MATERIAL SAFETY DATA SHEET HARRY J. BOSWORTH COMPANY 7227 North Hamlin Avenue Skokie, Illinois 60076-3999 Information Phone: 847.679.3400 Emergency Phone: 800.535.5053 N F P A HAZARD RA TING 4 - EXTREME 3 - HIGH 2 - MODERATE 1 - SLIGHT 0 - INSIGNIFICANT Healt h Fi re Special React i vi t y PRODUCT: DATE PREPARED: 08/08/02 New Truliner Liquid Hazardous Components Physical/Chemical Characteristics INGREDIENTS: PERCENTAGE: BOILING POINT/FLASH POINT: ph: 1. Alkyl methacrylate monomer 2. Alkyl phthlate 3. Dimethy-p-toluidine 1. 2. 3. 760 mm Hg - 311 F (155 C) COMMON NAMES AND SYNONYMS: CAS NUMBER: SPECIFIC GRAVITY: (Water=1) VAPOR DENSITY: 1. Acrylic 2. Ester 3. Accelerator 1. 97-86-9 2. 84-74-2 3. 99-97-2 0.88 @ 20 C 4.91 @ 60 F (Air=1) PEL: UN NUMBER: VAPOR PRESSURE: EVAPORATION RATE: 1. ND 2. 5 mg/m 3 3. ND 1. UN 2283 2. 3. UN 2810 3 mm Hg @ 68 F (20 C).5 (Butyl Acetate=1) TLV: APPEARANCE/ODOR: SOLUBILITY IN WATER: 1. ND 2. 5 mg/m 3 3. ND Colorless liquid, characteristic acrylic odor. Reactivity Data Fire and Explosion Hazard Data STABILITY: FLASH POINT: LIMITS: Stable above 113 F TCC (45 C) LEL: 1.8 vol% UEL: 8.2 vol% EXTINGUISHING MEDIA: Avoid heat and ignited sources, storage in inert atmosphere, avoid contamination with foreign materials. Avoid reducing agents and oxidizing agents. Material has strong action and can soften paint and Chemical foam, carbon dioxide, dry chemical, water fog (by trained personnel) rubber. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and nitrogen smoke of various hydrocarbons. SPECIAL FIREFIGHTING PROCEDURES: Fight fires from safe distance or protected areas. Cool containers of material exposed to heat with cold water spray. Wear NIOSH approved breathing apparatus. HAZARDOUS POLYMERIZATION: May occur. UNUSUAL FIRE AND EXPLOSION HAZARDS: Sealed containers elevated to temperatures and any rupture due to polymerization. Liquid vapors are heavier than air and may travel to ignition source. Avoid excessive heat. Store in absence of inhibitor. Avoid inadvertent addition of catalyst. Strong oxidizing agents.
Health Hazard Data Emergency and First Aid Procedures CARCINOGENICITY: NTP: TREATMENT FOR EYE CONTACT: None of the components are listed as a carcinogen by NTP, IARC, OHSA. No evidence Immediately flush eyes with water, contact physician. IARC: OSHA REGULATED: TREATMENT FOR SKIN CONTACT: No evidence No Wash skin with soap and water. Effects and Hazards of Overexposure (Acute and Chronic) EFFECTS AND HAZARDS OF EYE CONTACT: Prolonged exposure may irritate or bury eyes TREATMENT FOR INHALATION (BREATHING): Move to fresh air. Administer oxygen or artificial respiration if needed, contact physician. TREATMENT FOR INGESTION (SWALLOWING): Induce vomiting and contact a physician. EFFECTS AND HAZARDS OF SKIN CONTACT: Prolonged exposure may irritate skin. EFFECTS AND HAZARDS OF INHALATION (BREATHING): High concentrations can cause nausea, headaches, drowsiness, breathing difficulties and unconsciousness. EFFECTS AND HAZARDS OF INGESTION (SWALLOWING): As above OTHER REGULATORY INFORMATION: California Proposition 65 Warning: This product may contain a chemical known to the state of California to cause cancer. Precautions for Safe Handling and Use STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Evacuate area, remove other materials to avoid contamination. Avoid contact, confine and remove with inert absorbent. WASTE DISPOSAL METHOD: Do not allow to drain into sewer system. Biological digestion can be considered. Abide local, state and federal laws of disposal. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers closed; store away from heat and direct sunlight, ignition sources. Allow air to exist in container. OTHER PRECAUTIONS: Ground containers when transferring liquid. Allow air space to exist inside storage containers. Control Measures RESPIRATORY PROTECTION: Use SCBA if levels exceed 100ppm Additional Information This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29CFR 1910.1200) and is to be used only for this product. The information contained in this sheet is, to the best of our knowledge, believed to be accurate Health Hazard Index: Ratings: Ventilation SEVERE HAZARD 1 LOCAL EXHAUST VENTILATION SERIOUS HAZARD 2 To keep sufficient vapor concentration under 100 ppm per 8 hours MODERATE HAZARD SPECIAL VENTILATION: SLIGHT HAZARD 4 None MINIMUM HAZARD 5 MECHANICAL (GENERAL) VENTILATION: None OTHER VENTILATION: None needed PROTECTION GLOVES: Neoprene gloves EYE PROTECTION: 3 Safety goggles OTHER PROTECTIVE EQUIPMENT: UN 2283 Eyewash, safety shower. Overshoes and coveralls WORK AND HYGIENIC PRACTICES: Wash hands before eating and smoking REGULATED IATA: PROPER SHIPPING NAME: Isobutul Methacrylate HAZARD CLASS: IDENTIFICATION NUMBER: PACKAGING GROUP: III LABEL: Flammable liquid Shipping Information To the best of our knowledge, the information contained herein is accurate. However, The Harry J. Bosworth company does not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. New Truliner Liquid MSDS 976 3
