MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product number 985-003 Product name Citra Orange Jinx Citrus Organic Crazy All Clean Purpose Cleaner Effective date 15-Dec-2009 Company information Claire Sprayway, Manufacturing Inc Co 500 484 Vista Ave Addison, IL 60101 United States Company phone General Assistance 630-543-7600 Emergency telephone US 800-424-9300 Emergency telephone outside US 703-527-3887 Version # 15 Supersedes date 04-Aug-2009 Emergency overview Potential health effects Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms 2 Hazards Identification CONTENTS UNDER PRESSURE Aerosol Irritating to eyes Prolonged exposure may cause chronic effects Causes eye irritation Contact with skin can cause irritation and allergic reaction (sensitization) in some individuals Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash) Intentional misuse by concentrating and inhaling the product can be harmful or fatal Exposure by ingestion of an aerosol is unlikely Components of the product may be absorbed into the body by ingestion Central nervous system May cause central nervous system disorder (eg, narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage Narcosis Defatting of the skin Irritation Sensitization 3 Composition / Information on Ingredients Components d-limonene n-hazardous and other components below reportable levels CAS # 5989-27-5 74-98-6 106-97-8 Percent 3-5 1-3 1-3 > 90 First aid procedures Eye contact Skin contact Inhalation Ingestion Flammable properties Extinguishing media Suitable extinguishing media 4 First Aid Measures Remove contact lenses, if present and easy to do Immediately take off all contaminated clothing Wash off with warm water and soap If symptoms develop move victim to fresh air If symptoms persist, get medical attention In the unlikely event of swallowing contact a physician or poison control center 5 Fire Fighting Measures Vapor or gas may spread to distant ignition sources and flash back Water fog Foam Dry chemical powder Carbon dioxide (CO2) 1 / 5
Protection of firefighters Protective equipment and precautions for firefighters Methods for containment Methods for cleaning up In the event of fire and/or explosion do not breathe fumes Containers should be cooled with water to prevent vapor pressure build up 6 Accidental Release Measures Stop leak if you can do so without risk Move the cylinder to a safe and open area if the leak is irreparable Stop the flow of material, if this is without risk Prevent entry into waterways, sewers, basements or confined areas Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal Small Spills: Wipe up with absorbent material (eg cloth, fleece) Clean contaminated surface thoroughly Handling Storage 7 Handling and Storage Pressurized container: Do not pierce or burn, even after use Do not use if spray button is missing or defective Do not get this material in contact with eyes Do not get this material in contact with skin Wear personal protective equipment Avoid prolonged exposure Level 1 Aerosol Contents under pressure Do not puncture, incinerate or crush Keep away from heat, sparks, and flame Avoid exposure to long periods of sunlight Store in cool place Keep out of the reach of children Do not store, incinerate, or heat this material above 120 degrees Fahrenheit 8 Exposure Controls / Personal Protection Exposure limits ACGIH Components CAS # TWA STEL Ceiling 74-98-6 1000 ppm t established t established 106-97-8 1000 ppm t established t established OSHA Components CAS # TWA STEL Ceiling 74-98-6 1000 ppm t established t established Personal protective equipment Eye / face protection t normally needed Skin protection Respiratory protection Wear appropriate chemical resistant clothing Protective gloves t normally needed personal respiratory protective equipment normally required If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator 9 Physical & Chemical Properties Appearance Boiling point Color Flammability (HOC) Flash back Flash point Form Odor Compressed liquefied gas 2048 F (961 C) estimated White 46876 kj/g estimated -156 F (-1044 C) Propellant Aerosol fruity ph 9-10 Physical state Pressure Solubility Specific gravity Liquid 70-90 psig @ 70F Partially 09545 estimated 2 / 5
Conditions to avoid Incompatible materials 10 Chemical Stability & Reactivity Information Heat, flames and sparks known 11 Toxicological Information Acute effects Component analysis - LD50 Toxicology Data - Selected LD50s and LC50s d-limonene Sensitization Teratogenicity Acute LD50: 43352 mg/kg estimated, Rat, Dermal 5989-27-5 Oral LD50 Rat 4400 mg/kg; Dermal LD50 Rabbit >2000 mg/kg 106-97-8 Inhalation LC50 Rat 658 mg/l 4 h 74-98-6 Inhalation LC50 Rat 658 mg/l 4 h May cause sensitization by skin contact t expected to be hazardous by OSHA criteria Ecotoxicity Waste codes Disposal instructions 12 Ecological Information LC50 12389 mg/l, Fish, 9600 Hours, EC50 49786 mg/l, Daphnia, 4800 Hours, IC50 11489 mg/l, Algae, 7200 Hours, Components of this product have been identified as having potential environmental concerns 13 Disposal Considerations D001: Waste Flammable material with a flash point <140 F Contents under pressure Dispose of this material and its container at hazardous or special waste collection point Do not incinerate sealed containers Do not allow this material to drain into sewers/water supplies If discarded, this product is considered a RCRA ignitable waste, D001 Dispose in accordance with all applicable regulations 14 Transport Information Department of Transportation (DOT) Requirements Proper shipping name Consumer commodity ORM-D Subsidiary hazard class 156, 306 Packaging non bulk 156, 306 Packaging bulk IMDG Proper shipping name UN number Item Labels required Transport Category AEROSOLS 21 1950 LTD QTY 5F 2 3 / 5
IATA Proper shipping name UN number Labels required Aerosols, flammable 21 1950 LTD QTY 21 15 Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19101200 CERCLA/SARA Hazardous Substances - t applicable Occupational Safety and Health Administration (OSHA) 29 CFR 19101200 hazardous chemical CERCLA (Superfund) reportable quantity Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Section 311 hazardous chemical Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Inventory status Country(s) or region Inventory name On inventory (yes/no)* China Europe Europe Japan Korea United States & Puerto Rico Inventory of Existing Chemical Substances in China (IECSC) European Inventory of New and Existing Chemicals (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) Toxic Substances Control Act (TSCA) Inventory A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations US - Pennsylvania - RTK (Right to Know) List 106-97-8 Present 74-98-6 Present 16 Other Information Further information HMIS ratings Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: HMIS is a registered trade and service mark of the NPCA 4 / 5
Disclaimer MSDS sections updated Prepared by The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication, The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification, The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text This document has undergone significant changes and should be reviewed in its entirety Regulatory Compliance 5 / 5