multiclean Fluid for cleaning and temporary lubrication in physiologically and ecologically sensitive areas. Can be used in areas in which food is processed or stored. NSF H1 1. In this context, the product may come into contact with foodstuffs for technical reasons. Good cleaning and degreasing performance. Removes oils, resin encrustations and silicone residues. Suitable for use in physiologically and ecologically sensitive areas. Safe working. Good material compatibility. Applications: For residue-free cleaning and degreasing during assembly and maintenance work on machines, aggregates and tools in critical areas of the printing and paper industries as well as for applications in which the use of easily and highly flammable cleaners is not desired. Spray from a distance of approx. 20 cm on to the parts that are to be cleaned and allow to dry. If used in areas in which food is processed or stored, only the technically necessary minimum quantity may be used. Contents in ml Art No. Pack Qty. 400 0890 109 6 1/12 Technical Data Chemical Basis Colour Density at 20 o C (active substance) Flash point Aliphatic hydrocarbons Colourless 0.77g/cm 2 40 o C NSF H1, K1 registered (No: 135926), corresponds to the requirements of USDA 1998 H1. This information is only a recommendation based on our experience. Preliminary testing required. Acetone-free AOX and silicone-free. 1 NSF = Internationally recognised organisation for the supervision and registration of products used in the food sector. 2 VbF = Ordinance concerning Combustible Liquids (no longer valid as from 01.01.2004), has been replaced by the BetrSichV [Operational Safety Ordinance] (valid as from 03.10.2002) AUS. pub. 05/13 04 0511
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product information Commercial Product Name : Product code : 0890 109 6 MSDS-Identcode : 10033954 Product Use Description : Cleaning agent Company : Wurth Australia Pty Ltd 2/1 Healey Road Dandenong South, Victoria, 3175 Australia Telephone : +61 3 8788 1111 Responsible/issuing person : prodsafe@wuerth.com Emergency telephone number : 1300 657 765 Advisory office in case of poisoning - National Poisons Centre: 131 126 2. HAZARDS IDENTIFICATION DANGEROUS GOODS. HAZARDOUS SUBSTANCE. Dangerous goods classification according to the Australia Dangerous Goods Code. Classified as hazardous according to the criteria of NOHSC. Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated R-phrase(s) Extremely flammable. Repeated exposure may cause skin dryness or cracking. S-phrase(s) Do not breathe spray, vapour. Avoid contact with skin. This material and its container must be disposed of in a safe way. Use only in well-ventilated areas. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components 1 / 12
Chemical Name CAS-No. Concentration low boiling point hydrogen 64742-48-9 >= 95 - <= 100% treated naphtha Carbon dioxide 124-38-9 >= 3 - < 5% 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed : If you feel unwell, seek medical advice (show the label where possible). First aider needs to protect himself. Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately. : If breathed in, move person into fresh air. In the case of inhalation of aerosol/mist consult a physician if necessary. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. : In case of contact, immediately flush skin with soap and plenty of water. Do NOT use solvents or thinners. If skin irritation persists, call a physician. : Protect unharmed eye. If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : If swallowed, seek medical advice immediately and show this container or label. If swallowed, DO NOT induce vomiting. If a person vomits when lying on his back, place him in the recovery position. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Foam Dry powder Carbon dioxide (CO2) Water mist 2 / 12
Unsuitable extinguishing media Specific hazards during firefighting Special protective equipment for firefighters Further information : High volume water jet : Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition products may be formed under fire conditions (see section 10). Exposure to decomposition products may be a hazard to health. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Pay attention to flashback. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Remove all sources of ignition. Avoid contact with skin and eyes. Ensure adequate ventilation, especially in confined areas. Immediately evacuate personnel to safe areas. Avoid inhalation of vapour or mist. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Methods for cleaning up : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. : Clean contaminated surface thoroughly. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national 3 / 12
regulations. 7. HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion Dust explosion class : Limit the stocks at work place. Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. Do not spray on a naked flame or any incandescent material. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Take precautionary measures against static discharges. For personal protection see section 8. : Normal measures for preventive fire protection. Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Keep away from heat and sources of ignition. Do not smoke. No sparking tools should be used. Electrical equipment should be protected to the appropriate standard. : not applicable Storage Requirements for storage areas and containers Further information on storage conditions Advice on common storage Materials to avoid : Store in original container. BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep containers tightly closed in a dry, cool and wellventilated place. Please observe the storage instructions for aerosols! : AS/NZS 3833 The storage and handling of mixed classes of Dangerous Goods in packages and intermediate bulk containers. : Incompatible with oxidizing agents. : Oxidizing agents 4 / 12
