Page 1 of 5 Section: 1 CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name: For Additional Product Information: Chemical Family: Water Rinseable CIC Remover Manufacturer: Spray Zip-Chem Products 400 Jarvis Drive Morgan Hill, CA 95037 4info@zipchem.com In Emergency: Section: 2 HAZARDS IDENTIFICATION 1 (408) 782-2335 1 (800) 424-9300 or Nationaal Vergiftigingen Informatie Centrum +31 (0) 30-2748888 (only for physicians) R 10 R 38 R 43 R 50/53 Flammable. Irritating to skin May cause sensitization by skin contact Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section: 3 COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS Preparation, containing the following hazardous ingredients Descriptive Name CAS Number Einecs/Elincs Percentage Range Symbols R-phrases Number Terpene Based Hydrocarbons 5989-27-5 227-813-5 35-40 Xi, N 10, 38, 43, 50/53 Dimethyl Ether propellant 115-10-6 204-065-8 40-45% F+ 12 Section: 4 FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION: May be an eye irritant. Flush immediately with water for 15 minutes and take to physician. Wash affected area and consult a physician if irritation persists. Call a physician and/or transport to emergency facility immediately. Do not induce vomiting so as to avoid aspiration of material into the lungs. Remove from exposure and restore breathing. Seek medical attention. Page 1 of 5 Approval date: 15-04-09 Printdate: 15-04-09
Page 2 of 5 Section: 5 FIRE AND EXPLOSION HAZARDS FLAMMABILITY DATA: FLAMMABLE/COMBUSTIBLE/PYROPHORIC: Combustible FLASH POINT OF PRODUCT: 57 C (PMCC on expelled product) FLASH POINT PROPELLANT -41 C AUTOIGNITION TEMPERATURE: Not established FLAMMABLE LIMITS AT NORMAL TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR): LEL: 1% UEL: 18% EXTINGUISHING MEDIA: Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog FIRE FIGHTING TECHNIQUES AND COMMENTS: Use standard firefighting techniques to fight fires involving this material Section: 6 ACCIDENTAL SPILL/RELEASE INFORMATION SPILL MITIGATION PROCEDURES: Stop source of spill as soon as possible and notify appropriate personnel. Burm around spill area to prevent spill from spreading. Ventilate area. Do not flush into sewers. AIR RELEASE: Vapors may be suppressed by use of water fog or spray. Contain all liquid for treatment or neutralization. WATER RELEASE: Dam water and contain for treatment. LAND SPILL: Create a trench to contain materials. Spilled materials may be contained using sand, clay, earth or a commercial absorbent. Do not place materials back in their original container. SPILL RESIDUES: Dispose of per guidelines under section 13, DISPOSAL CONSIDERATIONS. PERSONNEL PROTECTION FOR EMERGENCY SPILL AND FIRE FIGHTING SITUATIONS: Additional protective clothing must be worn to prevent personal contact with this material. Those items include but are not limited to gloves, apron, and safety glasses. Section: 7 HANDLING AND STORAGE DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES AND CLOTHING. UPON CONTACT WITH SKIN OR EYES WASH OFF WITH WATER. STORAGE CONDITIONS: Store in a cool, dry, well-ventilated place. STORE AT TEMPERATURES BETWEEN 10-30 C. DO NOT STORE OR USE NEAR HEAT, SPARKS, OR FLAMES. AVOID BREATHING VAPORS. VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS AND OTHER CONFINED AREAS. PRODUCT STABILITY AND COMPATIBILITY: SHELF LIFE LIMITATIONS: 36 months from date of shipment when stored at recommended storage conditions. INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: Strong Oxidizing Agents INCOMPATIBLE MATERIALS FOR PACKAGING: No common metal alloys known to be incompatible. Page 2 of 5 Approval date: 15-04-09 Printdate: 15-04-09
Page 3 of 5 Section: 8 PREVENTIVE MEASURES PERSONAL PROTECTION FOR ROUTINE USE OF THIS PRODUCT: RESPIRATORY PROTECTION: Not required for using this product. SKIN AND EYE PROTECTIVE EQUIPMENT: Butyl lined gloves are recommended to prevent skin contact. Chemical goggles to prevent eye contact are recommended. ENGINEERING CONTROLS VENTILATION: Local or mechanical to keep Section II ingredients below their exposure limits. EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE): RESPIRATOR TYPE: Not required PROTECTIVE CLOTHING TYPE: (This includes: gloves, boots, apron, protective suit): Butyl gloves, impervious apron, chemical goggles WASTE DISPOSAL: Spilled material collected in