LG Chemical Limited. LG Twin Tower/East Wing, 20, Yoido-dong, Yongdungpo -gu, Seoul, Korea Tel : 82-80-914-8282 Fax : 82-80-258-2581 MSDS Material Safety Data Sheet Issue Date : 1996. 4. 9 Revised Date Revised Item Page : 1 / 9 SECTIO 1 CHEMICAL PRODUCT AD COMPAY IDETIFICATIO CAS UMBER : 78-83-1 RTECS UMBER : P9625000 SUBATACE : TRADE AMES/SYOMS : ISOBUTAOL, FERMETATIO BUTYL ALCOHOL ISOPROPYLCARBIOL, 2-METHYLPROPYL ALCOHOL 1-HYDROXYMETHYLPROPAE, 2-METHYL-1-PROPALOL 2-METHYLPROPA-1-OL, ISO-BUTHYL ALCHOL 1-PROPAOL, 2-METHYL-, IBA79 BUTYL ALCOHOL, BUTAOL MAUFACTURER S AME, ADDRES : LG Chemical, 20, Yoido-dong, Yongdungpo-gu, Seoul, Korea P.O Box 150-721 TELEPHOE & FAX :TEL 82-2-3773-3672, FAX 82-2-3773-2581 CHEMICAL FAMILY : Hydroxyl, aliphatic CREATIO DATE : 16 /06 /96 SECTIO 2 COMPOSITIO, IFORATIO O IGREDIETS CAS UMBER : 78-83-1 PERCETAGE :100 OTHER COTAMIATS : OE SECTIO 3 HAZARDS IDETIFICATIO FPA PRTIGS (SCALE 0-4) : HEALTH=1 FIRE=3 REACTIVITY=0 EMERGECY OVERVIEW : Colorless,volatile liquid with a mile, sweet, non-residual odor. Causes respiratory tract, skin, and eye irritation. May affect the central nervous system. Flammable liquid and vapor. May cause flash fire. Keep away from all ignition sources. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Keep container tightly closed. Wash thoroughly after handling Use only with adequate ventilation.
Page : 2 / 9 POTETIAL HEALTH EFFECTS : IHALATIO : SHORT TERM EFFECTS : May cause irritation. Additional effects may include nausea, shortness of breath, headache, drowsiness and drunkenness. LOG TERM EFFECTS : In addition to effects from short term exposure, hearing loss may occur. SKI COTACT : SHORT TERM EFFECTS : May cause irritation. LOG TERM EFFECTS : Same effects as short term exposure. EYE COTACT : SHORT TERM EFFECTS : May cause irritation. Additional effects may include blurred vision. LOG TERM EFFECTS : o information is available on significant adverse effects. IGESTIO : SHORT TERM EFFECTS : May cause nausea, vomiting, stomach pain, headache, blurred vision. LOG TERM EFFECTS : o information is available on significant adverse effects. ADDITIOAL DATA : Drinking alcohol may worsen the effects. CARCIOGE STATUS : OSHA : TP : IARC : SECTIO 4 FIRST AID MEASURES IHALATIO : FIRST AID Remove form exposure area to fresh air immediately. Perform artificial respiration if necessary. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention. SKI COTACT : FIRST AID Remove contaminated clothing and shoes immediately. Wash with soap or mild detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes). Get medical attention immediately. EYE COTACT : FIRST AID Wash eyes immediately with large amounts of water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains (at least 15-20 minutes). Get medical attention immediately.
