Safety Data Sheet Freeman TUF Fil Gray (Aluminum) Date of Preparation: June 1, 2015 Section 1 Chemical Product and Company Identification 1.1 Product identifiers Product name: Freeman TUF Fil Gray (Aluminum) 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: N/A 1.3 Details of the supplier of the safety data sheet Freeman Manufacturing and Supply Company 1101 Moore Road, Avon, OH 44011 Phone (440) 934 1902 FAX (440) 934 7200 1.4 Emergency telephone number Emergency Phone (800) 424 9300 HMIS H 3 F 2 R 1 PPE Sec. 8 Section 2 Hazards Identification 2.1 Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910.1200 (OSHA HCS) Flammable liquids, Category 3 Skin corrosion/irritation, Category 3 Acute toxicity, Inhalation Category 4 Skin irritation, Category 2 Eye irritation, Category 2A Carcinogenicity, Category 2 Reproductive toxicity, Category 2 Specific target organ toxicity, repeated exposure Category 1 2.2 GHS Label elements, including precautionary statements Signal word Danger Hazard statements Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure.
Freeman TUF Fil Gray (Aluminum) Section 2 Hazards Identification cont. Precautionary statements Prevention Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed when not in use. Do not breathe fumes or vapors. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only in a well ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin: Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and call doctor/physician if not feeling well. If in eyes: Rinse continuously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage Store in a well ventilated place. Keep cool. Disposal Dispose of contents and container to an appropriate waste site in accordance with local and national regulations. 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS None. Section 3 Composition/Information on Ingredients 3.1 Substance Ingredient Name CAS Number Polyester Resin Proprietary Styrene Monomer 100 42 5 Titanium Dioxide 13463 67 7 Section 4 First Aid Measures 4.1 Description of first aid measures If inhaled Move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes thoroughly with water. If irritation persists, get medical assistance. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11. Page 2 of 6
Freeman TUF Fil Gray (Aluminum) Section 4 First Aid Measures cont. 4.3 Indication of any immediate medical attention and special treatment needed. Section 5 Fire Fighting Measures 5.1 Extinguishing media Suitable extinguishing media: Use water spray, alcohol resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Nature of decomposition products not known. 5.3 Advice for firefighters Wear self contained breathing apparatus for firefighting if necessary. 5.4 Further information. Section 6 Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Avoid breathing vapors, mist or gas. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. Section 7 Handling and Storage 7.1 Precautions for safe handling Use normal precautions when handling flammable materials. Do not breathe fumes or vapor. Do not allow material to contact skin. Provide appropriate exhaust ventilation. 7.2 Conditions for safe storage, including any incompatibilities Store at ambient temperatures in closed containers. This material can catch fire if overheated. Do not heat this material above the flash point. Keep away from flame and open electrical coils. No chemical incompatibilities. Section 8 Exposure Controls/Personal Protection 8.1 Control parameters Components with workplace control parameters Ingredient OSHA ACGIH PEL STEL TWA STEL Styrene Monomer 50 ppm 100 ppm 50 ppm 100 ppm Titanium Dioxide 5 mg/m 3 15 mg/m 3 10 mg/m 3 None estab. 8.2 Exposure controls Appropriate engineering controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. An eye wash station and safety shower should be located near the workstation. Page 3 of 6
Freeman TUF Fil Gray (Aluminum) Section 8 Exposure Controls/Personal Protection cont. 8.3 Personal protective equipment Eye/face protection With product at ambient temperatures, use safety glasses equipped with side shields. 8.4 Skin protection Hand Protection With product at ambient temperatures, use disposable nitrile gloves. Contaminated gloves should be replaced. Body Protection Prevent skin contact when handling material. 