Section 1. Chemical Product and Company Identification Product Name: H2S Scavenger Version: 1 Effective Date: 2015/10/20 Supplier/ Chemfax Products Ltd. Manufacturer: 11444 42 Street SE Calgary, AB T2C 5C4 Tel: 403-287-2055 Material Uses Odour control/h2s Scavenger 24 Hour Emergency Canutec (613) 996-6666 WHMIS CLASIFICATION: D2B This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR HMIS Ratings for this product are: Health 1, Flammability 0, Reactivity 0 Section 2. Composition and Information on Ingredients Name CAS# % by weight 1,3,5-Triazine-1,3,5(2H,4H,6H)-triethanol 4719-04-4 30-60 Balance of ingredients are considered non hazardous and constitute a proprietary blend See Section 8 for information on permissible exposure limits and threshold limit values Section 3. Hazards Identification Physical State and Appearance Hazard Summary Routes of Exposure Liquid Irritating to eyes and skin. May cause allergic skin reaction. May be harmful if swallowed. Prolonged or repeated contact may dry skin and cause irritation. Do not breath vapour or mist. Do not ingest. Do not get on skin or clothing. Avoid contact with eyes. Use only with good ventilation. Wash thorough after handling. Dermal and eye contact. Inhalation. Chemfax Products Ltd. Page 1 of 6 October 20, 2015
Potential Acute Health Effects Medical Conditions Aggravated by Exposure See Toxicological Information Section 11 Additional Hazard Identification Remarks Skin: Irritating to skin. May cause severe irritations or burns. May cause sensitization by skin contact. Eyes: Irritating to eyes. May cause severe irritation or burns. Inhalation: Irritating to respiratory system. May cause severe irritation burns. Ingestion: May be harmful if swallowed. Irritating to mouth, throat and stomach. May cause severe irritation or burns. Pre-existing skin disorder and disorders involving gastrointestinal tract, eyes, lens or cornea may be aggravated by over-exposure to this product. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Notes to Physician Additional First Aid Remarks Flush eyes with water for 15 minutes. Seek medical attention. Immediately flush skin with running water. Remove and isolate contaminated clothing and shoes. Get medical attention if irritation develops and persists. Remove victim to fresh air. If there is difficulty breathing, seek immediate medical attention. If symptoms develop obtain medical attention or call POISON CONTROL CENTER. Do not induce vomiting unless directed to do so by medical personnel. If spontaneous vomiting occurs, keep head below hips to prevent aspiration of vomitus. Section 5. Fire Fighting Measures Flammability of the Product Flash Point Explosive Limits Auto Ignition Temperature In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of subsequent explosion. Not flammable and not combustible. 100 C (closed cup) Not available. Not available. Chemfax Products Ltd. Page 2 of 6 October 20, 2015
Static Discharge Suitable Extinguishing Media Hazardous Combustion Products Precautions for Fire Fighting Ground container during transfer of material. Use dry chemical, CO 2, water spray (fog) or foam. Carbon monoxide, Oxides of Nitrogen Fire fighters should wear self contained breathing apparatus and full protective clothing. Use water spray to cool containers and structures exposed to fire. Section 6. Accidental Release Measures Personal Precautions Environmental Precautions Methods for Clean Up No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Stop leak if without risk. Move containers from spill area. Absorb with an inert material. Use spark-proof tools and explosion-proof equipment. Dispose of via licensed waste disposal contractor. In case of larger spills approach release from upwind. Dike spill area and do not allow product to reach sewer system or ground water. Notify any reportable spill to authorities. Contain and collect spill with noncombustible material i.e. sand, earth, diatomaceous earth and place the container for disposal according to local regulations. Section 7. Handling and Storage Handling Put on appropriate personal protective equipment, i.e. respirator if area not ventilated, chemical resistant gloves, safety goggles, face shield, and protective clothing to cover skin. Eating, drinking and smoking is prohibited in areas where this material is handled and stored. Use only with adequate ventilation. Do not reuse empty container. Storage Store in accordance with local regulations. Store in segregated and approved area. Eliminate all sources of ignition. Store in dry, cool and well-ventilated area, away from oxidizing and reducing material and acids. Chemfax Products Ltd. Page 3 of 6 October 20, 2015
Section 8. Exposure Controls and Personal Protection Exposure Guidelines Triazine Exposure Controls Personal Protection Respiratory Skin Eyes TWA: 8 Hr STEL: 15 min Ceiling IDLH * - - - - Local exhaust ventilation If a risk assessment indicates it is necessary, use a properly fitted supplied air respirator complying with and approved standard. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Wear long sleeves and other protective clothing to prevent repeated or prolonged skin contact. Wear chemical safety goggles. When transferring material wear faceshield in addition to chemical safety goggles. Section 9. Physical and Chemical Properties Physical State and Appearance Clear liquid Odour Threshold Not available. ph 10.7 Boiling Point 99 C Melting Point / Freezing point < -20 C Evaporation Rate Not determined Vapour Density Not determined Vapour Pressure Not determined Relative Density 1.09 Solubility in Water Soluble % Volatile Not determined Other Data Section 10. Stability and Reactivity Chemical Stability The product is stable Hazardous Polymerisation Will not occur Conditions to Avoid Do not allow vapour to accumulate in low or confined area. Materials to Avoid Oxidizing and reducing agents and acids. Chemfax Products Ltd. Page 4 of 6 October 20, 2015
Hazardous Decomposition Products Under normal storage condition decomposition will not occur. Section 11. Toxicological Information Principle Routes of Exposure Skin: Eyes: Inhalation: Ingestion: Additional Information Acute Toxicity Can cause irritation. Can cause irritation and damage to eyes. May cause irritation of the upper respiratory tract. May be irritating to mouth, throat and stomach. No information available. Chronic Toxic Effects No information available. Carcinogenicity No information available. Section 12. Ecological Information Ecotoxicity Triazine: acute EC50 6.66 mg/l (green algae, 72 h); LC50 16.07 mg/l (fish, 96 h). BOD and COD Not available Biodegradability / OECD Not available Toxicity of the Products Not available of Biodegradation Special Remarks Section 13. Disposal Considerations Dispose of in accordance with local, provincial and federal regulations Section 14. Transport Information TDG Classification Emergency Response Guide # Marine Pollutant Special Precautions Not regulated under TDG. Not applicable No Chemfax Products Ltd. Page 5 of 6 October 20, 2015
Section 15. Regulatory Information Canada DSL Inventory TSCA WHMIS Hazard Class Additional Information All components of this product are either on the Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) or exempt All components of this product are either on the Toxic Substances Control Act (TSCA) Inventory List or exempt D2B Section 16. Other Information Prepared by: Chemfax Products Ltd., Technical Department Date Prepared: Revision Date: Disclaimer Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Chemfax Products Ltd. expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose with respect to the product provided. Chemfax Products Ltd. Page 6 of 6 October 20, 2015