater than 140 mm diameter. 6.3 Character marking Characters used in stencils, labels or transfers should conform to the sizes given in Annex D where practicable. 6.4 Symbol marking Where alpha-numeric symbols are required to be stencilled or stamped on the container or collar, these symbols are to be presented in block capitals in order to conform to accepted trade practice. Note: In Europe decimal places are denoted with a comma, e.g. 25,5, in contrast to the normal UK practice of a decimal point, e.g. 25.5. Similarly, in Europe a space is used to mark thousands, e.g. 10 000 000, in contrast to the normal UK practice of using a comma, e.g. 10,000,000. The European convention shall be used for container marking. 6.5 Notes to tables The Notes applicable to the tables in SECTIONS 2, 3, 4 and 5 have been collected together and are listed in SECTION 6. 12

SECTION 1 GENERAL REQUIREMENTS 7 HAZARD WARNINGS 7.1 The Filler of the container shall ensure that the container is correctly labelled and that safety and other statutory markings and labels on containers conform to the European Transportable Pressure Equipment Regulations, and International regulations, e.g. Restructured ADR or UN Model Regulations, appropriate to the product and the movement involved. (See Annex B). 7.2 Where transit cases are used to transport gas containers, it shall be responsibility of the packer to ensure that both the transit case and the gas container shall be fully labelled so as to identify the contents of the gas container, its properties and the associated hazards. (See Annex B). 7.3 The primary method of identification of a gas container is by the name of the gas marked on the container and its warning label. Colour marking of containers is a secondary method of identifying the hazard group appertaining to the contents and is not to be relied upon as a means of identifying the actual content. There is no common universal standard for container colour coding. Individual nations, manufacturers, etc, generally follow their own national standards. MOD Policy is to comply with BS EN 1089-2 for precautionary labels and BS EN 1089-3 for colour coding. 13

SECTION 2 GROUND CONTAINERS 8 GENERAL REQUIREMENTS 8.1 Contractor owned containers Contractor owned transportable gas containers shall be stamp marked in accordance with the requirements of BS ISO 13769, labelled in accordance with the requirements of BS EN 1089-2 and the Restructured ADR, and colour-coded in accordance with the requirements of BS EN 1089-3. In addition, in order to meet the requirements for Aircraft Cross-Servicing, Ground Containers containing gases to be used in servicing aircraft shall be labelled with the appropriate NATO Code Number and NATO Gas Name in accordance with Table E-1. Note: this may be achieved by the use of a separate label, by adding this additional information to the labels required by BS EN 1089-2, or by paint stencilling. Note: Sub-clause 8.2 and Clauses 9, 10, 11 and 12 do not apply to Contractor owned containers. 8.2 MOD owned Ground Containers MOD owned transportable containers shall be stamp marked in accordance with Clause 9; colour coded in accordance with Clause 10, be fitted with a Next Test Date disc in accordance with Clause 11 and stencilled in accordance with Clause 12. In addition, a precautionary label in accordance with the requirements of BS EN 1089-2 and the Restructured ADR shall be firmly attached to the container. This label shall, as a minimum, identify the contents with the appropriate coloured Hazard diamond, the UN Number, the Proper Shipping Name of the gas or mixture, and the UN Class Number. (See Annex B). In order to meet the requirements for Aircraft Cross-Servicing, containers containing gases to be used in servicing aircraft shall be labelled with the appropriate NATO Code Number and NATO Gas Name, in accordance with Table E-1. Note: this may be achieved by the use of a separate label, or by adding this additional information to the labels required by BS EN 1089-2, or by paint stencilling. 9 STAMP MARKING 9.1 General Stamp marking shall be applied on the container shoulder unless a non-ferrous stamping ring is fitted, and is to contain the information detailed at 9.3 or 9.4, as appropriate for its intended application. 14

SECTION 2 GROUND CONTAINERS Containers obtained prior to 1 st July 2003 shall comply as a minimum with the pre- 2003 column of Table 1 or 2, as appropriate. Containers obtained since 1 st July 2003 will already comply with either the BS EN 1089-1 or BS ISO 13769 requirements and shall be stamp marked with the information specified in the Restructured ADR column of Table 1 or 2, as appropriate. 9.2 Size For sizes of stamped markings see 6.2. 15

SECTION 2 GROUND CONTAINERS 9.3 Permanent Gases The following table lists information required on the containers for permanent gases. Table 1: Stamp marking information permanent gases Item Information required example Pre 2003 Example Markings Remarks Example: Restructured ADR Remarks 1 Government property mark MOD see Note 1 MOD see Note 1 2 Design BS5045/1/C BSEN1964-1 specification/material construction code 3 Mark number (if allocated) Mk 7A Mk 7A, or equivalent 4 NATO stock number 8120-99-000- See Note 2 8120-99-xxxxxxx See Note 2 (NSN) 0000 5 Test pressure TP372BAR PH372BAR 6 Date of test TD4/89 V See Note 17 2001/11 See Note 3 (month/year) (year/month) 7 Manufacturer s initials or trade mark XYZ LTD GB + XYZ LTD See Notes 31 and 32 8 Manufacturer s container 876543 876543 serial number 9 Mass of container shell and collar (if fitted) 10 Charged pressure CP248BAR AT 11 Design gas chemical symbol 12 Climatic area identification letter 13 Manufacturer s inspection stamp M130KG 130KG No M symbol. Rounded to 3 significant digits See Note 14 PW248BAR Operating pressure 15 C see Note 23 N 2 N 2 D See BS 5355 Not used Only for BS 5045 AB 14 Independent inspection See Note 31 CD GB + CD authority mark 15 Refurbisher s approved EF As necessary. stamp (where applicable) EF 03/11 See Note 5 16 Min Design thickness Not used 6,9MM See Note 29 17 Designated water capacity Not used 50L 18 NDT tested Not used UT See Note 24 19 Neck internal thread size Not used 25E 20 Notified Body Not used 1234 Identification 21 Pi mark, comply with Not used Π See Note 28 TPED 22 Min operating temperature Not used -40 This is Celcius. 23 Steel Compatibility Not used H See Note 25 Notes applicable to the tables are in SECTION 6. A typical pre-2003 stamp marking layout drawing is shown in Figure 1. The Restructured ADR stamp marking requirements are summarised in Annex A. AB 16

SECTION 2 GROUND CONTAINERS 9.4 Liquefiable Gases The following table lists information required on the containers for liquefiable gases and liquefiable gases used with a permanent gas as a discharging agent (padded): Table 2: Stamp marking information liquefiable gases and liquefiable gases used with a permanent gas as a discharging agent (padded) Item Information required Pre 2003 Remarks. Example: Remarks example Example Markings Restructured ADR 1 Government property mark MOD see Note 1 MOD see Note 1 2 Design BS5045/1/C specification/material BSEN1964-1 construction code 3 Mark number (if allocated) Mk 6 Mk 6 equivalent 4 NATO stock number 8120-99-000- See Note 2 8120-99-xxxxxxx (NSN) 0000 See Note 2 5 Test pressure TP243BAR PH243BAR 6 Date of test TD4/89V see Note 17 2001/11 See Note 3 7 Design water capacity in litres (month/year) (year/month) WC34 L 34L No WC symbol. Rounded to 3 significant digits 8 Tare (= mass of container T50KG + valve + paint) See Note 4 TARE50,0KG No T symbol 9 Manufacturer s initials or XYZ LTD GB + XYG LTD See Notes 31 and trade mark 32 10 Manufacturer s container 765432 serial number 765432 11 Design gas chemical symbol. CO 2 See Item 19 See Note 26 12 Climatic area identification letter D See BS 5355 Not used Only for BS 5045 13 Filling ratio.667 See BS 5335 Not used See Note 26 14 Manufacturer s inspection stamp AB AB 15 Independent inspection See Note 31 CD authority mark GB + CD 16 Refurbisher s approved As necessary. EF EF 03/11 stamp (where applicable) See Note 5 17 Min Design thickness Not used 6,31MM See Note 29 18 Mass of container shell Not used 48KG Empty weight and collar (if fitted) 19 Max Filling mass Not used 22,5KG CO 2 See Note 26 20 NDT tested Not used UT See Note 24 21 Neck internal thread size Not used 25E 22 Notified Body Not used 1234 Identification 23 Steel Compatibility Not used H See Note 25 24 Pi mark comply with TPED Not used Π See Note 28 Notes applicable to the tables are in SECTION 6. A typical pre-2003 stamping layout drawing is shown in Figure 2. The Restructured ADR stamp marking requirements are summarised in Annex A. 17