8.5 Respiratory Protection The need for respiratory protection is not anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, a NIOSH approved organic vapor respirator equipped with a dust/mist prefilter should be used. 8.6 Safety Stations Make emergency eyewash stations, safety/quick drench showers, and washing facilities available in work area. 8.7 General Hygienic Practices Avoid breathing vapor or mist. Avoid contamination of food, beverages, or smoking materials. Wash thoroughly after handling, and before eating, drinking or smoking. Remove contaminated clothing promptly and clean thoroughly before reuse. Section 9 Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance Light Gray paste Odor Styrene Odor Threshold ph Melting Point VOC Content 1.20 lbs/gal Initial boiling point & boiling range Flash Point (COC) 35 C (95 F) Evaporation rate Flammability (solid, gas) Upper/lower flammability Vapor Pressure Vapor density Relative density (g/cc) 1.7±0.05 Water Solubility Negligible Coefficient: n octanol/water Auto ignition temperature Viscosity Paste at Room Temperature Explosive Properties None Oxidizing Properties None % Volatile 10 15% Page 4 of 6
Freeman TUF Fil Gray (Aluminum) Section 10 Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions None. 10.4 Conditions to avoid Heat and open flames. 10.5 Incompatible materials Oxidizing agents, peroxides 10.6 Hazardous decomposition products Thermal oxidative decomposition can produce CO and CO 2. Section 11 Toxicological Information 11.1 Information on toxicological effects Acute Oral toxicity Low toxicity Acute Inhalation toxicity Low toxicity Acute Dermal toxicity Low toxicity Skin corrosion/irritation Skin irritant Serious eye damage/eye irritation Eye irritant Respiratory or skin sensitization Not a skin sensitizer Germ cell mutagenicity Carcinogenicity IARC Styrene (CAS #100 42 5) is considered a class 2B suspect human carcinogen. Titanium Dioxide (CAS #13463 67 7) is considered a class 2B suspect human carcinogen. ACGIH Styrene is not classifiable as a carcinogen. NTP Styrene is reasonably anticipated to be a human carcinogen. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen. Reproductive toxicity Not expected to be a hazard Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Not expected to be a hazard Section 12 Ecological Information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT & vpvb assessment Page 5 of 6
Freeman TUF Fil Gray (Aluminum) Section 13 Disposal Considerations 13.1 Disposal Use safety containers for disposal. Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and local regulations. 14.1 DOT Transportation Data (49 CFR 172.101) 14.2 Shipping Name Polyester Resin Kit Hazard Class: 3 ID No.: UN 3269 Packing Group: III Label: Consumer Commodity ORM D (gal.) Flammable Class 3 (3 gal.) Section 14 Transport Information Section 15 Regulatory Information 15.1 US Federal Regulations RCRA Hazardous Waste Number (40 CFR 261.33): Not listed RCRA Hazardous Waste Classification (40 CFR 261): Not classified CERCLA Hazardous Substance (40 CFR 302.4): Listed/unlisted specific per RCRA Sec. 3001 SARA 311/312 Codes: Chronic Health Hazard, Fire Hazard SARA Toxic Chemical (40 CFR 372.65): No components were identified TSCA Inventory Status: All ingredients listed on TSCA inventory requirements 15.2 State Regulations This product is not known to contain any components for which the State of California has found to cause cancer, birth defects or other reproductive harm. Talc (CAS #14807 96 6) and Titanium Dioxide (CAS #13463 67 7), and Styrene (CAS #100 42 5) are on the New Jersey and Pennsylvania Right to Know Lists. Section 16 Other Information 16.1 Disclaimer The following supersedes Buyer s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer s sole remedy and Seller s sole liability for any claims shall be Buyer s purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the human body is intended. Page 6 of 6
Safety Data Sheet Freeman TUF Fil Aluminum w/o TiO 2 Date of Preparation: June 1, 2015 Section 1 Chemical Product and Company Identification 1.1 Product identifiers Product name: Freeman TUF Fil Aluminum w/o TiO 2 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: N/A 1.3 Details of the supplier of the safety data sheet Freeman Manufacturing and Supply Company 1101 Moore Road, Avon, OH 44011 Phone (440) 934 1902 FAX (440) 934 7200 1.4 Emergency telephone number Emergency Phone (800) 424 9300 HMIS H 3 F 2 R 1 PPE Sec. 8 Section 2 Hazards Identification 2.1 Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910.1200 (OSHA HCS) Flammable liquids, Category 3 Skin corrosion/irritation, Category 3 Acute toxicity, Inhalation Category 4 Skin irritation, Category 2 Eye irritation, Category 2A Carcinogenicity, Category 2 Reproductive toxicity, Category 2 Specific target organ toxicity, repeated exposure Category 1 2.2 GHS Label elements, including precautionary statements Signal word Danger Hazard statements Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure.
