OCIMENE PQ Page 1 Issued: 13/09/02 Revision No: 9 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: OCIMENE PQ CAS number: 13877-91-3 EINECS number: 237-641-2 Product code: 32176 Company name: Innospec Widnes Limited Dans Road Widnes Cheshire WA8 0RF Tel: 0151 423 8000 Fax: 0151 423 8127 Emergency tel: +44 (0)151 424 5018 2. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: OCIMENE 70-90% EINECS: 237-641-2 CAS: 13877-91-3 [-] R10; [Xn] R22; [Xi] R38; [Xn] R65 LIMONENE 10-30% EINECS: 205-341-0 CAS: 138-86-3 [-] R10; [Xi] R38; [Sens.] R43; [N] R50/53 3. HAZARDS IDENTIFICATION Main hazards: Other hazards: Harmful if swallowed. Irritating to skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Combustible. 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: Eye contact: Ingestion: Inhalation: There may be irritation and redness at the site of contact. An itchy rash may occur at the site of contact. There may be irritation and redness. There may be irritation of the throat. Nausea and stomach pain may occur. There may be vomiting. Inhalation of fumes from the stomach may cause symptoms similar to direct inhalation. There may be irritation of the throat with a feeling of tightness in the chest. Drowsiness or mental confusion may occur. There may be loss of consciousness. There may be congestion of the lungs causing severe shortness of breath. Convulsions may occur.
OCIMENE PQ Page 2 4. FIRST AID MEASURES (ACTION) Skin contact: Eye contact: Ingestion: Inhalation: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning. Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination. Do not induce vomiting. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible. Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible. 5. FIRE-FIGHTING MEASURES Extinguishing media: Exposure hazards: Protection of fire-fighters: Carbon dioxide. Dry chemical powder. Alcohol resistant foam. Flammable. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Clean-up procedures: Eliminate all sources of ignition. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Do not discharge into drains or rivers. Contain the spillage using bunding. Mix with sand or vermiculite. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Take all measures to minimise contact with water. 7. HANDLING AND STORAGE Handling requirements: Storage conditions: Suitable packaging: Ensure there is sufficient ventilation of the area. Avoid direct contact with the substance. Earth any equipment used in handling. Store in cool, well ventilated area. Keep away from sources of ignition. Keep container tightly closed. Ensure lighting and electrical equipment are not a source of ignition. Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Respiratory protection: Hand protection: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Self-contained breathing apparatus must be available in case of emergency. Protective gloves.
OCIMENE PQ Page 3 Eye protection: Skin protection: Safety goggles. Ensure eye bath is to hand. Protective clothing with elasticated cuffs and closed neck. Boots made of PVC. Ensure safety shower is to hand. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Liquid Colour: Colourless Odour: Characteristic odour Evaporation rate: Negligible Solubility in water: Not miscible Also soluble in: Most organic solvents. Flash point C: 57 Vapour pressure: <1 mm Hg @ 20C Relative density: 0.808 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Haz. decomp. products: Stable under normal conditions. Heat. Sources of ignition. Oxidising agents. Acids. Bases. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. 11. TOXICOLOGICAL INFORMATION Acute toxicity: OCIMENE PQ ORL RAT LD50 5000 mg/kg Hazardous ingredients: OCIMENE ORL RAT LD50 5 g/kg LIMONENE ORL RAT LD50 5300 mg/kg Chronic toxicity: May cause sensitisation by skin contact. 12. ECOLOGICAL INFORMATION Mobility: Persistence and degradability: Bioaccumulative potential: Other adverse effects: Floats on water. No data available. No data available. Very toxic to aquatic organisms. 13. DISPOSAL CONSIDERATIONS Disposal operations: Disposal of packaging: D10 Incineration on land. R1 Solvent reclamation/regeneration. Arrange for collection by specialised disposal company.
OCIMENE PQ Page 4 NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 1993 ADR Class: 3 Shipping name: FLAMMABLE LIQUID, N.O.S. (ESSENTIALLY 3,7-DIMETHYLOCTA-1,3,6 TRIENE) Labelling: 3 Hazard ID no: 30 IMDG / IMO UN no: 1993 Class: 3 Packing group: III EmS: 3-07/ Marine pollutant:. Labelling: 3 IATA / ICAO UN no: 1993 Class: 3 Packing group: III Packing instructions: 310 Labelling: 3 15. REGULATORY INFORMATION Hazard symbols: Harmful. Dangerous for the environment. Risk phrases: Safety phrases: R22: Harmful if swallowed. R38: Irritating to skin. R43: May cause sensitisation by skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. S24: Avoid contact with skin. S36/37: Wear suitable protective clothing and gloves. S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S29: Do not empty into drains.
OCIMENE PQ Page 5 Precautionary phrases: Note: S57: Use appropriate container to avoid environmental contamination. S61: Avoid release to the environment. Refer to special instructions / safety data sheets. S60: This material and its container must be disposed of as hazardous waste. Contains Dipentene. May produce an allergic reaction. The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: Risk phrases used in s.2: Legal disclaimer: This product contains material listed in European Directive 2003/15/EC as an allergen. Use and label all your products containing this material, to be used as fragrance/cosmetics products, as required by any applicable legislation and IFRA guidelines R10: Flammable. R22: Harmful if swallowed. R38: Irritating to skin. R65: Harmful: may cause lung damage if swallowed. R43: May cause sensitisation by skin contact. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]