SECTION 2 GROUND CONTAINERS 10 COLOUR CODING For Containers obtained since 1 st July 2003, the container colour, shoulder or band colour(s) and position(s) where appropriate, shall be as specified in Table 3. The shoulder colour(s) and width of the band(s), if any, shall be in accordance with BS EN 1089-3. Table 4 specifies the container colour, shoulder or band colour(s) and position(s) that were used on Containers obtained prior to 1 st July 2003 (to BS 349 standard). Some of these marking colours are not compliant with the requirements of BS EN 1089-3 and when next refurbished these containers shall be re-marked in accordance with Table 3. 11 REFERENCE TO NEXT TEST DATE The next test date (Year/Month, e.g. 2006/05) shall be clearly indicated on the container by means of stamping, engraving, a durable label, or a disc fitted between the valve and the container. To provide consistency between MOD owned containers, and European Standards for periodic inspection and testing of transportable gas containers, the use of Next Test Date Discs is preferred, as specified in the, now withdrawn, BS 5430 series of standards and their possible ISO replacements. Where ever practicable, these discs should be incorporated during the next refurbishment cycle. (See Annex F). 12 STENCILLING 12.1 General Stencilling is to be applied on the container as detailed in 12.2 to 12.7, as appropriate for its intended application. The container stencilling colour(s), where appropriate, shall be as specified in Table 3. Table 4 specifies the stencilling colours that were used on Containers obtained prior to 1 st July 2003 (to BS 349 standard). Some of these marking colours are not compliant with the requirements of BS EN 1089-3 and when next refurbished these containers shall be marked in accordance with Table 3. 12.2 Size For sizes of stencil characters see Annex D. 18

SECTION 2 GROUND CONTAINERS Table 3:- Gas Abbreviations with Container, Band, Sector and Stencilling Colours for Ground Containers (Restructured ADR Requirements) Item Name of gas Abbreviation or chemical symbol Container Colour RAL 840 HR Shoulder colour RAL 840 HR Shoulder Sector Colours Shoulder Stencilling colour Cylinder section Opposite end 1 AIR, COMPRESSED AIR Dusty Grey 7037 Yellow Green 6018 - Black Black Black 2 AIR, BREATHING AIR BREATHING Dusty Grey 7037-9005 9010 9005 9010 Black 90 White 90 Black 90 White 90 Grey Black Black 3 PURE AIR PURE AIR Dusty Grey 7037 Pure White 9010 - Black Black Black 19 4 BORON TRIFLUORIDE BF 3 Silver - Zinc Yellow 1018 - Black Black Black 5 CARBON DIOXIDE CO 2 Black - Dusty Grey 7037 - White White White 6 CARBON DIOXIDE NITROGEN PADDED CO 2/N 2 Silver - Dusty Grey 7037 - White Black Black 7 HELIUM, COMPRESSED He Olive Brown 8008 Olive Brown 8008 - White White White 8 HYDROGEN, COMPRESSED H 2 Flame Red 3000 Flame Red 3000 - Black Black Black 9 ELECTROLYTIC HYDROGEN EL H 2 Flame Red 3000 Flame Red 3000 - Black Black Black 10 METHYL BROMIDE CH 3Br Zinc Yellow Continued on Page 20 1018 - White White White DEF STAN 81-24/5

SECTION 2 GROUND CONTAINERS Table 3: (Concluded from Page 19) - Gas Abbreviations with Container, Band, Sector and Stencilling Colours for Ground Containers (Restructured ADR: BS EN 1089-3 Requirements) Item Name of gas 11 METHYL CHLORIDE (REFRIGERANT GAS R40) Abbreviation or chemical symbol Container Colour RAL 840 HR Shoulder RAL 840 HR Shoulder Stencilling colour Sector Colours Shoulder Cylinder Opposite end section CH 3Cl Light green - Flame Red 3000 - Black Black Black DEF STAN 81-24/5 12 NITROGEN, COMPRESSED N 2 Dusty Grey 7037 Jet Black 9005 - White Black Black 13 HIGH PURITY NITROGEN N 2 HIGH PURITY Dusty Grey 7037 Jet Black 9005 - White Black Black 14 BREATHING OXYGEN O 2 AV Jet Black 9005 Pure White 9010 - Black White White 20 15 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R12) 16 MONOCHLORODIFLUOROMETHANE (REFRIGERANT GAS R22) CCl 2F 2 Dusty Grey 7037 Yellow Green CHClF 2 Silver - Yellow Green 6018 - White White White 6018 - Black Black Black 17 1,2-DICHLORO-1,1,2,2- TETRAFLUOROETHANE (REFRIGERANT GAS R114) (CClF 2) 2 Silver - Yellow Green 6018 - Black Black Black 18 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R134a) CF 3CH 2F, (R134A) Silver - Yellow Green 6018 - Black Black Black 19 REFRIGENT GAS, N.O.S. (CHLORODIFLUOROMETHANE, PERFLUOROPROPANE, PROPANE MIXTURE) (REFRIGERANT 403b) R403B Silver - Yellow Green 6018 - Black Black Black NOTE 1: The width and positions of the colour bands where appropriate shall comply with the printing and stencilling drawings available from the relevant Engineering Authority.

SECTION 2 GROUND CONTAINERS Table 4: - Gas Abbreviations with Container, Band, Sector and Stencilling Colours for Ground Containers (Pre-2003: BS 349 Requirements). Item Name of gas Abbreviation or chemical symbol Container Colour BS 381C Shoulder Band colour Adjoining Parallel BS 381 C Valve end Sector Colours (shoulder) Shoulder Stencilling colour Cylinder section Opposite end 1 AIR AIR French grey 630 - - - - Black Black Black 2 AIR BREATHING AIR BREATHING French grey 630 - - - Black 90 White 90 Black 90 White 90 French grey Black Black 3 PURE AIR PURE AIR French grey 630 White - - - Black Black Black 21 4 BORON TRIFLUORIDE BF 3 Silver - Golden yellow - 356 - Black Black Black 5 CARBON DIOXIDE CO 2 Black - French grey - - - White White White 6 CARBON DIOXIDE NITROGEN PADDED CO 2/N 2 Silver - - - - - Black Black Black 7 HELIUM He Middle brown 411 - - - - White White White 8 HYDROGEN H 2 Signal red 537 - - - - Black Black Black 9 ELECTROLYTIC HYDROGEN EL H 2 Signal red 537 - - - - Black Black Black 10 METHYL BROMIDE CH 3Br Peacock blue 103 Black - - - White White White 11 METHYL CHLORIDE (FLAMMABLE REFRIGERANT) CH 3Cl Light Brunswick green 225 Signal red - 537 - Black Black Black Continued on Page 22 DEF STAN 81-24/5

SECTION 2 GROUND CONTAINERS Table 4: (Concluded from Page 21) - Gas Abbreviations with Container, Band, Sector and Stencilling Colours for Ground Containers (Pre-2003: BS 349 Requirements). Item Name of gas Abbreviation or chemical symbol Container Colour BS 381C Band colour Adjoining Shoulder Parallel BS 381 C Shoulder Sector Colours Shoulder Stencilling colour Cylinder section Opposite end DEF STAN 81-24/5 12 NITROGEN N 2 French grey 630 Black - - - White Black Black 13 HIGH PURITY NITROGEN N 2 HIGH PURITY French grey 630 Black - - - White Black Black 14 BREATHING OXYGEN O 2 AV Black - White - - - Black White White 15 REFRIGERANT 12 (DICHLORODIFLUOROMETHANE) CCl 2F 2 French grey 630 Violet - 796 - White White White 22 16 REFRIGERANT 22 (MONOCHLORODIFLUOROMETHANE) CHClF 2 Silver - - - - - Black Black Black 17 REFRIGERANT 114 (DICHLOROTETRAFLUOROETHANE) (CClF 2) 2 Silver - - - - - Black Black Black NOTE 1: The width and positions of the colour bands where appropriate shall comply with the printing and stencilling drawings available from the relevant Engineering Authority. NOTE 2: Some containers, e.g. for Methyl Bromide and the four refrigerants, have specified shoulder colours that comply with the old BS 349 standard, not BS EN 1089-3 colours. Other containers may differ only in respect of the shade of colour. NOTE 3: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle.