PRODUCT: DATE PREPARED: 10/01/04 New Truliner Powder Pink/Vein/Clear Hazardous Components Physical/Chemical Characteristics INGREDIENTS: PERCENTAGE: BOILING POINT/FLASH POINT: MELTING POINT 1. Nuisance, dust 5.) TiO 2 1. 5. N/D 2. Organic Peroxide 2. 3. Residual Monomer 4. Cadmium Pigment(not in case of clear) 3. 4. COMMON NAMES AND SYNONYMS: CAS NUMBER: SPECIFIC GRAVITY: (H 2O=1) VAPOR DENSITY 1. Polyethyl methacrylate 1. N/D 5. 13453-67-7 1.25 @ 20 C (Air = 1) 2. Benzoyl Peroxide 5. Titanium-dioxide 2. 94-36-0 3. Cadmium Pigments(not in clear) 3. 7440-43-9 4. Residual Monomer 4. N/D PEL: UN NUMBER: VAPOR PRESSURE: EVAPORATION RATE: 1. 15 mg/m 3 1. (Butyl Acetate = 1) 2. 5 mg/m 3 5. 2. 3102 5. 3. 0.02 mg/m 3 3. 4. 0.05 mg/m 3 4. TLV: APPEARANCE/ODOR: SOLUBILITY IN WATER: 1. 10 mg/m 3 2. 5 mg/m 3 5. 10 mg/m 3 3. 0.05 mg/m 3 4. Fine pink/vein/clear powder with faint odor when in bulk. Insoluble Reactivity Data Fire and Explosion Hazard Data STABILITY: FLASH POINT: LIMITS: Stable 304 C LEL: UEL: EXTINGUISHING MEDIA: Heating over 300 C Water, carbon dioxide, dry chemical HAZARDOUS DECOMPOSITION PRODUCTS: Methyl methacrylate monomers and oxides of carbon HAZARDOUS POLYMERIZATION: Will not occur SPECIAL FIREFIGHTING PROCEDURES: Avoid extinguishing methods which may generate dust clouds. Water stream can disperse dust into air, producing a fire hazard and possible explosion hazard if exposed to ignition source. UNUSUAL FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer particles suspended in air are approximately those of coal dust. Fire fighters should wear self-contained breathing apparatus. Health Hazard Data Emergency and First Aid Procedures CARCINOGENICITY: NTP: TREATMENT FOR EYE CONTACT: California Proposition 65 Warning: This product may contain a chemical known to the state of Immediately flush eyes with water, contact physician. California to cause cancer and/or birth defects. IARC: OSHA REGULATED: TREATMENT FOR SKIN CONTACT: No evidence No Wash skin with soap and water. Effects and Hazards of Overexposure (Acute and Chronic) EFFECTS AND HAZARDS OF EYE CONTACT: TREATMENT FOR INHALATION (BREATHING): Move to fresh air. TREATMENT FOR INGESTION (SWALLOWING):
May be irritated by gross overexposure Rinse mouth out with water. EFFECTS AND HAZARDS OF SKIN CONTACT: May be irritated by gross overexposure EFFECTS AND HAZARDS OF INHALATION (BREATHING): N/D Precautions for Safe Handling and Use STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep up with sweeping compound. Avoid dusting. EFFECTS AND HAZARDS OF INGESTION (SWALLOWING): Call physician WASTE DISPOSAL METHOD: May be disposed of in landfill or incinerated. Follow Federal, state and local regulations for disposal. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Handle with care. Store in cool, dry place. Keep container closed to prevent water absorption and contamination. OTHER PRECAUTIONS: This product is for professional use only as stated in directions. It is the responsibility of the dentist to train personnel. Control Measures RESPIRATORY PROTECTION: Use type for particulates not otherwise classified, if needed. Additional Information This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29CFR 1910.1200) and is to be used only for this product. The information contained in this sheet is, to the best of our knowledge, believed to be accurate Health Hazard Index: Ratings: Ventilation SEVERE HAZARD 1 LOCAL EXHAUST VENTILATION SERIOUS HAZARD 2 Use if necessary. MODERATE HAZARD SPECIAL VENTILATION: SLIGHT HAZARD 3 4 Use if necessary. MINIMUM HAZARD 5 MECHANICAL (GENERAL) VENTILATION: Use if necessary. OTHER VENTILATION: Open window if necessary PROTECTION GLOVES: Impervious gloves EYE PROTECTION: Safety glasses OTHER PROTECTIVE EQUIPMENT: WORK AND HYGIENIC PRACTICES: Wash hands before eating and smoking REGULATED IATA: PROPER SHIPPING NAME: HAZARD CLASS: NONE IDENTIFICATION NUMBER: PACKAGING GROUP: LABEL: Shipping Information
