Page 1 of 5 1 PRODUCT AND COMPANY IDENTIFICATION Manufacturer Distributed By: Wechem, Inc 5734 Susitna Dr Harahan, LA 70123 Contact: Phone: Fax: Web: Ligia Hernandez 504-733-1152 504-733-2218 www.wechem.com Product Name: Revision Date: M Number: Product Code: EPA Number: Chemical Family: Emergency Telephone Number: INFOTRAC at 1-800-535-5053 9/4/13 PS50A PS50 45385-28-34370 Botanical Insecticide 2 Route of Entry: Target Organs: Inhalation: Skin Contact: Eye Contact: Ingestion: HMIS III: HAZARDS IDENTIFICATION Inhalation, skin absorption, ingestion, eye Liquid is irritating to eyes and skin. Inhalation of high concentration may cause CNS depression. Liquid is toxic and will be harmful if swallowed. Excessive inhalation may cause CNS Depression, headache, dizziness, nausea. In extreme cases, death may occur. Causes irritation Causes irritation Liquid is toxic. Harmful or fatal if swallowed. H*1/F2/PH0 1 2 0 B Safety Glasses, Gloves
Page 2 of 5 GHS Signal Word: WARNING GHS Hazard Pictograms: GHS Classifications: Physical, Flammable Liquids, 4 Health, Skin corrosion/irritation, 3 Health, Serious Eye Damage/Eye Irritation, 2 A GHS Phrases: Combustible liquid Causes mild skin irritation Causes serious eye irritation 3 COMPOSITION/INFORMATION ON INGREDIENTS Ingredients: (OSHA LIMITS) OPTIOL Hazardous Components CAS # PEL STEL CEILING ACGIH TLV % Pyrethrins 8003-34-7 5mg/m3 N/A N/A 5mg/m3 0.13 Piperonyl butoxide technical* 51-03-6 N/A N/A N/A N/A 1.27 Solvent 170 64742-47-8 400 N/A N/A 400 N/A Solvent 142 64742-88-7 400 N/A N/A N/A N/A *REPORTABLE UNDER SARA SECT.313 4 Inhalation: Skin Contact: Eye Contact: Ingestion: FIRST AID MEASURES Remove to fresh air. Resuscitate if necessary. Give oxygen if necessary. Get medical attention. Remove contaminated clothing and shoes. Wash with soap and water. If irritated seek medical attention. Flush with water for 15 minutes. If irritated, seek medical attention. Do NOT induce vomiting. Get immediate medical attention.
5 FIRE FIGHTING MEASURES Page 3 of 5 Flammability: Flammable Flash Point: > 141 Deg. F. Burning Rate: ND Autoignition Temp: ND LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Use foam, dry chemical, carbon dioxide, water fog SPECIAL FIRE FIGHTING PROCEDURES: WARNING. Flammable. Clear fire area of unprotected personnel. Cool fire-exposed containers to prevent rupturing. Use self-contained breathing apparatus for confined areas. UNUSUAL FIRE & EXPLOSION HAZARDS: Cool containers exposed to intense heat with water to prevent container rupture from vapor pressure build-up. 6 ACCIDENTAL RELEASE MEASURES IN CASE MATERIAL IS RELEASED OR SPILLED: Keep liquid and vapor away from heat, sparks and flame. Handling equipment must be grounded to prevent sparking. Shut off source of leak if safe to do so. Dike and contain. Clean up with absorbents. WASTE DISPOSAL METHOD: Waste material is considered hazardous under EPA-RCRA (40 CFR 261.33). Follow latest EPA or state regulations regarding proper disposal. 7 Handling Precautions: Storage Requirements: HANDLING AND STORAGE Keep liquid and vapor away from heat, sparks and flame. Keep liquid and vapor away from heat, sparks and flame. Empty containers can contain explosive vapors. Avoid static electricity by grounding equipment. OTHER PRECAUTIONS: Bond and ground transfer equipment. 8 EXPOSURE CONTROLS/PERSOL PROTECTION Engineering Controls: Personal Protective Equip: VENTILATION: LOCAL EXHAUST: Use explosion-proof ventilation as required MECHANICAL EXHAUST: Use explosion-proof ventilation as required HMIS PP, B Safety Glasses, Gloves RESPIRATORY PROTECTION: Air purifying respirator for organic vapors or air-supplying respirator. OTHER PROTECTIVE EQUIPMENT: Use explosion-proof ventilation as required to control vapor concentration. Protective gloves: Chemical resistant Eye protection: Safety glasses / goggles Hygienic work practices: Explosion proof ventilation. Air dry contaminated clothing in a well ventilated area.
M Number: PS50A Page 4 of 5 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance: Physical State: Particle Size: Spec Grav./Density: Viscosity: Sat. Vap. Conc.: Boiling Point: Vapor Pressure: ph: Evap. Rate: Molecular weight: Light yellow liquid Liquid (H20=1): 0.803 Odor: Molecular Formula: Solubility: Softening Point: Percent Volatile: Heat Value: Freezing/Melting Pt.: Octanol: Vapor Density: VOC: Bulk Density: Mineral spirits odor 10 STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid: Hazardous Decomposition: Hazardous Polymerization: Stable. Avoid heat, sparks and flame. Avoid - Heat, sparks, flame, strong oxidizing agents, alkali metal hydroxides. Strong oxidizers, Alkali, metal hydroxides Carbon monoxide and unidentified organics may be formed during combustion. Will not occur 11 TOXICOLOGICAL INFORMATION 12 ECOLOGICAL INFORMATION This product is toxic to fish, birds and other wildlife. Do not apply directly to water. 13 DISPOSAL CONSIDERATIONS Dispose of according to local, state or federal regulations. 14 TRANSPORT INFORMATION UN #: UN3082 Proper Shipping Name: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S. (Pyrethrins) PGIII
15 REGULATORY INFORMATION COMPONENT / (CAS/PERC) / CODES ---------------------------------------------------------------- Piperonyl butoxide technical 51-03-6 1.27% SARA313 Page 5 of 5 REGULATORY KEY DESCRIPTIONS ---------------------------------------------------------------- SARA313 = SARA 313 Title III Toxic Chemicals 16 OTHER INFORMATION D.O.T. Hazard Classification: Combustible Liquid Bill of Lading Description: Chemicals, NOI All information contained in this Safety Data Sheet is furnished free of charge and is intended for your evaluation. In our opinion the information is, as of the date of this Safety Data Sheet, reliable, however, it is your responsibility to determine the suitability of the information for your use. You are advised not to construe the information as absolutely complete since additional information may be necessary or desirable when particular, exceptional or variable conditions or circumstances exist or because of applicable laws or government regulations. Therefore, you should use this information only as a supplement to other information gathered by you and you must make independent determinations of the suitability and completeness of the information from all sources to assure both proper use of the material described herein and the safety and health of employees. Accordingly, no guarantee expressed, or implied is made by as to the results to be obtained based upon your use of the information nor does assume any liability arising out of your use of the information. [a] NTP [b] IARC Monograph [c] OSHA [d] Not listed [e] Animal Data only N/A = Not available N/D = Not determined