Material Safety Data Sheet Revision Number: 001.0 Issue date: 10/14/2011 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product use: Company address: Henkel Electronic Materials LLC 14000 Jamboree Road Irvine, CA 92606 LOCTITE ABLESTIK 104 PTB known as ECCOBOND 104 PTB 3LB 14.5 OZ GA Adhesive Region: Canada Contact information: Telephone: 1.888.9.HENKEL (1.888.943.6535) MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Solid, Powder WHMIS hazard class: D.2.A, D.2.B Color: White Odor: Mild WARNING: Relevant routes of exposure: INHALATION OF DUST MAY CAUSE LUNG DAMAGE. INHALATION OF DUST CAN CAUSE CANCER. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Chronic exposure to dust containing quartz silica in excess of exposure limits can cause silicosis and can also increase the risks of developing respiratory cancer. Dusts of this product may cause irritation of the nose, throat, and respiratory tract. May cause allergic skin reaction. May cause moderate skin irritation. Rash. Redness. May cause irritation. Pain and discomfort. Redness. Not expected under normal conditions of use. Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Mica 12001-26-2 30-60 Benzene-1,2:4,5-tetracarboxylic dianhydride 89-32-7 30-60 Benzene-1,2,4,5-tetracarboxylic acid 89-05-4 1-5 Quartz (SiO2) 14808-60-7 0.1-1 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Page 1 of 5
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Never give anything by mouth to an unconscious person. If individual is conscious, wash out mouth with water. If symptoms develop and persist, get medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Sensitivity to Mechanical Impact: Sensitivity to static discharge: Product is a solid. Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Use water spray to keep fire exposed containers cool and disperse vapors. If mixed with air in sufficient amounts and proportions, organic dusts can form flammable or explosive dust/air mixtures. Oxides of carbon. Oxides of nitrogen. Irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Sweep up spilled material and place in a closed container for disposal. Avoid creating dust. 7. HANDLING AND STORAGE Handling: Storage: Avoid breathing dust. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Avoid any condition that will suspend or float powder particles in the air creating a dust cloud. Reduce all potential of static electrical discharge through bonding and grounding. Store in tightly closed containers to prevent moisture contamination. Keep away from heat, spark and flame. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 2 of 5
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Mica 3 mg/m3 TWA Respirable fraction. 20 MPPCF TWA Benzene-1,2:4,5-tetracarboxylic dianhydride Benzene-1,2,4,5-tetracarboxylic acid 2.4 MPPCF TWA Respirable. Quartz (SiO2) 0.3 mg/m3 TWA Total dust. 0.025 mg/m3 TWA 0.1 mg/m3 TWA Respirable fraction. Respirable. Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Special ventilation procedures may be required to avoid explosion hazards if dust situation exists. Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists. Safety goggles or safety glasses with side shields. Chemical resistant, impermeable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid, Powder Color: White Odor: Mild Odor threshold: ph: Vapor pressure: < 0.1 mm hg Boiling point/range: Melting point/ range: Specific gravity: 1.6 Vapor density: Flash point: Product is a solid. Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Insoluble Partition coefficient (n-octanol/water): VOC content: Negligible 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable under recommended storage conditions. Will not occur. under normal use. Oxidizing agents. Acids. Bases. Alkali metals. Ammonia. Reducing agents. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Avoid static discharge. Avoid dust formation. High concentration of airborne dust may form explosive mixture with air. 11. TOXICOLOGICAL INFORMATION Toxicologically synergistic products: Page 3 of 5
Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) ACGIH Carcinogen Mica No No No No Benzene-1,2:4,5-tetracarboxylic dianhydride No No No No Benzene-1,2,4,5-tetracarboxylic acid No No No No Quartz (SiO2) Known carcinogen. Group 1 No Group A2 Hazardous components LD50s and LC50s Health Effects/Target Organs Mica Lung Benzene-1,2:4,5-tetracarboxylic dianhydride Oral LD50 (RAT) = 2,250 mg/kg Irritant, Respiratory, Allergen Benzene-1,2,4,5-tetracarboxylic acid No Data Quartz (SiO2) Immune system, Lung, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. 14. TRANSPORT INFORMATION The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging as exceptions may apply. Refer to shipping documents for package specific transportation classification. Canada Transportation of Dangerous Goods - Ground International Air Transportation (ICAO/IATA) Water Transportation (IMO/IMDG) Page 4 of 5
15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: First issue. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and the MSDS contains all the information required by the CPR. Prepared by: Michele Oltra, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5