Conforms to HCS 2012 - United States SAFETY DATA SHEET R Heavy Duty Metal Protector Section 1. Identification Date Version 07/15/2016 6 GHS product identifier Code Product type Heavy Duty Metal Protector Aerosol. Identified uses Corrosion inhibitor. Supplier's details AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel +1 715-392-7101 Emergency telephone number (with hours of operation) CHEMTREC Within USA and Canada 1-800-424-9300 Outside USA and Canada +1 703-741-5970 (collect calls accepted) (24/7) Section 2. Hazards identification OSHA/HCS status Classification of the substance or mixture This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Liquefied gas SKIN IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 3 GHS label elements Hazard pictograms Signal word Hazard statements Danger Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. 1/12 Date of issue 07/15/2016
Precautionary statements Prevention Response Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Avoid breathing vapor. Wash hands thoroughly after handling. Pressurized container Do not pierce or burn, even after use. IF INHALED Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs Get medical attention. Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. Store in a well-ventilated place. Disposal Hazards not otherwise classified Dispose of contents and container in accordance with all local, regional, national and international regulations. None known. Section 3. Composition/information on ingredients Substance/mixture Other means of identification Mixture Not available. CAS number/other identifiers CAS number Product code United States Not applicable. Ingredient name CAS number Hydrogenated Base Oil (64742-47-8) 25-40 64742-47-8 Hydrogenated Base Oil (64742-49-0) 15-25 64742-49-0 Hydrogenated Base Oil (64742-52-5) 1-5 64742-52-5 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. % Section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. 2/12 Date of issue 07/15/2016
Inhalation Skin contact Ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention if symptoms occur. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Inhalation Skin contact Ingestion Over-exposure signs/symptoms Eye contact Inhalation Skin contact Ingestion Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Causes skin irritation. No known significant effects or critical hazards. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Adverse symptoms may include the following pain or irritation watering redness Adverse symptoms may include the following respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following irritation redness Adverse symptoms may include the following nausea or vomiting Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Specific treatments Protection of first-aiders Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. No specific treatment. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) 3/12 Date of issue 07/15/2016
Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. None known. Specific hazards arising from the chemical Hazardous thermal decomposition products Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Decomposition products may include the following materials carbon dioxide carbon monoxide Special protective actions for fire-fighters Special protective equipment for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. 4/12 Date of issue 07/15/2016
Methods and materials for containment and cleaning up Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Put on appropriate personal protective equipment (see Section 8). Pressurized container protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Hydrogenated Base Oil (64742-47-8) ACGIH TLV (United States, 3/2015). Absorbed through skin. TWA 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Hydrogenated Base Oil (64742-49-0) None. Hydrogenated Base Oil (64742-52-5) ACGIH TLV (United States, 3/2015). TWA 5 mg/m³ 8 hours. Form Inhalable fraction NIOSH REL (United States, 10/2013). TWA 5 mg/m³ 10 hours. Form Mist STEL 10 mg/m³ 15 minutes. Form Mist OSHA PEL (United States, 2/2013). TWA 5 mg/m³ 8 hours. 5/12 Date of issue 07/15/2016
Appropriate engineering controls Environmental exposure controls Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Individual protection measures Hygiene measures Eye/face protection Skin protection Hand protection Body protection Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold ph Melting point / Pour point Boiling point Flash point Evaporation rate Flammability (solid, gas) Liquid. [Aerosol.] Amber. Solvent. Not available. Not available. Not available. Not available. Not available. Not available. Not available. 6/12 Date of issue 07/15/2016
Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Partition coefficient n- octanol/water Auto-ignition temperature Decomposition temperature Viscosity Aerosol product Type of aerosol Heat of combustion Not available. Not available. Not available. Not available. Insoluble Not available. Not available. Not available. Not available. Spray 9.14 kj/g Section 10. Stability and reactivity Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical stability The product is stable. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Avoid all possible sources of ignition (spark or flame). Incompatible materials Reactive or incompatible with the following materials oxidizing materials. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Hydrogenated Base Oil (64742-52-5) LD50 Oral Rat >5000 mg/kg - Irritation/Corrosion Sensitization Mutagenicity 7/12 Date of issue 07/15/2016
Carcinogenicity Classification Product/ingredient name OSHA IARC NTP ACGIH EPA NIOSH Hydrogenated Base Oil (64742-47-8) - - - A3 - - Reproductive toxicity Teratogenicity Specific target organ toxicity (single exposure) Name Hydrogenated Base Oil (64742-49-0) Category 3 Not applicable. Narcotic effects Specific target organ toxicity (repeated exposure) Aspiration hazard Name Category Result Route of exposure Hydrogenated Base Oil (64742-47-8) ASPIRATION HAZARD - Category 1 Hydrogenated Base Oil (64742-49-0) ASPIRATION HAZARD - Category 1 Hydrogenated Base Oil (64742-52-5) ASPIRATION HAZARD - Category 1 Target organs Information on the likely routes of exposure Potential acute health effects Eye contact Inhalation Skin contact Ingestion Dermal contact. Eye contact. Inhalation. Ingestion. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Causes skin irritation. No known significant effects or critical hazards. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Symptoms related to the physical, chemical and toxicological characteristics Eye contact Inhalation Adverse symptoms may include the following pain or irritation watering redness Adverse symptoms may include the following respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness 8/12 Date of issue 07/15/2016
Skin contact Ingestion Adverse symptoms may include the following irritation redness Adverse symptoms may include the following nausea or vomiting Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects Potential chronic health effects General No known significant effects or critical hazards. Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure Hydrogenated Base Oil (64742-47-8) Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Persistence and degradability Bioaccumulative potential Product/ingredient name LogPow BCF Potential Hydrogenated Base Oil (64742-49-0) 2.2 to 5.2 10 to 2500 high Mobility in soil Soil/water partition coefficient (KOC) 9/12 Date of issue 07/15/2016
Other adverse effects No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Section 14. Transport information DOT Classification IMDG IATA UN number UN1950 UN1950 UN1950 UN proper shipping name Aerosols, flammable (each not exceeding 1 L capacity) Aerosols, flammable (each not exceeding 1 L capacity) Aerosols, flammable (each not exceeding 1 L capacity) Transport hazard class(es) 2.1 2.1 2.1 Packing group - - - Environmental hazards No. No. No. Additional information Remarks Limited quantity Emergency schedules (EmS) F-D, S-U Remarks Limited quantity Remarks Limited quantity AERG 126 Special precautions for user Transport within user s premises always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according to Annex II of MARPOL and the IBC Code Not available. 10/12 Date of issue 07/15/2016
Section 15. Regulatory information U.S. Federal regulations Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 Clean Air Act (CAA) 112 regulated flammable substances Propane; Butane Not listed Not listed Not listed Not listed Not listed Composition/information on ingredients No products were found. SARA 304 RQ SARA 311/312 Classification TSCA 8(a) CDR Exempt/Partial exemption Not determined United States inventory (TSCA 8b) All components are listed or exempted. Not applicable. Composition/information on ingredients Fire hazard Sudden release of pressure Immediate (acute) health hazard Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Hydrogenated Base Oil (64742-47-8) 25-50 Yes. No. No. No. No. Hydrogenated Base Oil (64742-49-0) 10 - <25 Yes. No. No. Yes. No. SARA 313 State regulations Massachusetts New York New Jersey Pennsylvania California Prop. 65 No products were found. The following components are listed Propane; Butane None of the components are listed. The following components are listed Propane; Butane The following components are listed Hydrogenated Base Oil (64742-47-8); Propane; Butane; Hydrogenated Base Oil (64742-52-5) 11/12 Date of issue 07/15/2016
Section 16. Other information Procedure used to derive the classification History Classification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Liquefied gas SKIN IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 3 Date of issue mm/dd/yyyy Date of previous issue Version Prepared by 07/15/2016 09/15/2014 6 AMSOIL INC. On basis of test data Expert judgment Calculation method Calculation method Expert judgment Calculation method Justification Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 12/12 Date of issue 07/15/2016