Page : 3 / 9 IGESTIO : FIRST AID Remove form exposure area to fresh air immediately. Perform artificial respiration if necessary. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention. OTE TO PHYSISIA ASTIDOTE : o Specific antidote. Treat symptomatically and supportively. SECTIO 5 FIRST FIDHTIG MEASURES FIRE AD EXPLOSIO HAZARDS : Dangerous fire hazard when exposed to heat, flame, or oxidizers. Vapor-air mixtures are explosive above flash point. Vapors are heavier than air may travel a considerable distance to a source of ignition and flash back. EXTIGUSIHIG MEDIA : Dry chemical, carbon dioxide, water spray or alcohol - resistant foam CREATIO DATA : OE SECTIO 6 ACCIDETAL RELEASE MEASURES OCCUPATIOAL SPILL : Shut off ignition sources. Do not touch spilled material. Stop leak if you can do it without risk. Use water spray to reduce vapor. Do not get water inside container. For small spills, take up with sand or other absorbent material and place into containers for later disposal. For large spills, disk far ahead of spill for later disposal. o smoking, flames or flares in hazard area. Keep unnecessary people away ; isolate hazard area and deny entry. Reportable Quantity (RQ) : 5000 pounds The Superfund Amendments and Reauthorization Act (SARA) Section 304 requires that a release equal to or greater than the reportable quantity for this substance be immediately reported to the local emergency planning committee and the state emergency response commission (40 CFR 355. 40). If the release of this substance is reportable under CERCLA Section 103, the ational Response Center must be notified immediately at (800) 424-8802 or (202) 426-2675 in the metropolitan Washington, D.C. area (40 CFR 302.6)
Page : 4 / 9 SOIL SPILL : Dig holding area such as lagoon, pond or pit for containment. Dike flow of spilled material using soil or sandbags or foamed barriers such as polyurethane or concrete. Use cement powder or fly ash to absorb liquid mass. eutralize spill with slaked lime, sodium bicarbonate or crushed limestone. AIR SPILL : Knock down vapors with water spray. Keep upwind. Water used to knock down vapors may become corrosive or toxic and should be contained properly for later disposal. Water SPILL eutralize with agricultural lime, slaked lime, crushed limestone or sodium bicarbonate. If dissolved, at a concentration of 10 ppm or greater, apply activated carbon at ten times the amount that has been spilled. Use mechanical dredges or lifts to extract immobilized masses of pollution and precipitates. SECTIO 7 HADIG AD STORAGE Observe all federal, state and local regulations when storing this substance. Bonding and grounding : Substances with low electric conductivity, which may be ignited by electrostatic sparks, should be stored in containers which meet the bounding and grounding guidelines specified in FPA 77-1983. Recommended Practice on Static Electricity. Store away from incompatible substances. SECTIO 8 EXPOSURE COTROLS, PERSOAL PROTECTI EXPOSURE LIMITS : o occupational exposure limits established by OSHA, ACGIH, or IOSH. 5000 pounds CERCLA Section 103 Report table Quantity VETILATIO : Provide local exhaust or process enclosure ventilation. Ventilation equipment should be explosion-proof if explosive concentrations of dust, vapor or fume are present.
Page : 5/ 9 EYE PROTECTIO : Employee must wear splash-proof or dust-resistant safety goggles to prevent eye contact with this substance Emergency wash facilities : Where there is any possibility that an employee s eyes and / or skin may be exposed to this substance, the employer should provide an eye wash fountain and quick drench shower within the immediate work area for emergency use. CLOTHIG : Employee must wear appropriate protective (impervious) clothing and equipment to prevent any possibility of skin contact with this substance. GLOVES : Employee must wear appropriate protective gloves to prevent contact with this substance. RESPORATOR : The following respirators are recommended based on information found in the physical data, toxicity and health effects sections. They are ranked in order from minimum respiratory selected must be based on operation levels found in the work place, must be base on contamination levels found the working limits of the respirator and must be jointly approved by the ational Institute for Occupational Safety and Health and the Mine Safety and Health Administration (IOSH-MSHA). Any type C supplied-air respirator with a full facepiece operated in pressure-demand or other positive pressure mode or with a full facepiede, helmet or hood operated in continuous-flow mode. Any self-contained breathing apparatus with a full facepiede operated in pressure - demand or other positive pressure mode. FOR FIREFIGTIG AD OTHER IMMEDIATELY DAGEROUS TO LIFE OR HEALTH CODITIOS : Any self-contained breathing apparatus that has a full facepiece and is operates ins a pressuredemand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operates ins a pressure- demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Page : 6/ 9 SECTIO 9 PHYSICAL AD CHEMICAL PROPERTIES DESCRIPITIO : Colorless liquid with pungent, rancid butter odor. MOLECULAR WEIGHT : 88.12 MOLECULAR FORMULA : (CH3) 2-C-H-C-O-O-H BOILIG POIT : 305-311 F (152-155 C) FREEZIG POIT : -52 F (-47 C) VAPOR PRESSURE : 1 mmhg @ 15 C VAPOR DESITY : 3.4 SPECIFIC DRAVITY : 0.959 WATER SOLIBILITY : soluble PH : 2.9 ( 0.1 solution ) Odor threshold : 8 PPM EVAPORATIO RATE : not available SOLVET SOLUBILITY : Miscible in alcohol, chloroform and ether. Saturated vapor is 1316 ppm at 25 C SECTIO 10 STABILITY AD REACTIVITY REACTIVITY : Stable under normal temperatures and pressure. CODITIOS TO AVOID : Avoid contact with heat, sparks, flames, or other sources of ignition. Vapors may be explosive. Material is corrosive avoid contact with skin or eyes. Do not allow contamination of water sources. ICOMPATIBILITIRS : ALUMIUM : Corrosive, exothermic reaction. BRASS : Corrosive IRO : Corrosive LEAD : Corrosive OXIDIZERS (STROG) : Fire and explosion hazard. REACTIVE METALS : Flammable hydrogen gas. STEEL : Corrosive. HAZARDOUS DECOMPOSITIO : Thermal decomposition may release acrid smoke and irritating fumes. POLUMERIZATIO : Hazardous polymerization has not been reported to occur under normal temperatures and pressures.