SECTION 2 GROUND CONTAINERS 12.3 Permanent gases The following table lists information and stencil positioning required for permanent gases: Table 5: Stencilling Information Permanent Gases Item Information Position Information Required Pre 2003 Example Markings Remarks Example: Restructured ADR Remarks 1 AT VALVE END (SHOULDER) Abbreviation of gas name or chemical symbol N 2 see Table 3 or 4 N 2 see Table 3 2 Charged pressure CP 414 BAR/6000 PSI see Note 14 PW414 BAR See Note 23 3 NATO stock number (NSN) 6830-99-000-0000 see Note 6 6830-99-000- xxxx see Note 6 4 High pressure warning (where applicable) WARNING CP 414 BAR see Note 10 WARNING PW 414 BAR see Note 10 5 ON CYLINDRICAL Government property mark SECTION 6 LENGTHWISE Name of gas (in full) MOD see Note 1 MOD see Note 1 NITROGEN see Note 7 NITROGEN see Note 7 7 Discharge instruction DO NOT DISCHARGE BELOW 7 BAR/100 PSI DO NOT DISCHARGE BELOW 7 BAR 8 Hazard warning USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS 9 ON OPPOSITE END Date of test (month/year) TD 4/89 V see Note 17 2001/11 (year/month) See Notes 3 & 5 Notes applicable to the tables are in SECTION 6. Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 23

SECTION 2 GROUND CONTAINERS 12.4 Liquefiable gases The following table lists information and stencil positioning required for liquefiable gases, except refrigerants and padded gases (see 12.5 and 12.7). Table 6: Stencilling Information Liquefiable Gases (except refrigerants and padded gases) Item Information Position Information required Pre 2003 Example Markings Remarks Example: Restructured ADR Remarks 1 AT VALVE END Abbreviation of (SHOULDER) gas name or chemical symbol CO 2 see Table 3 or 4 CO 2 see Table 3 2 NATO stock number (NSN) 6830-99-000-0000 See Note 6 6830-99-000-0000 See Note 6 3 ON CYLINDRICAL Government property mark SECTION LENGTHWISE 4 Name of gas (in full) MOD see Note 1 MOD see Note 1 CARBON DIOXIDE See Note 7 CARBON DIOXIDE See Note 7 5 Tare (mass of container and valves) T 50 KG/110 LB see Note 4 TARE50KG 6 Filled mass FM 73 KG/160 LB see Note 15 Not Used 7 Max. Permissible Filling Weight Not Used 10KG CO2 See Note 26 8 Siphon tube marking see Note 16 see Note 16 9 ON OPPOSITE END Date of test TD 4/89 V (month/year) see Note 17 2001/11 (year/month) See Notes 3 & 5 Notes applicable to the tables are in SECTION 6. Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 24

SECTION 2 GROUND CONTAINERS 12.5 Refrigerants The following table lists information and stencil positioning required for refrigerants: Table 7: Stencilling Information Refrigerants Item Information position Information required Pre 2003 Example markings Remarks Example: Restructured ADR Remarks 1 AT VALVE END (SHOULDER) Abbreviation of gas name or chemical symbol CCL 2 F 2 see Table 3 or 4 CCL 2 F 2 see Table 3 2 NATO stock number (NSN) 6830-99-000-0000 see Note 6 6830-99-000- xxxx see Note 6 3 ON CYLINDRICAL Government property mark SECTION LENGTHWISE 4 Identification of refrigerant MOD REFRIGERANT 12 see Note 1 MOD see Note 1 REFRIGERANT 12 5 Chemical symbol (for Ammonia the name of the gas in full shall be used) 6 Tare (mass of container and valve) CCL 2 F 2 CCL 2 F 2 T 62 KG/136 LB See Note 4 TARE62KG No T 7 Filled mass FM 95 KG/209 LB see Note 15 Not used 8 Max. Permissible Filling Weight Not Used 10KG CCL 2 F 2 See Note 26 9 Siphon tube marking see Note 16 see Note 16 10 ON OPPOSITE END Date of test TD 4/89 V (month/year) see Note 17 2001/11 (year/month) See Notes 3 & 5 Notes applicable to the tables are in SECTION 6. Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 25

SECTION 2 GROUND CONTAINERS 12.6 Mixed gases (permanent) The following table lists information and stencil positioning required for mixed gases (permanent): Table 8: Stencilling Information Mixed Gases (permanent) Item Information position Information required Pre 2003 Example markings Remarks Example: Restructured ADR Remarks 1 AT VALVE END (SHOULDER) Abbreviations of gas names or chemical symbols with percentage content 16 % O 2 / 84 % He See Table 3 or 4. See Note 11 16 % O 2 / 84 % He See Table 3 see Note 11 2 Charged pressure CP 276 BAR/4000 PSI see Note 14 PW276BAR See Note 23 3 NATO stock number (NSN) 6830-99-000-0000 see Note 6 6830-99-000- xxxx see Note 6 4 ON CYLINDRICAL Government property mark SECTION 5 LENGTHWISE Names of gases (in full with percentage content) MOD see Note 1 MOD see Note 1 OXYGEN / HELIUM 16% OXYGEN / 84% HELIUM see Note 11 OXYGEN / HELIUM 16% OXYGEN / 84% HELIUM see Note 11 6 Discharge instruction DO NOT DISCHARGE BELOW 7 BAR / 1OO PSI DO NOT DISCHARGE BELOW 7 BAR 7 Hazard warning USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS 8 ON OPPOSITE END Date of test TD 4/89 V (month/year) see Note 17 2001/11 (year/month) See Notes 3 & 5 Notes applicable to the tables are in SECTION 6. Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 26

SECTION 2 GROUND CONTAINERS 12.7 Liquefiable gases (padded) The following table lists information and stencil positioning required for liquefiable gases (padded): Table 9: Stencilling Information Liquefiable Gases (padded) Item No Information position Information required Pre 2003 Example markings Remarks Example: Restructured ADR Remarks 1 AT VALVE END (SHOULDER) Abbreviations of gas names or chemical symbol CO 2 /N 2 See Table 3 or 4 CO 2 /N 2 See Table 3 2 NATO stock number (NSN) 6830-99-000-0000 see Note 6 6830-99-000- xxxx see Note 6 3 4 ON CYLINDRICAL SECTION LENGTHWISE Government property mark Names of gases (in full) with controlling pressure and temperature MOD see Note 1 MOD see Note 1 CARBON DIOXIDE NITROGEN PADDED TO 100 BAR /1450 PSI AT 15 C CARBON DIOXIDE NITROGEN PADDED TO 100 BAR AT 15 C 5 Tare (mass of container and valve) T 9.5 KG / 21 LB see Note 4 TARE9,5KG 6 Filled Mass FM 13.5 KG /30 LB see Note 15 Not Used 7 Max. Permissible Filling Weight Not Used 10KG CCL 2 F 2 See Note 26 8 Siphon tube marking see Note 16 see Note 16 9 ON OPPOSITE END Date of test TD 4/89 V (month/year) see Note 17 2001/11 (year/month) See Notes 3 & 5 Notes applicable to the tables are in SECTION 6. Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 27