Other data : No decomposition if stored and applied as directed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value Control parameters Carbon dioxide 124-38-9 STEL 30,000 ppm 54,000 mg/m3 Update Basis 1995-05-01 AU OEL STEL 30,000 ppm 54,000 mg/m3 2005-08-01 AU OEL Further information : H: ACGIH is the documentation source TWA 12,500 ppm 22,500 mg/m3 1995-05-01 AU OEL TWA 5,000 ppm 9,000 mg/m3 2005-08-01 AU OEL Further information : H: ACGIH is the documentation source Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003], as amended through August 2005 Biological occupational exposure limits no biological limit allocated Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN 5 / 12
141). Hand protection Eye protection Skin and body protection Hygiene measures : Nitrile rubber Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. : In case of splash hazard, please wear protective goggles. : Flame retardant antistatic protective clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Do not inhale aerosol. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Follow the skin protection plan. Wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Odour Threshold Safety data Flash point Lower explosion limit Upper explosion limit Flammability Auto-ignition temperature : aerosol : colourless : characteristic : 0 %(V) : 7 %(V) 6 / 12
ph Melting point/range Boiling point/boiling range Vapour pressure : 4,000 hpa at 20 C Density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic Relative vapor density Evaporation rate Thermal decomposition : insoluble 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid Hazardous decomposition products : Oxidizing agents : Carbon oxides nitrogen oxides (NOx) Build-up of dangerous/toxic fumes possible in cases of fire/high temperature. Hazardous reactions : Vapours may form explosive mixtures with air. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. Stability : No decomposition if stored and applied as directed. 11. TOXICOLOGICAL INFORMATION Acute toxicity Acute oral toxicity 7 / 12
Acute oral toxicity (Components) low boiling point hydrogen : LD50: > 15,000 mg/kg treated naphtha Species: rat Acute dermal toxicity (Components) low boiling point hydrogen : LD50: > 3,160 mg/kg treated naphtha Species: rabbit Skin corrosion/irritation Skin irritation : Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Serious eye damage/eye irritation Eye irritation : May irritate eyes. Respiratory or skin sensitization Sensitisation Chronic toxicity Mutagenicity Carcinogenicity Teratogenicity Reproductive toxicity Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration toxicity Further information low boiling point hydrogen treated naphtha : Aspiration hazard if swallowed - can enter lungs and cause damage. 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Bioaccumulation Biodegradability 8 / 12
Mobility in soil Further information on ecology Adsorbed organic bound halogens (AOX) Results of PBT assessment Additional ecological information : not included : The product should not be allowed to enter drains, water courses or the soil. 13. DISPOSAL CONSIDERATIONS Product Disposal of contaminated packaging : In accordance with local and national regulations., This material and its container must be disposed of as hazardous waste. : Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. Please ensure aerosol cans are sprayed completely empty (including propellant) Containers that have not been emptied in compliance with regulations are regarded as hazardous waste. Dispose of as unused product. 14. TRANSPORT INFORMATION ADG UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Labels : 2.1 Hazchem Code : 2YE Environmentally hazardous : no 9 / 12
IATA UN number : 1950 Description of the goods : Aerosols, flammable Class : 2.1 Labels : 2.1 Packing instruction (cargo : 203 aircraft) Packing instruction (passenger : 203 aircraft) Packing instruction (passenger : Y203 aircraft) Environmentally hazardous : no IMDG UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Packing group : -- Labels : 2.1 EmSNumber 1 : F-D EmS Number 2 : S-U Marine Pollutant : no 15. REGULATORY INFORMATION Labelling according to EC Directives 1999/45/EC R-phrase(s) : R12 Extremely flammable. R66 Repeated exposure may cause skin dryness or cracking. S-phrase(s) : S23 Do not breathe spray, vapour. S24 Avoid contact with skin. S35 This material and its container must be disposed of in a safe way. S51 Use only in well-ventilated areas. Special labelling of certain mixtures : Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Keep away from sources of ignition - No smoking. 10 / 12
Keep out of the reach of children. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. National regulatory information For detailed advice on Personal Protective equipment, refer to the following Australian Standards :- HB 9 (Handbook 9) Manual of industrial personal protection. AS/NZS 1337 Eye protectors for industrial applications. AS/NZS 1715 Selection, use and maintenance of respiratory protective devices. AS/NZS 1716 Respiratory protective devices. AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance. AS/NZS 2919: Industrial clothing. Hazard category Extremely flammable National Code of Practice for the Preparation of Material Safety Data Sheets [NOHSC:2011] List of Designated Hazardous Substances [NOHSC]. Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]. Amendment to National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC](2005) Australian Dangerous Goods Code. Standard Uniform Scheduling of Drugs and Poisons. Notification status AICS : On the inventory, or in compliance with the inventory 16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R12 Extremely flammable. R66 Repeated exposure may cause skin dryness or cracking. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a 11 / 12
warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet 12 / 12