Page : 7/ 9 SECTIO 11 TOZICOLOGICAL IFORMATIO IRRITATIOM DATA : 139 ug/24 hours open skin-rabbit mild TOXICITY DATA : 500 mg/ kg skin-rabbit LD50 ; 280 mg/ kg oral-rat LD50 CARCIOGE STATUS : one. LOCAL EFFECTS : corrosive-inhalation, skin, eye. ACUTE TOXICTY LEVEL : Toxic by dermal absorption and ingestion. TARGET EFFECTS : o data available. HEALTH EFFECTS IHALATIO : CORROSIVE. ACUTE EXPOSURE Vapor may cause nasal irritation, sore throat, coughing, hoarseness and in extreme exposures, difficulty breathing and lung edema. The maximum exposure time to a concentrated vapor with no deaths after a 14 day observation period was 8 hours in rats. CHROIC EXPOSURE o data available. SKI COTACT : ACUTE EXPOSURE The liquid may cause redness, pain, burns, blistering and tissue destruction. Dome necrosis was reported after 24 hours following application of 10 mg to rabbit skin. The lethal does reported in rabbits was 500 mg/kg. CHROIC EXPOSURE Repeated or prolonged contact cause dermatitis with redness, dryness and itching EYE COTACT : CORROSIVE. ACUTE EXPOSURE Vapor or dilute solutions may cause burns with redness, pain and blurred vision. Sever corneal burning form application of a 5% aqueous solution of an unspecified volume to rabbit eyes was reported. CHROIC EXPOSURE Effects depend on concentration and duration of exposure. Repeated or prolonged contact with corrosive substance may result in conjunctivitis or effects as in acute exposure. IGESTIO : TOXIC. ACUTE EXPOSURE May cause mild to severe irritation of the mouth and stomach with sore thoat, abdominal pain, nausea and vomiting, The lethal does reported in rats was 280 mg/kg. CHROIC EXPOSURE o data available.
Page : 8 / 9 SECTIO 12 ECOLOGICAL IFORMATIO EVIROMETAL IMPACT RATIG ( 0-4 ) : no data available ACUTE AQUATIC TOXICITY : no data available DEGRADABILITY : no data available LOG BIOCOCETRATIO FACTOR ( BCF ) : no data available LOG OCTAOL/WATER PARTITIO CODEFFICIET : no data available SECTIO 13 DISPOSAL COSIDERATIOS Observe all federal, state and local regulations when disposing of this substance. Disposal must be in accordance with standards applicable to generators of hazardous waste, 40 CFR 262, EPA Hazardous Waste umber D001. 100 pound CERCLA Section 103 Reportable Quantity. Disposal must be in accordance with standards applicable to generators of hazardous waste, 40 CFR 262, EPA Hazardous Waste umber D002. 100 pound CERCLA Section 103 Reportable Quantity SECTIO 14 TRASPORT IFORMATIO U.S. DEPARTMET OF TRASPORTATIO SHIPPIG AME- ID UMBER, 49 CFR 172. 101 : losbutyric acid-u 2529 U.S. DEPARTMET OF TRASPORTATIO HAZARD CLASS OR DIVISIO, 49 CFR 172. 101 : 3-Flammable liquid U.S. DEPARTMET OF TRASPORTATIO PACKIG AUTHORIZATIOS : EXCEPTIOS : 49 CFR 173. 150 O-BULK PACKAGIG : 49 CFR 173. 242 U.S. DEPARTMET OF TRASPORTATIO QUATITY LIMITATIOS, 49 CFR 172. 101 : PASSEGER AIRCRAFT OR RAILCAR : 60 L CARDO AIRCRAFT OLY : 220 L.
Page : 9/9 SECTIO 15 REGULATORY IFORMATIO TSCA IVETORY STATUS : CERCLA SECTIO 103 (40CFR302.4 ) : SARA SECTIO 302 (40CFR355.30 ) : SARA SECTIO 304 (40CFR355.40 ) : SARA SECTIO 313 (40CFR372.65 ) : OSHA PROCESS SAFETY ( 29CFR1910.119 ) : CALIFORIA PROPOSITIO 65 : Y SARA HAZARD CATEGORIES, SARA SECTIOS 311/312 (40 CFR 370.21) ACUTE HAZARD : CHROIC HAZARD : FIRE HAZAED : REACTIVE HAZAED : SUDDE RELEASE HAZAED : SECTIO 16 OTHER IFORMATIO