Page 1/6 1 Identification of substance: Product details: Application of the substance / the preparation: Specialty chemical (i.e. additive for overprint varnishes)/ For industrial use only Manufacturer/Supplier: Indulor Group Email: info@indulor.de Schulstraße 3 D-49577 Ankum Germany Phone: +49-5462 74120 Fax:+49-5462 741274 Emergency information: 24 h Medical Emergency Phone: (800)420-8841 (USA and Canada) or +1-651-632-6198 (International) In the event of emergency spill, fire or exposure call Chemtrec: (800)424-9300 or international: +1-703-5273887 2 Composition/Data on components: CAS Wt % Components Proprietary > 99.5 Styrene-acrylic resin (non-hazardous) Proprietary < 0.5 Volatile organic compounds 3 Hazards identification Effects of acute exposure: Eye: May cause mild eye irritation. Skin: Prolonged or repeated contact may cause mild skin irritation. Inhalation: Inhalation of the vapours of the heated product may cause irritation of mucuous membranes, headache, nausea, dizziness drowsiness. Ingestion: May cause nausea or abdominal discomfort. Information pertaining to particular dangers for man and environment According to current European laws and regulations the product is not dangerous or toxic material (based on the available data). At high temperatures could be formed corrosive and irritant vapours. NFPA ratings (scale 0-4) Health = 1 0= Insignificant Flammability = 1 1= Slight Reactivity = 0 2= Moderate 3= High 4= Very High 4 First aid measures General information Immediately remove any clothing soiled by the product. (Contd. on page 2)
Page 2/6 (Contd. of page 1) After inhalation Under certain conditions forming of irritant/corrosive vapours is possible. If such vapours are inhaled take affected person into fresh air, keep warm and call for a doctor. After skin contact Remove soiled clothes and shoes. Clean effected skin thoroughly with water and a mild cleansing agent. No residues shall remain on the skin. If irritation develops, consult a doctor. After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing Rinse out mouth and then drink plenty of water. Seek medical treatment. Information for doctor The following symptoms may occur: After inhalation of the vapours: Irritation of mucuous membranes, headache, nausea, dizziness, drowsiness. 5 Fire fighting measures Flashpoint: not applicable Flammable Limits: not applicable Autoignition: not applicable Suitable extinguishing agents CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire fighting measures that suit the environment. Special hazards caused by the material, its products of combustion or resulting gases: Material may burn in heat of fire. Dangerous decomposition products see chapter 10: stability and Reactivity. Protective equipment: Wear self-contained respiratory protective device. Do not inhale combustion vapors. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Collect contaminated fire fighting water separately. It must not enter the sewage system. 6 Accidental release measures Person-related safety precautions: Avoid formation of dust. Keep unprotected persons away. Measures for environmental protection: Do not allow product to reach sewage system or any water course. Measures for cleaning/collecting: Pick up mechanically. Send for recovery or disposal in suitable receptacles. Dispose contaminated material as waste according to item 13. (Contd. on page 3)
Page 3/6 (Contd. of page 2) 7 Handling and storage Handling Information for safe handling: Prevent formation of dust. Any deposit of dust which cannot be avoided must be regularly removed. Avoid inhalation of dust. Avoid inhalation of vapours formed by heated product. Avoid contact with eyes and skin. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Storage Requirements to be met by storerooms and receptacles: Store receptacles tightly closed at a cool and dry place with sufficient ventilation. Information about storage in one common storage facility: Store away from foodstuffs and feed. Further information about storage conditions: None. 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment General protective and hygienic measures The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale dust / smoke / mist. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Do not eat or drink while working. All protective equipment used shall be according to 29 CFR.1910 Subpart I Personal Protective Equipment Breathing equipment: At formation of dust: NIOSH/MSHA-approved respirator. (Contd. on page 4)
Page 4/6 (Contd. of page 3) Protection of hands: Protective gloves if prolonged or repeated contact is possible. To avoid skin problems reduce the wearing of gloves to the required minimum. Check protective gloves prior to each use for their proper condition. The glove material has to be impermeable and resistant to the product. After use of gloves apply skin-cleaning agents and skin cosmetics. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Eye protection: Chemical safety goggles with side shields Body protection: Protective work clothing. 9 Physical and chemical properties: General Information Form: Solid. Color: Slightly yellowish Odor: Characteristic Value/Range Unit Method Change in condition Melting point/melting range: undetermined Boiling point/boiling range: undetermined Flash point: Not applicable Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Bulk density: at 20 C ~ 0.7 kg/m³ Solubility in / Miscibility with Water: Insoluble Additional information VOC content: < 0.5 % 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. Materials to be avoided: Strong oxidants Reducing agents Dangerous reactions No dangerous reactions known Dangerous products of decomposition: In the case of fire or at high temperatures the formation of the following decomposition products is possible: Irritant gases/vapours Corrosive gases/vapours (Contd. on page 5)
Page 5/6 (Contd. of page 4) 11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification: LD 50 (oral, rat): > 5000 mg/kg (analogy) LD 50 (dermal, rat): > 5000 mg/kg (analogy) Primary irritant effect: on the skin: possible after prolonged contact on the eye: Irritation to the eyes is possible. Sensitization: No sensitizing effects known. Experience with humans: If used according to instructions no negative effects have been reported due to many years of experience. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. 12 Ecological information: Ecotoxical effects: Acquatic toxicity: Presently there are no ecotoxicological values available. General notes: Not known to be hazardous to water. This product is classified according to the official classification of other plastic materials, ident-no. 766. (German regulation) 13 Disposal considerations Product: Recommendation Disposal according to instructions of local authorities. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information DOT regulations: Hazard class: - regulations Land transport ADR/RID (cross-border) ADR/RID class: - regulations (Contd. on page 6)
Page 6/6 (Contd. of page 5) Maritime transport IMDG: IMDG Class: - regulations Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - regulation 15 Regulations Markings according to EU guidelines: Observe the general safety regulations when handling chemicals. The substance is not subject to classification according to the sources of literature known to us. The product is not subject to identification regulations according to directives on hazardous materials. National regulations: Water hazard class (Germany) Not known to be hazardous to water. Regulation or reporting requirements USA SARA section 355: This product is not subject to the reporting requirements under SARA 355. SARA section 313: This product is not subject to the reporting requirements under SARA 313. Prop. 65 Cancer: Substance is not listed. Prop. 65 - Repr. tox.: Substance is not listed. 16 Other information: This information is based on our present knowledge. However, this shall not constitute a warranty, express or implied, for any specific product features and shall not establish a legally valid contractual relationship. Statements herein should not be construed as representations or warranties. Users are responsible to evaluate all available information when using product for any particular use and to comply with all applicable laws and regulations. Department issuing MSDS: Quality assurance Dr. Oberschmidt Contact: refer to section 1