SECTION 3 AIRBORNE CONTAINERS 13 GENERAL REQUIREMENTS The use of airborne high pressure containers is subject to various constraints regarding container life, the number of cycles in which the container can be filled and discharged and to reconditioning requirements (see Def Stan 81-121). Clauses 14, 15 and 16 detail various requirements for stamp marking, marking colours, stencilling and labelling of containers. In addition a system of coding with coloured spots is employed to indicate container life-extension and reconditioning status (see Tables 12, 13 and 14). Clauses 14, 15 and 16 identify the markings found on existing containers that were applied prior to February 2004 and detail those that meet the requirements of the Restructured ADR. Most airborne containers were manufactured to specifications provided by aircraft and cylinder design authorities, Def Stan 00-970, or earlier versions such as Ministry of Aviation specifications, which are not recognised by the Restructured ADR and TPED. However the marking of these items should as far as practicable, comply with the requirements of the Restructured ADR. Any stamping, stencilling, painting or labelling applied to airborne containers post issue of this Def Stan are to be, as far as practicable in the format specified by the Restructured ADR as specified in Tables 10 to 16. 14 STAMP MARKING 14.1 General Stamp marking shall be applied either on the non-ferrous neck collar provided for the purpose or on the container shoulder or both, unless otherwise approved by the Engineering Authority, and is to contain the information detailed at 14.3 and 14.4. 14.2 Size For sizes of stamped markings see 6.2. 28

SECTION 3 AIRBORNE CONTAINERS 14.3 Permanent gases The following table lists information required on the container neck collar or the neck collar and/or shoulder for permanent gases: Table 10: Stamp marking Information Permanent Gases Item Information required Pre 2003 Example markings 1 Government property mark Remarks Example: Restructured ADR Remarks MOD see Note 1 MOD see Notes 1 and 34 2 Mark number MK A25 MK A25, or equivalent 3 NATO stock number (NSN) 8120-99-000-0000 See Note 34 see Note 2 8120-99-000-XXX see Note 2 4 Test pressure TP 259 BAR PH259BAR 5 Mass of container shell M 28 KG 28KG 6 Date of test TD 4/89 V (month/year) see Note 17 1989/04 (year/month) See Note 3 7 Material identification CM see Note 12 see Note 12 8 Manufacturer s initials or trade mark 9 Manufacturer s container serial number XYZ LTD GB + XYZ LTD See Notes 31 and 32 87654 87654 10 Manufacturer s inspection stamp 11 Independent inspection authority mark. (where appropriate) AB CD See Note 20 AB See Note 20 See Note 20 See Note 20. GB + CD See Note 31 12 Refurbisher s approved stamp (where (applicable) EF EF 03/11 See Note 5 13 Date of Manufacture DoM 12/77 (Month/Year) DoM 2003/07 (Year/Month) 14 Manufacturer s ABC1 234 see Note 22 ABC1 234 see Note 22 Drawing or Part 15 Min Design thickness Not used 6,31MM See Note 29 Notes applicable to the tables are in SECTION 6. A typical pre-2003 stamping layout is shown in Figure 3. The Restructured ADR stamp marking requirements are summarised in Annex A. 29

SECTION 3 AIRBORNE CONTAINERS 14.4 Liquefiable gases and liquefiable gases (padded) The following table lists information required on the container neck collar or the neck collar and/or shoulder for liquefiable gases and liquefiable gases (padded): Table 11: Stamp marking Information Liquefiable Gases and Liquefiable Gases (padded) Item Information required Pre 2003 Example markings Remarks Example: Restructured ADR Remarks 1 Government property mark MOD see Note 1 MOD see Notes 1 and 34 2 Mark number MK A11 MK A11 See Note 34 3 NATO stock number (NSN) 8120-99-000-0000 see Note 2 8120-99-000- XXXX 4 Test pressure TP 180 BAR PH180BAR 5 Date of test TD 4/89 V (month/year) 6 Design water capacity in litres WC 6.3 L see Note 17 2003/11 (Year/month) see Note 2 See Note 3 6,3L No WC symbol 7 Tare (mass of container T 9.5 KG and valve) see Note 4 TARE9,6KG No T symbol 8 Material identification CM see Note 12 see Note 12 9 Manufacturer s initials or XYZ LTD GB + XYZ LTD See Notes 31 trade mark and 32 10 Manufacturer s container serial number 98765 98765 11 Manufacturer s inspection stamp AB See Note 20 AB See Note 20 12 Independent inspection authority mark (where appropriate) 13 Refurbisher s approved stamp (where applicable) CD EF See Note 20 See Note 20. See Note 31 GB + CD EF 03/11 See Note 5 14 Date of Manufacture DoM 12/77 (Month/Year) DoM 2003/12 (Year/Month) 15 Manufacturer s Drawing ABC1 234 see Note 22 ABC1 234 see Note 22 or Part 16 Min Design thickness Not used 6,31MM See Note 29 Notes applicable to the tables are in SECTION 6. A typical pre-2003 stamping layout is shown in Figure 4. The Restructured ADR stamp marking requirements are summarised in Annex A. 30

SECTION 3 AIRBORNE CONTAINERS 15 MARKING COLOURS The container colour, stencilling colour(s), sector colour(s) and position(s) where appropriate, should be as specified in Table 15, or Table 16. The shoulder colours for containers since 2003 should be in accordance with BS EN 1089-3 (as specified in Table 15). Table 16 gives the container colour, shoulder or band colour(s) and position(s) that were used on Containers obtained prior to 2003 (to BS 349 standard), when next refurbished these containers should be re-marked in accordance with Table 15. 16 PRECAUTIONARY LABELS 16.1 General Precautionary labelling should be carried out using any suitable combination of labelling, marking and stencilling on the container as detailed in 16.3, 16.4 or 16.5, as appropriate for its intended application. Note: Airborne containers are subject to reconditioning intervals and procedures, as specified in Def Stan 81-121; this requires the stencilling/marking of additional data and the addition of 25 mm diameter coloured spots as detailed in 16.3, 16.4 or 16.5, as appropriate. 16.2 Symbol sizes For sizes of stencil/marking characters see Annex D. 31

SECTION 3 AIRBORNE CONTAINERS 16.3 Permanent gases The following table lists information and stencil/marking positioning required for permanent gases: Table 12: Stencilling/Marking Information Permanent Gases Item 1 Information position AT VALVE END (SHOULDER) Information required Abbreviation of gas name or chemical symbol 2 Charged pressure 3 4 5 6 7 8 9 10 Additional symbols Government property mark Name of gas (in full) Gas capacity in litres Hazard warning NATO stock number (NSN) Exclusion of use To indicate extension of reconditioning life 11 Date of Initial Charge of new Cylinder 12 Date of Reconditioning 13 Date of first charge after reconditioning 14 ON CYLINDRICAL SECTION LENGTHWISE Pre 2003 Example markings O 2 AV CP 152 BAR /2200 PSI 25mm black or white spot Example: Restructured ADR O 2 AV PW152BAR 25mm black or white spot Remarks See Note 8 See Table 15 or 16. see Note 14 see Note 19 MOD MOD see Note 1 OXYGEN-AV CAP 3620 L USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS OXYGEN-AV USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS see Note 8 see Note 13 6830-99-000-0000 6830-99-000-0000 see Note 6 FOR AIRBORNE USE ONLY 25mm Yellow Spot INIT CH 21/12/77 (Day/Month/Year) TD 21/12/77 (Day/Month/Year) CH 21/12/77 (Day/Month/Year) FOR AIRBORNE USE ONLY 25mm Yellow Spot INIT CH 2001/12/17 (Year/Month/Day) LAST TEST DATE 2001/12/21 (Year/Month/Day) CH 2001/12/17 (Year/Month/Day) To be removed when cylinder is reconditioned To be applied prior to putting the cylinder to its intended use. See Note 21 See Note 21 To be applied prior to putting the cylinder to its intended use after reconditioning. See Note 21 Additional symbols see Note 9 Notes applicable to the tables are in SECTION 6. 32

