SAFETY DATA SHEET 1. Identification Product identifier Tapmatic Dual Action Plus #2 Cutting Fluid Other means of identification Part Number 40220, 40230, 40240, 40260 Recommended use A metal-cutting fluid safe for tapping, drilling, reaming, threading or finishing on aluminum. Recommended restrictions ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name LPS Laboratories, a division of Illinois Tool Works, Inc. Address 4647 Hugh Howell Rd. Tucker, GA 30084 Country (U.S.A.) Tel: +1 770-243-8800 In Case of Emergency 1-800-424-9300 (inside U.S.) +001 703-527-3887 (outside U.S.) Website www.lpslabs.com E-mail sds@lpslabs.com 2. Hazard(s) identification Physical hazards Flammable liquids Category 4 Health hazards Acute toxicity, oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B OSHA hazard(s) Label elements Aspiration hazard t classified. Category 1 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Danger H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H320 - Causes eye irritation. H227 - Combustible liquid. P210 - Keep away from flames and hot surfaces- smoking. P260 - Do not breathe mist or vapor. P270 - Do not eat, drink or smoke when using this product. P280 - Wear protective gloves/eye protection/face protection. P264 - Wash thoroughly after handling. P370 + P378 - In case of fire: Use appropriate media for extinction. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical advice/attention. P332 + P313 - If skin irritation occurs: Get medical advice/attention. P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 - Rinse mouth. P331 - Do NOT induce vomiting. P403 + P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/container in accordance with local/regional/national/international regulations. t classified. 1 / 6
Supplemental information ne known. 3. Composition/information on ingredients Mixtures Hazardous components Chemical name Distillates Petroleum, Hydroteated Light Benzyl Acetate CAS number % 64742-47-8 140-11-4 Other components below reportable levels 20 - < 30 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures 72.8 < 0.3 Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. Get medical attention if symptoms persist. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention immediately. Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. Provide general supportive measures and treat symptomatically. Symptoms of overexposure can include shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, and are reversible if exposure is stopped. In case of shortness of breath, give oxygen. Keep victim under observation. Suitable extinguishing media Dry chemical powder. Water spray. Water fog. Foam. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Do not use water jet as an extinguisher, as this will spread the fire. Combustible. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Use standard firefighting procedures and consider the hazards of other involved materials. Cool containers exposed to heat with water spray and remove container, if no risk is involved. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. In the event of fire and/or explosion do not breathe fumes. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Move container from fire area if it can be done without risk. Use standard firefighting procedures and consider the hazards of other involved materials. Local authorities should be advised if significant spillages cannot be contained. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Do not touch or walk through spilled material. Wear appropriate protective equipment and clothing during clean-up. Avoid skin contact and inhalation of vapors during disposal of spills. Ensure adequate ventilation. 2 / 6
Methods and materials for containment and cleaning up ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). The product is immiscible with water and will spread on the water surface. Environmental precautions 7. Handling and storage Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Precautions for safe handling DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. All equipment used when handling the product must be grounded. Do not breathe vapor. Avoid contact with skin and eyes. Avoid prolonged exposure. Do not get this material on clothing. Use only in well-ventilated areas. Wear personal protective equipment. Wash thoroughly after handling. Avoid release to the environment. Do not empty into drains. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Benzyl Acetate (CAS 140-11-4) Do not handle or store near an open flame, heat or other sources of ignition. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Use care in handling/storage. Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type Distillate s Petroleum, Hydroteate d Light (CAS 64742-47-8) Biological limit values Appropriate engineering controls REL Value 10 ppm Value biological exposure limits noted for the ingredient(s). 100 mg/m3 Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Avoid contact with eyes. Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended. Chemical resistant gloves are recommended. Do not get this material in contact with skin. Wear suitable gloves and eye/face protection. Chemical resistant gloves. personal respiratory protective equipment normally required. Avoid breathing dust/fume/gas/mist/vapors/spray. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph When using do not smoke. Do not get in eyes. Avoid contact with skin. Wash hands after handling. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice. Liquid. Liquid. Liquid. Amber Mild. Oily. t established t applicable 3 / 6
Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) t established ~195 C (383 F) > 165.20 F (> 74.00 C) Tag Closed Cup < 0.1 BuAc t applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) 0.6 % 7 % Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure < 0.05 mm Hg @ 20 C Vapor density > 1 (air = 1) Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Heat of combustion t soluble > 1 > 442.4 F (> 228 C) t established t established t established Percent volatile 70-75 % Specific gravity 0.83-0.85 (water = 1) VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity 0 % per State and Federal Consumer Product Regulations Strong oxidizing agents. Material is stable under normal conditions. Hazardous polymerization does not occur. Heat, flames and sparks. Avoid temperatures exceeding the flash point. Strong oxidizing agents. At thermal decomposition temperatures, carbon monoxide and carbon dioxide. May be harmful if swallowed. May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Causes skin irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Causes eye irritation. Irritating to eyes, respiratory system and skin. Defatting of the skin. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Harmful if swallowed. Causes skin irritation. Defatting, drying and cracking of skin. Causes eye irritation. Based on available data, the classification criteria are not met. Irritating to skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. 4 / 6
Carcinogenicity t classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Benzyl Acetate (CAS 140-11-4) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Ecotoxicity 3 t classifiable as to carcinogenicity to humans. Based on available data, the classification criteria are not met. Eyes. May cause irritation to the respiratory system. Narcotic effects. Skin. Lungs. Respiratory system. Central nervous system. May be fatal if swallowed and enters airways. Prolonged or repeated contact may cause drying, cracking, or irritation. Prolonged inhalation may be harmful. Symptoms may be delayed. Persistence and degradability t inherently biodegradable. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Tapmatic Dual Action Plus #2 Cutting Fluid > 1 Benzyl Acetate 1.96 Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information Dispose of contents/container in accordance with local/regional/national/international regulations. t assigned. DOT t regulated as a hazardous material by DOT. IATA t regulated as a dangerous good. IMDG t regulated as a dangerous good. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. information available. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) t on regulatory list. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - 5 / 6
SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number t listed. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) DEA Exempt Chemical Mixtures Code Number Food and Drug Administration (FDA) US state regulations US. Massachusetts RTK - Substance List Distillates Petroleum, Hydroteated Light (CAS 64742-47-8) US. New Jersey Worker and Community Right-to-Know Act Distillates Petroleum, Hydroteated Light (CAS 64742-47-8) US. Pennsylvania RTK - Hazardous Substances Distillates Petroleum, Hydroteated Light (CAS 64742-47-8) US. Rhode Island RTK Distillates Petroleum, Hydroteated Light (CAS 64742-47-8) US. California Proposition 65 10000 LBS US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance t listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s) 16. Other information, including date of preparation or last revision Issue date 01-24-2013 Version # 01 Further information Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. 6 / 6