absorbent material should be transferred to steel disposal or recovery drums. If this product becomes a waste, it should be disposed of in accordance with local, state and federal regulations by incineration. Section: 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE(gas, liquid, solid): Liquid APPEARANCE: Amber liquid ODOR: Citrus odor FREEZING POINT: BOILING RANGE: DECOMPOSITION TEMPERATURE: SPECIFIC GRAVITY (H20=1): 0.74 (0.89 for the concentrate) DENSITY: 741 kg/m³ ph @ 25 Deg C: 9.0 VAPOR PRESSURE @ 25 C: SOLUBILITY IN WATER: Soluble EVAPORATION RATE: Slower than Ether VAPOR DENSITY: Heavier than air VOLATILE ORGANIC COMPOUND (VOC) G/L: 571 grams/liter (77 weight %) Section: 10 STABILITY AND REACTIVITY DATA CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE: No HAZARDOUS POLYMERIZATION: Will Not Occur INCOMPATIBLE MATERIALS: Strong Oxidizing Agents CONDITIONS OF REACTIVITY: None known HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, other combustion products of carbon. Page 3 of 5 Approval date: 15-04-09 Printdate: 15-04-09
Page 4 of 5 Section: 11 TOXICOLOGICAL PROPERTIES ROUTES OF ABSORPTION This product will not exert a significant adverse effect to health from any route of exposure. WARNING STATEMENTS AND WARNING PROPERTIES: DO NOT TAKE INTERNALLY. SIGNS, SYMPTOMS AND EFFECTS OF EXPOSURE INHALATION ACUTE: Irritation of nose and throat may occur from breathing high concentrations. CHRONIC Breathing extremely high concentrations of the vapors may lead to irritation of nose and throat. SKIN ACUTE: May cause irritation. CHRONIC: There are no known or reported effects from chronic exposure except for effects similar to those experienced from a single exposure EYE May cause irritation. INGESTION ACUTE: Ingestion of this product may cause irritation gastrointestinal discomfort consisting of nausea, vomiting, lethargy and/or diarrhea. CHRONIC: There are no known or reported effects from chronic exposure except for effects similar to those experienced from a single exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known. INTERACTIONS WITH OTHER CHEMICALS THAT ENHANCE TOXICITY: None known or reported. ACUTE TARGET ORGAN TOXICITY: No organs know to be damaged from exposure to this product. CHRONIC TARGET ORGAN TOXICITY: There are no known effects from repeated exposure. REPRODUCTIVE AND DEVELOPMENTAL TOXICITY: There are no known or reported effects on reproductive function or fetal development. CARCINOGENICITY: This product is not known to be carcinogenic MUTAGENICITY: This product is not known to be mutagenic. EXPOSURE LIMITS: Section: 12 ECOLOGICAL INFORMATION AQUATIC TOXICITY: Pure d-limonene is considered to be very toxic to aquatic organisms. Section: 13 DISPOSAL CONSIDERATIONS Spilled material collected in absorbent material should be transferred to steel disposal or recovery drums. If this product becomes a waste, it should be disposed of in accordance with local, state and federal regulations by incineration. Section: 14 TRANSPORT INFORMATION ADR Aerosols Class: 2 Page 4 of 5 Approval date: 15-04-09 Printdate: 15-04-09
Page 5 of 5 Classification Code 5 F Packing Group - IMO/IMDG Aerosols (maximum 1 litre) Class 2 Packing Group - EMS # F-D, S-U IATA Aerosols Flammable Class: 2.1 Packing Group: - Labelling Symbols Xi N Section: 15 REGULATORY INFORMATION Irrititant Dangerous for the environment R-phrases 10 Flammable 38 Irritating to skin. 43 May cause sensitization by skin contact. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrases 62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. 24 Avoid contact with skin. 37 Wear suitable gloves. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 60 This material and its container must be disposed of as hazardous waste. 61 Avoid release to the environment. Refer to special instructions / Safety data sheets. Section: 16 PREPARATION INFORMATION REVISION INFORMATION: Updated for compliance to REACH PREPARED BY: J. Smith This product safety data sheet conforms to EC Directive 1907/2006/EEC(REACH). This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Zip-Chem Products Company. The data in this sheet is related only to the specific material designated herein. Zip-Chem Products Company assumes no legal responsibility for use or reliance upon these data. Page 5 of 5 Approval date: 15-04-09 Printdate: 15-04-09