SECTION 3 AIRBORNE CONTAINERS 16.4 Liquefiable gases The following table lists information and stencil/marking positioning required for liquefiable gases, except padded gases (see 16.5): Table 13: Stencilling/Marking Information Liquefiable Gases (except padded gases) Item Information position Information required 1 AT VALVE END Abbreviation of (SHOULDER) gas name or chemical symbol Pre 2003 Example markings Example: Restructured ADR Remarks CO 2 CO 2 see Table 15 or 16 2 Additional 25mm black or 25mm black or see Note 19 symbols white spot white spot 3 ON Government MOD MOD see Note 1 CYLINDRICAL property mark 4 SECTION Name of gas (in CARBON CARBON LENGTHWISE full) DIOXIDE DIOXIDE 5 Tare (mass of container and T 9.5 KG / 21 LB TARE9,5 KG see Note 4 valve) 6 Filled mass FM 13.2 KG / 30 FM 13,2 KG see Note 15 LB 7 Max. Permissible Filling Weight Not Used 10KG CO2 See Note 26 8 NATO stock 6830-99-000-0000 6830-99-000-0000 see Note 6 number (NSN) 9 Exclusion of use FOR AIRBORNE FOR AIRBORNE USE ONLY USE ONLY 10 To indicate 25mm Yellow Spot 25mm Yellow Spot To be removed extension of when cylinder reconditioning life is reconditioned 11 Date of Initial Charge of new Cylinder 12 Date of Reconditioning INIT CH 21/12/77 (Day/Month/Year) TD 21/12/77 (Day/Month/Year) INIT CH 2001/12/17 (Year/Month/Day) LAST TEST DATE 2001/12/21 (Year/Month/Day) To be applied prior to putting the cylinder to its intended use. See Note 21 See Note 21 13 Date of first charge after reconditioning 14 Siphon tube marking CH 21/12/77 (Day/Month/Year) CH 2001/12/17 (Year/Month/Day) To be applied prior to putting the cylinder to its intended use after reconditioning. See Note 21 see Note 16 Notes applicable to the tables are in SECTION 6. 33

SECTION 3 AIRBORNE CONTAINERS 16.5 Liquefiable gases (padded) The following table lists information and stencil/marking positioning for liquefiable gases (padded): Table 14: Stencilling/Marking Information Liquefiable Gases (padded) Item Information position Information required 1 AT VALVE END Abbreviation of gas (SHOULDER) name or chemical symbol 2 Additional symbols 3 ON CYLINDRICAL Government SECTION property mark 4 LENGTHWISE Names of gases (in full) with controlling pressure and temperature Pre 2003 Example markings Example: Restructured ADR Remarks CO 2 /N 2 CO 2 /N 2 see Table 15 or 16 25mm black or white spot 25mm black or white spot see Note 19 MOD MOD see Note 1 CARBON DIOXIDE NITROGEN PADDED TO 100 BAR / 1450 PSI AT 20 C CARBON DIOXIDE NITROGEN PADDED TO 100 BAR AT 20 C see Note 14 5 Tare (mass of T 9.5 KG / 21 LB TARE9,5KG container and valve) see Note 4 6 Filled mass FM 13.5 KG /30 LB FM 13,2 KG see Note 15 7 Max. Permissible Filling Weight Not Used 10KG CO2 See Note 26 8 NATO stock 6830-99-000-0000 6830-99-000-0000 see Note 6 number (NSN) 9 Exclusion of use FOR AIRBORNE USE ONLY 10 Siphon tube marking 11 To indicate extension of reconditioning life 25mm Yellow Spot FOR AIRBORNE USE ONLY 25mm Yellow Spot see Note 16 To be removed when cylinder is reconditioned 12 Date of Initial Charge of new Cylinder 13 Date of Reconditioning INIT CH 21/12/77 (Day/Month/Year) TD 21/12/77 (Day/Month/Year) INIT CH 2003/12/17 (Year/Month/Day) LAST TEST DATE 2001/12/21 (Year/Month/Day) To be applied prior to putting the cylinder to its intended use. See note 21 See note 21 14 Date of first charge after reconditioning CH 21/12/77 (Day/Month/Year) CH 2003/12/17 (Year/Month/Day) To be applied prior to putting the cylinder to its intended use after reconditioning. See note 21 Notes applicable to the tables are in SECTION 6. 34

SECTION 3 AIRBORNE CONTAINERS Table 15: Gas Abbreviations with Container, Sector and Stencilling Colours for Airborne Containers (Restructured ADR: BS EN 1089-3 Requirements) Item Name of gas Abbreviation or chemical symbol Container colour RAL 840 HR Shoulder colour RAL 840 HR Stencilling colour Shoulder Cylindrical section Additional stencilling Cylindrical section 1 AIR AIR Dusty Grey 7037 Yellow green 6018 Black Black 2 AIR BREATHING AIR BREATHING Dusty Grey 7037 Black 90 White 90 Black 90 White 90 9005 9010 9005 9010 Dusty Grey Black 35 3 PURE AIR PURE AIR Dusty Grey 7037 Pure White 9010 Black Black 4 5 CARBON DIOXIDE * CARBON DIOXIDE NITROGEN PADDED * CO 2 Jet Black 9005 Dusty Grey 7037 White White CO 2 /N 2 Silver - Dusty Grey 7037 Black Black 6 NITROGEN N 2 Dusty Grey 7037 Jet Black 9005 White Black 7 HIGH PURITY NITROGEN 8 BREATHING OXYGEN NOTE 1: (*) See Note 18 at SECTION 6. N 2 Dusty Grey 7037 Jet Black 9005 White Black O 2 AV Jet Black 9005 Pure White 9010 Black White Two horizontal filled rectangles, black on white background DEF STAN 81-24/5

Table 16: Gas Abbreviations with Container, Sector and Stencilling Colours for Airborne Containers (Pre 2003: BS 349 Requirements) Item Name of gas Abbreviation or chemical symbol Container colour BS 381C Shoulder colour Stencilling colour Shoulder Cylindrical section 1 AIR AIR French grey 630 - Black Black Additional stencilling Cylindrical section DEF STAN 81-24/5 2 PURE AIR PURE AIR French grey 630 White Black Black 36 3 CARBON CO 2 Black - - White White DIOXIDE * 4 CARBON CO 2 /N 2 Silver - - Black Black DIOXIDE NITROGEN PADDED * 5 NITROGEN N 2 French grey 630 Black White Black 6 HIGH PURITY NITROGEN 7 BREATHING OXYGEN NOTE 1: (*) See Note 18 at SECTION 6. N 2 French grey 630 Black White Black O 2 AV Black - White Black White Two horizontal filled rectangles, black on white background NOTE 2: BS 381C colour numbers are listed in this table, not the RAL colour numbers called up by BS EN 1089-3. NOTE 3: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 36

SECTION 4 DIVING CONTAINERS 17 GENERAL REQUIREMENTS 17.1 Contractor owned containers Contractor owned transportable gas containers shall be stamp marked in accordance with the requirements of BS ISO 13769, labelled in accordance with the requirements of BS EN 1089-2 and colour-coded in accordance with the requirements of BS EN 1089-3. Note: Sub-clause 17.2 and Clauses 18, 19, 20 and 21 do not apply to Contractor owned containers. 17.2 MOD owned containers MOD owned transportable containers shall be stamp marked in accordance with Clause 18, colour coded in accordance with Clause 19, be fitted with a Next Test Date disc in accordance with Clause 20 and stencilled in accordance with Clause 21. In addition, a precautionary label in accordance with the requirements of BS EN 1089-2 and the Restructured ADR shall be firmly attached to the container. This label shall, as minimum, identify the contents with the appropriate coloured Hazard diamond with UN Number, Proper Shipping Name of the gas or mixture, and the UN Class Number. (See Annex B). 18 STAMP MARKING 18.1 General Stamp marking shall be applied in accordance with 18.2 or 18.3. 18.2 Aluminium alloy containers For aluminium alloy, stamp marking is to be applied on the container shoulder, as lightly as possible, consistent with producing a permanent record as shown on the stamp marking drawing. Existing containers may retain marking on the base of the container except that on reconditioning, retest data should be stamped on the container shoulder. 18.3 Steel containers For steel all stamp marking shall be applied on the thickened part of the shoulder as shown on the stamp marking drawing. 18.4 Size For sizes of stamped markings see 6.2. 18.5 Permanent gases Stamp marking shall be applied on the container shoulder unless a non-ferrous stamping ring is fitted. Certain diving containers will have stamp marking both on the shoulder and on a non-ferrous stamping ring. 37