PRODUCT: DATE PREPARED: 12/05/00 Bonding Liquid Hazardous Components Physical/Chemical Characteristics INGREDIENTS: PERCENTAGE: BOILING POINT/FLASH POINT: MELTING POINT: Methyl Methacrylate 101 C (214 F) @760 mg/hg COMMON NAMES AND SYNONYMS: CAS NUMBER: Specific Gravity: (Water=1) VAPOR DENSITY: Methacrylic Acid, Methyl Ester 80-62-6 0.944 @ 68 F 3.6 (Air=1) PEL: UN NUMBER: VAPOR PRESSURE: EVAPORATION RATE: 100 ppm UN 1247 28 mm/hg @ 68 F (20 C) 3 (Butyl Acetate=1) TLV: APPEARANCE/ODOR: SOLUBILITY IN WATER: 100 ppm Colorless Liquid Acrid Acrylic Odor. 1.6 WT% @20 C Reactivity Data Fire and Explosion Hazard Data STABILITY: FLASH POINT: LIMITS: Stable except when heated 10 C (50 F) LEL: 2.1 vol% UEL: 12.5 vol% EXTINGUISHING MEDIA: Avoid heat and ignition source, storage in inert atmosphere, contamination with foreign materials. Foam, dry chemical and CO 2 HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and smoke. Can soften paint and rubber. HAZARDOUS POLYMERIZATION: May occur. SPECIAL FIREFIGHTING PROCEDURES: Keep personnel removed and upwind of fire. Wear self-contained breathing apparatus and full protective equipment. Cool container with water spray. Fight fire from distance, heat may rupture containers. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are uninhibited and may form polymers in vents or flame arrestors resulting in stoppage of vents. Avoid excessive heat, storage in absence of inhibitor and inadverent addition of catalyst. Avoid oxidizing and reducing agents. Health Hazard Data Emergency and First Aid Procedures CARCINOGENICITY: NTP: TREATMENT FOR EYE CONTACT: Flush eyes with penty of water. Call a physician if necessary. IARC: OSHA REGULATED: TREATMENT FOR SKIN CONTACT: Wash skin with soap and water. Seek medical attention if irritation perists. Effects and Hazards of Overexposure (Acute and Chronic) TREATMENT FOR INHALATION (BREATHING): Remove person to fresh air. Give artificial respiration or oxygen if neessary. Call physician
EFFECTS AND HAZARDS OF EYE CONTACT: Irritation, Cornea injury EFFECTS AND HAZARDS OF SKIN CONTACT: Irritation, potential skin sensitizes. EFFECTS AND HAZARDS OF INHALATION (BREATHING): Eye, nose and throat irritation, Headache, dizziness. EFFECTS AND HAZARDS OF INGESTION (SWALLOWING): As above for inhalation. TREATMENT FOR INGESTION (SWALLOWING): Do not induce vomiting. Drink water. Do not give anything if person is unconscious. Call physician. Precautions for Safe Handling and Use STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove personnel, source of fire, ventilate area. Wear self-contained breathing appaaratus, soak u spill with absorbent material. WASTE DISPOSAL METHOD: Must be disposed in accordance with applicable Federal, State/provincial and local regulations. Material should not be allowed to drain into sewers PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in cool place, away from sunlight and heat. Maintain air space inside container. Keep container tightly closed. OTHER PRECAUTIONS: This product is for professional use only as stated in directions. It is the responsibility of the dentist to train personnel. Control Measures RESPIRATORY PROTECTION: A NIOSH/MSDA approved air purifying respirator with an organic vapor cartridge or canister may be used. Additional Information This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29CFR 1910.1200) and is to be used only for this product. The information contained in this sheet is, to the best of our knowledge, believed to be accurate Health Hazard Index: Ratings: Ventilation SEVERE HAZARD 1 LOCAL EXHAUST VENTILATION SERIOUS HAZARD 2 Keep sufficient vapor conc. Under 100 ppm/8hp MODERATE HAZARD SPECIAL VENTILATION: SLIGHT HAZARD 4 None MINIMUM HAZARD 5 MECHANICAL (GENERAL) VENTILATION: None OTHER VENTILATION: None PROTECTION GLOVES: REGULATED IATA: PROPER SHIPPING NAME: Shipping Information Methyl Methacrylate Monomer - Inhibited Nitrile or neoprene impervious gloves. HAZARD CLASS: EYE PROTECTION: 3 Safety glasses IDENTIFICATION NUMBER: OTHER PROTECTIVE EQUIPMENT: UN 1247 Apron, coat, eye wash WORK AND HYGIENIC PRACTICES: Wash hands before eating and smoking PACKAGING GROUP: II LABEL: Flammable Liquid 3