SECTION 4 DIVING CONTAINERS Containers obtained prior to 2003 shall as a minimum comply with the pre- 2003 column of Table 17. Containers obtained since 1 st July 2003 already comply with either the BS EN 1089-1 or BS ISO 13769 requirements and shall be stamp marked with the information specified in the Restructured ADR column of Table 17: Table 17: Stamp marking Information Permanent Gases Item Information required Pre 2003 Example markings Remarks Example: Restructured ADR Remarks 1 Government property mark MOD see Note 1 MOD See Note 1 2 Design BS 5045/1/CM BSEN1964-1 specification/material construction code (*steel) 3 Drawing and issue No DP 1234 DP 2345 (*aluminium) 4 NATO stock number (NSN) 8120-99-000- see Note 2 8120-99-xxx-xxxx See Note 2 0000 5 Test pressure TP 310 BAR PH372BAR 6 Date of test TD 4/89 V (month/year) see Note 17 2001/11 V (year/month) See Notes 3 and 33 7 Manufacturer s initials or trade mark XYZ LTD GB + XYZ LTD See Notes 31 and 32 8 Manufacturer s container serial number 543210 876543 9 Manufacturer s inspection stamp AB AB 10 Mass of container shell M 35 KG 130KG No M symbol 11 Charged pressure CP 205 BAR see Note 14 PW205BAR see Note 23 12 Design gas chemical O 2 O 2 symbol 13 Climatic Area identification letter D see BS 5355 Not used Only for BS 5045 14 Independent inspection authority mark (where CD GB + CD See Note 31 appropriate) 15 Refurbisher s approved stamp (where applicable) As necessary. EF EF 03/11 See Note 5 16 Min Design thickness Not used 6,9MM See Note 29 17 Designated water Not used 50L capacity 18 NDT tested Not used UT See Note 24 19 Neck internal thread size Not used 25E 20 Notified Body Not used 1234 Identification 21 Pi mark, comply with Not used Π See Note 28 TPED 22 Min operating Not used -40 temperature 23 Steel Compatibility (*) Not used H See Note 25 24 UW Mark (*aluminium) Not used UW See Note 30 Notes applicable to the tables are in SECTION 6. Note: In this Table (*steel) refers only to steel containers, and (*aluminium) refers only to Aluminium Alloy Containers. A typical pre-2003 stamp marking layout drawing is shown in Figure 1. The ADR stamp marking requirements are summarised in Annex A. 38

SECTION 4 DIVING CONTAINERS 19 MARKING COLOURS For Containers obtained since 1 st July 2003, the container colour, shoulder or band colour(s) and position(s) where appropriate, shall be as specified in Table 19. The shoulder colour(s) and width of the band(s), if any, shall be in accordance with BS EN 1089-3. Table 20 specifies the container colour, shoulder or band colour(s) and position(s) that were used on Containers obtained prior to 2003 (to BS 349 standard). Some of these marking colours are not compliant with the requirements of BS EN 1089-3 and when next refurbished these containers shall be re-marked in accordance with Table 19. 20 REFERENCE TO NEXT TEST DATE The next test date (Year/Month, e.g. 2006/05) shall be clearly indicated on the container by means of stamping, engraving, a durable label, or a disc fitted between the valve and the container. To provide consistency between MOD owned containers and European Standards for period inspection and testing of transportable gas containers, the use of Next Test Date Discs is preferred, as specified in the, now withdrawn, BS 5430 series of standards and their ISO replacements. Where ever practicable, these discs should be incorporated during the next refurbishment cycle. (See Annex F). 21 STENCILLING REQUIREMENTS 21.1 General Precautionary labelling shall be provided by means of stencilling as detailed in 21.3 or 21.4, as appropriate. The container stencilling colour(s), where appropriate, shall be as specified in Table 19. 21.2 Size Stencil character sizes shall be as specified within Annex D. 39

SECTION 4 DIVING CONTAINERS 21.3 Permanent gases The following table lists information and stencil positioning required for permanent gases: Table 18: Stencilling information permanent gases Item Information position Information required Pre 2003 example markings Remarks Example: Restructured ADR Remarks 1 AT VALVE END Abbreviation of gas (SHOULDER) name or chemical symbol O 2 see Table 19 or 20 O 2 see Table 19 2 Charged pressure CP 205 BAR / 3000 PSI see Note 14 PW205BAR see Note 23 3 NATO stock number (NSN) 6830-99-000-0000 see Note 6 6830-99-000- XXX see Note 6 4 ON CYLINDRICAL Government property mark SECTION 5 LENGTHWISE Name of gas (in full) MOD OXYGEN see Note 1 MOD see Note 1 OXYGEN 6 Discharge instruction DO NOT DISCHARGE BELOW 7 BAR / 100 PSI DO NOT DISCHARGE BELOW 7 BAR 7 Hazard warning USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS 8 ON OPPOSITE END Date of test TD 4/89 V (month/year) see Note 17 2001/11 (Year/Month) see Notes 3, 5 & 33. Notes applicable to the tables are in SECTION 6 Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 40

SECTION 4 DIVING CONTAINERS 41 Table 19: Gas Abbreviations with Container, Band, Sector and Stencilling Colours for Diving Containers (Restructured ADR: BS EN 1089-3 Requirements) Item Name(s) of gas(es) Abbreviation or chemical symbol 1 AIR BREATHING AIR BREATHING Container Colour RAL 840 HR Colour of bands Width and position of bands Shoulder sector colours Dusty Grey 7037 - - Black 90 White 90 Black 90 White 90 2 OXYGEN O 2 Jet Black - - - Pure White 360 3 MIXTURE OXYGEN NITROGEN 32.5 % 67.5 % or OXYGEN NITROGEN 40 % 60 % or OXYGEN NITROGEN 60 % 40 % 4 MIXTURE OXYGEN HELIUM 16 % 84 % or OXYGEN HELIUM 20 % 80 % or OXYGEN HELIUM 40 % 60 % or OXYGEN HELIUM 50 % 50 % O 2 / N 2 32.5 % / 67.5 % O 2 / N 2 40 % / 60 % O 2 / N 2 60 % / 40 % O 2 / He 16 % / 84 % O 2 / He 20 % / 80 % O 2 / He 40 % / 60 % O 2 / He 50 % / 50 % Dusty Grey 7037 - - Black 90 White 90 Black 90 White 90 Black - - - Brown 90 White 90 Brown 90 White 90 RAL 840 HR 9005 9010 9005 9010 Shoulder Black on white White on black 9010 Black on white 9005 9010 9005 9010 8008 9010 8008 9010 Black on white White on black Stencilling colour Cylindrical section Black White Black Opposite end Black White Black Black White White NOTE 1. The width and position of the colour bands where appropriate shall comply with the painting and stencilling drawings available from the relevant Engineering Authority DEF STAN 81-24/5

SECTION 4 DIVING CONTAINERS Table 20: Gas Abbreviations with Container, Band, Sector and Stencilling Colours for Diving Containers (Pre 2003: BS 349 Requirements) Item Name(s) of gas(es) Abbreviation or chemical symbol Container Colour BS 381C Colour of bands Width and position of bands Shoulder sector colour BS Stencilling colour 381C Shoulder Cylindrical section Opposite end DEF STAN 81-24/5 1 AIR BREATHING AIR BREATHING French grey 630 - - Black 90 White 90 Black 90 White 90 - - - - Black on white White on black 2 OXYGEN O 2 Black - - - white 360 - Black on white White White 3 MIXTURE OXYGEN NITROGEN 32.5 % 67.5 % O 2 / N 2 32.5 % / 67.5 % French grey 630 Black 250 mm wide centre of parallel section of body Black 117 Grey 243-630 White on black Black on grey Black Black on grey White on black Black Black 42 4 MIXTURE OXYGEN NITROGEN 40 % 60 % 5 MIXTURE OXYGEN NITROGEN 60 % 40 % 6 MIXTURE OXYGEN HELIUM 16 % 84 % or OXYGEN HELIUM 20 % 80 % or OXYGEN HELIUM 40 % 60 % or OXYGEN HELIUM 50 % 50 % O 2 / N 2 40 % / 60 % O 2 / N 2 60 % / 40 % O 2 / He 16 % 84 % O 2 / He 20 % / 80 % O 2 / He 40 % / 60 % O 2 / He 50 % / 50 % French grey 630 Black 250 mm wide centre of parallel section of body French grey 630 Black 250 mm wide centre of parallel section of body Black 144 Grey 216 Black 216 Grey 144 Black - - - Brown 90 White 90 Brown 90 White 90-630 - 630 White on black Black on grey White on black Black on grey NOTE 1. The width and position of the colour bands where appropriate shall comply with the painting and stencilling drawings available from the relevant Engineering Authority. 411 411 - Black on grey White on black Black on grey White on black Black Black Black White White NOTE 2: BS 381C colour numbers listed in this table, not the RAL colour numbers called up by BS EN 1089-3, however the differences relate solely to shade of colour.

SECTION 4 DIVING CONTAINERS 21.4 Mixed gases (permanent) The following table lists information and stencil positioning required for mixed gases (permanent): Table 21: Stencilling information mixed gases (permanent) Item 1 2 3 4 5 6 7 8 Information position AT VALVE END (SHOULDER) ON CYLINDRICAL SECTION LENGTHWISE ON OPPOSITE END Information required Abbreviations of gas names or chemical symbols with percentage content Pre-2003 Example markings Remarks 16 % O 2 / 84 % He see Note 11 Charged pressure CP 205 BAR / 3000 PSI NATO stock number (NSN) Government property mark Name of gases (in full, with percentage content) Discharge instruction Hazard warning Date of test see Note 14 Example: Restructured ADR 16 % O 2 / 84 % He 6830-99-000-0000 see Note 6 6830-99-000-0000 Remarks see Note 11 PW205BAR see Note 23 see Note 6 MOD see Note 1 MOD see Note 1 OXYGEN / HELIUM MIXTURE 16% OXYGEN 84% HELIUM DO NOT DISCHARGE BELOW 7 BAR / 100 PSI USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS TD 4/89 V (month/year) see Note 11 see Note 17 OXYGEN / HELIUM MIXTURE 16% OXYGEN 84% HELIUM DO NOT DISCHARGE BELOW 7 BAR USE NO OIL OR GREASE THEY CAUSE EXPLOSIONS 2001/11 (Year/month) see Note 11 see Notes 3, 5 & 33. Notes applicable to the tables are in SECTION 6. Note 1: Containers marked in pre-2003 markings shall be converted, where ever possible, to the Restructured ADR markings during the next refurbishment cycle. 43

SECTION 4 DIVING CONTAINERS 22 TRANSIT CASES 22.1 Identification marking Each transit case shall, in addition to the NSN of the case, be stencilled with the following typical information, e.g.: TRANSIT CASE FOR 4250 litre LIGHT ALLOY STORAGE CONTAINER. GROSS WT WITH CONTAINER 57 KG. GROSS WT WITHOUT CONTAINER 22 KG. 22.2 Additional marking card A reversible card shall be attached, marked as follows: One side of the card shall be marked with: (a) (b) (c) The NSN of the filled container. The description of gas(es) contained. Also the words: COMPRESSED GAS. PRESSURE 205 BAR. The other side of the card shall be marked with: a. The words: DISCHARGED CONTAINER. HOLDING CHARGE 7 BAR. FOR (insert gas name(s) in full) b. The NSN of the gas(es). 22.3 Precautionary label A Class 2 Warning Diamond label with the appropriate Division, symbols, colours and general format for the filled container to be transported. The Proper Shipping Name of the gas and the corresponding UN number proceeded by the letters UN. (See Annex B). 44

SECTION 5 MEDICAL CONTAINERS 23 GENERAL REQUIREMENTS 23.1 Contractor owned containers Contractor owned transportable gas containers shall be stamp marked in accordance with the requirements of BS ISO 13769; labelled in accordance with the requirements of BS EN 1089-2 and colour-coded in accordance with the requirements of BS EN 1089-3. Note: All UK medical containers are now Contractor owned. 24 PRECAUTIONARY LABELS 24.1 Labelling Labelling shall be as detailed in 24.2 to 24.8, inclusively. 24.2 Type The label(s) is to be plastic affixed by adhesive (to be to specification BS 5609). The label colour shall be as indicated in 24.6. 24.3 Location The label(s) shall be affixed to the hemispherical portion of the container at the valve end (shoulder), opposite to the stencilled markings and where possible, in a position clear of all stamped markings. 24.4 Identification marking The following information shall be printed on all labels of medical gas containers: NEVER USE OIL OR GREASE USE ONLY MODERATE FORCE WHEN CLOSING VALVE BEFORE COUPLING CONTAINER REMOVE SEAL AND OPEN VALVE MOMENTARILY KEEP CONTAINER COOL (except for mixtures of O 2 + N 2 O) Product licence number FOR MEDICINAL USE ONLY 45

SECTION 5 MEDICAL CONTAINERS 24.5 Additional marking In addition to the requirements of 24.4 above, the following instructions shall be printed on the label for the particular gas(es): a. Nitrous oxide CONTENTS MAY BE DETERMINED ON THE BASIS 100 LITRES WEIGHS 0.1875 kg. TARE ON VALVE. KEEP IN A COOL PLACE NOT EXPOSED TO THE SUN OR ARTIFICIAL HEAT (to be printed in red to emphasise the warning). CONTAINER FILLING RATIOS IN ACCORDANCE WITH BS 5355. b. Carbon dioxide CONTENTS MAY BE DETERMINED ON THE BASIS 100 LITRES WEIGHS 0.1872 kg. TARE ON VALVE. c. Oxygen + Nitrous oxide (500 litres) DO NOT STORE IN OPEN. ALWAYS PROTECT FROM COLD. IMMEDIATELY BEFORE USE ENSURE THAT CONTAINER HAS BEEN ADEQUATELY WARMED AND THEN INVERT IT COMPLETELY THREE TIMES. d. Oxygen + Nitrous oxide (2000 and 5000 litres) DO NOT STORE IN OPEN. ALWAYS PROTECT FROM COLD. STORE HORIZONTALLY FOR 24 HOURS AT A TEMPERATURE ABOVE 10 C BEFORE USE. 46

SECTION 5 MEDICAL CONTAINERS 24.6 Label colours The label and printing colours for the following gas(es) shall be in accordance with RAL 840 HR. a. Oxygen: White label with black printing. b. Nitrous oxide: Blue label with white printing; with gas name in a white panel. Second label (see 24.5 (a)) shall be white with red and black printing and affixed immediately below the main label. c. Carbon dioxide: Grey label with black printing. d. Oxygen + Carbon dioxide: Grey label with black printing; with gas names in a white panel. e. Helium: Brown label with black printing. f. Oxygen + Helium: Brown label with white printing; with gas names in a white panel with brown printing. g. Air breathing: White label with orange printing. h. Oxygen + Nitrous oxide: Blue label with white printing; with gas names and percentages in a white panel with blue printing. 24.7 Batch labelling An additional label shall be required providing details of the batch, e.g.: day, month, year, shift and depot of filling. 24.8 Special medical gases Where special medical gases are used, the colours, labelling and stencilling of the containers shall be in accordance with the supplier s specification. 47

SECTION 6 FIVE NOTES APPLICABLE TO SECTIONS TWO, THREE, FOUR AND Note Description 1. The requirement for the Government property mark i.e. pheon or broad arrow,, is to be in accordance with Section C(4) of Def Stan 05-34. 2. The stamped NATO stock number, or service reference number, shall be marked on the shoulder close to the neck or on the non ferrous ring, except for acetylene containers, and shall be that of the bare container, i.e. unpainted and un valved but with collar, if fitted, and metallized where required. For Airborne containers also see Note 22. 3. The UN Model Regulations specify the date of the initial inspection shall be a fourdigit year code followed by a / and then a two-digit month code. 4. The stamped or stencilled tare is that of the empty container with its permanent fittings, e.g. collar, if fitted, metallized, painted and valved. 5. For Stamp Marking this shall consist of an inspection stamp and a date of periodic inspection, in the form of a two-digit year code followed by a / and then a two-digit month code. (See also Note 3). 6. The stencilled NATO stock number on the container shall be that number allocated for the container in its filled condition, i.e. complete with collar, if fitted, painted, and valved. 7. For containers for gases of special purity the gas name shall be marked as stated in the contract or other requisitioning document. 8. Airborne containers for breathing oxygen shall be marked by the inscription OXYGEN-AV and O 2 AV. Containers for compressed breathing air shall be marked by the inscription AIR BREATHING. 9. Airborne containers for breathing oxyge n shall be marked by the symbol of two horizontal filled rectangles, black on a white background (see Def Stan 05-18). 10. For containers filled with a charging pressure > 300 bar only. It is to be stencilled in red both sides; on a white band adjoining the shoulder. 11. Actual percentage figures (by volume) to be stencilled in. 12. Material identification letters, NCM, CM, Mn and C, shall be used for nickel chrome molybdenum, chrome molybdenum, manganese steels and carbon steel respectively. For existing aluminium alloy containers made from BS L 105, BS L 111, or BS 1474: HE 30 TF the material identification marks are to be L 105, L 111, or HE 30, respectively. NOTE: Some of these standards have been withdrawn, i.e. BS L 111 has been replaced by BS EN 2326, but still remains current. BS 1474 has been withdrawn and superseded and should not be invoked when procuring new containers. 48

SECTION 6 FIVE NOTES APPLICABLE TO SECTIONS TWO, THREE, FOUR AND 13. Gas capacity for airborne containers shall be calculated for the gas in question, i.e. not nominal. 14. This is the pressure, at 15 C (20 C for airborne containers) to which the container should be charged, and is to be adjusted for other temperatures in accordance with BS 5355. 15. The mass is for the container with collar, if fitted, metallized, painted, valved and filled. 16. The presence of a siphon tube fitted in a container shall be indicated by a line at least 12 mm wide in the designated stencilling colour painted on the container. A stencilled line along the length of the cylindrical section shall indicate a full-length dip tube. A gooseneck eductor tube shall be indicated by a stencilled line on the shoulder of the container. 17. After satisfactory completion of the periodic inspection and test, the suffix V, where applicable, shall be used to indicate visual examination only and shall be located after test date. Note: This requirement is only applicable to BS 5430, Part 1:1990, container designs whereby some containers, such as those used for self-contained underwater breathing apparatus, are required to be Visually Examined midway through the hydraulic test interval. 18. Carbon dioxide containers used for airborne life raft purposes may be painted white with black stencilling to minimise their heat absorption propensities. 19 Wire-wound airborne gaseous containers that used a non acid flux in the winding process, are to be marked by a 25mm white spot on the shoulder away from the other markings or where space allows. White painted containers are to be designated with a 25mm black spot. At the next reconditioning such containers are to be marked with a second spot close to the first. 20. If reconditioning is carried out by any organisation other than the manufacturer this marking will not be transferred when a brass collar is replaced. 21. Contractors undertaking reconditioning of containers shall: a. Remove, obliterate or otherwise cancel any yellow spot or date legend previously stencilled on containers. b. Re-mark any date of initial charge, date of reconditioning, date of first charge after reconditioning (if applicable) or green or white or black spots which are perforce removed or obliterated as part of the reconditioning process. 22. The contractor shall stamp the drawing or part number of the container. If there is insufficient space, the drawing or part number shall take precedence over the NATO stock number. 23. Settled Working Pressure, bar, at 15 C. 49

SECTION 6 FIVE NOTES APPLICABLE TO SECTIONS TWO, THREE, FOUR AND 24. NDT test codes are: UT = Ultrasonic test; MT = magnetic particle test; PT = dye penetrant test; AT = acoustic emission (see BS ISO 13769). 25. Steel containers and composite containers with steel liners intended to be used for hydrogen and other gases possessing a risk of hydrogen embrittlement (see BS EN ISO 11114-1, Groups 2 and 10) shall be stamp marked with an H denoting compatibility of the steel. HG is for high grade stainless steel containers or liners. 26. The Maximum Permissible Filling Weight is the product of the Water Capacity of the container and the filling ratio of the gas. If it is stamp marked on the container it shall be followed by the letters KG and the name or chemical formula of the gas. 27. The TARE weight is the sum of the Empty weight, the mass of the valve (and dip tube if fitted), valve guard, the paint and other permanently fitted parts. 28. Pi Marking of containers has been mandatory since July 2003. However TPED will not be fully implemented until 1 st July 2006, followed by a 24 month period, when all containers will have to be periodically inspected by a body approved by the Competent Authority (see Figure A.1). 29. This mark is not mandatory for composite containers or containers with a water capacity of one litre or less. 30. This is a mandatory requirement for composite containers. 31. The Country of Approval of the Inspection Body. Identified by using the motor vehicle International Identity Symbol, e.g. GB (see BS EN ISO 3166-1). 32. The stamp mark only needs to precede the Manufacturers identity stamp when the Country of Manufacture is different from the Country of Approval. 33. HSE, HID, Offshore Division, Diving Operations Strategy Team recommendations to the Diving Industry are that containers used in underwater breathing apparatus require a full internal visual inspection mid-way between the full-test interval (sometimes known as periodic inspection and test ). After satisfactory completion of the periodic inspection and test, the suffix V, where applicable, shall be used to indicate visual examination only and shall be located after test date. Note: this is not a requirement imposed of BS EN 1968:2002 (see also Note 17). 34. If there is insufficient space available on the collar to accommodate all required stamping this marking may be omitted. 50

SECTION 7 TYPICAL STAMP MARKING LAYOUTS Note: See Annex A for current Restructured ADR stamp marking requirements FIGURE 1: Pre-2003, typical stamp marking layout. Permanent gases containers for Ground and Diving use. 51

SECTION 7 TYPICAL STAMP MARKING LAYOUTS Note: See Annex A for current Restructured ADR stamp marking requirements FIGURE 2: Pre-2003, typical stamp marking layout. Liquifiable gases containers for Ground use. 52

SECTION 7 Typical stamp marking layouts Note: See Annex A for current Restructured ADR stamp marking requirements FIGURE 3: Pre-2003, typical stamp marking layout. Permanent gases containers for Airborne use. 53

SECTION 7 TYPICAL STAMP MARKING LAYOUTS Note: See Annex A for current Restructured ADR stamp marking requirements FIGURE 4: Pre-2003, typical stamp marking layout. Liquifiable gases containers for Airborne use 54

SECTION 8 ANNEXES A STAMP MARKING: RESTRUCTURED ADR A.1 Stamp Marks A.1.1 The UN Model Regulations and the Restructured ADR classify Stamp Markings into one of three named groups, i.e. Certification Marks, Operational Marks, and Manufacturing Marks, plus Other Marks. A.1.1 The Regulations require that the three named groups of markings be placed in group-sequence and sequence: with Manufacturing Marks placed in the top band nearest to the valve; Operational Marks are placed in the middle band; and, Certification Marks placed in the bottom band. (see also BS ISO 13769). A.1.2 Other Marks such as the date of the last periodic inspection, the inspection body, NATO stock numbers, etc, may be placed, other than the side walls, in low stress areas, provided they do not create harmful stress concentrations, and provided they do not conflict with the Manufacturing, Operational and Certification Marks. A.1.3 Manufacturing Marks include, in sequence: identification of the container thread; the Manufacturer s Mark; the serial number; and, the compatibility mark H, if applicable. A.1.4 Operational Marks include, in sequence: the test pressure, preceded by PH ; the empty mass, followed by KG ; the minimum guaranteed wall thickness followed by MM ; for liquefied gases, the water capacity in litres followed by L. A.1.5 Certification Marks include, in sequence: the UN Mark, the design standard, the Country of Approval, the initial inspection mark and the date of initial inspection. A.1.6 Other Markings include the date of the last periodic inspection, the inspection body, and various markings required by the owner, such as the MOD pheon, NATO stock numbers, etc. A.2 Pi Mark The approved style of the Pi mark is given in Figure A.1. 55

SECTION 8 ANNEXES Figure A.1: Pi Mark. 56