Freeman TUF Fil Aluminum w/o TiO 2 Section 2 Hazards Identification cont. Precautionary statements Prevention Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed when not in use. Do not breathe fumes or vapors. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only in a well ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin: Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and call doctor/physician if not feeling well. If in eyes: Rinse continuously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage Store in a well ventilated place. Keep cool. Disposal Dispose of contents and container to an appropriate waste site in accordance with local and national regulations. 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS None. Section 3 Composition/Information on Ingredients 3.1 Substance Ingredient Name CAS Number Polyester Resin Proprietary Styrene Monomer 100 42 5 Section 4 First Aid Measures 4.1 Description of first aid measures If inhaled Move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes thoroughly with water. If irritation persists, get medical assistance. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11. Page 2 of 6
Freeman TUF Fil Aluminum w/o TiO 2 Section 4 First Aid Measures cont. 4.3 Indication of any immediate medical attention and special treatment needed. Section 5 Fire Fighting Measures 5.1 Extinguishing media Suitable extinguishing media: Use water spray, alcohol resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Nature of decomposition products not known. 5.3 Advice for firefighters Wear self contained breathing apparatus for firefighting if necessary. 5.4 Further information. Section 6 Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Avoid breathing vapors, mist or gas. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. Section 7 Handling and Storage 7.1 Precautions for safe handling Use normal precautions when handling flammable materials. Do not breathe fumes or vapor. Do not allow material to contact skin. Provide appropriate exhaust ventilation. 7.2 Conditions for safe storage, including any incompatibilities Store at ambient temperatures in closed containers. This material can catch fire if overheated. Do not heat this material above the flash point. Keep away from flame and open electrical coils. No chemical incompatibilities. Section 8 Exposure Controls/Personal Protection 8.1 Control parameters Components with workplace control parameters Ingredient OSHA ACGIH PEL STEL TWA STEL Styrene Monomer 50 ppm 100 ppm 50 ppm 100 ppm 8.2 Exposure controls Appropriate engineering controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. An eye wash station and safety shower should be located near the workstation. Page 3 of 6
Freeman TUF Fil Aluminum w/o TiO 2 Section 8 Exposure Controls/Personal Protection cont. 8.3 Personal protective equipment Eye/face protection With product at ambient temperatures, use safety glasses equipped with side shields. 8.4 Skin protection Hand Protection With product at ambient temperatures, use disposable nitrile gloves. Contaminated gloves should be replaced. Body Protection Prevent skin contact when handling material. 8.5 Respiratory Protection The need for respiratory protection is not anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, a NIOSH approved organic vapor respirator equipped with a dust/mist prefilter should be used. 8.6 Safety Stations Make emergency eyewash stations, safety/quick drench showers, and washing facilities available in work area. 8.7 General Hygienic Practices Avoid breathing vapor or mist. Avoid contamination of food, beverages, or smoking materials. Wash thoroughly after handling, and before eating, drinking or smoking. Remove contaminated clothing promptly and clean thoroughly before reuse. Section 9 Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance Dark Gray paste Odor Styrene Odor Threshold ph Melting Point VOC Content 1.20 lbs/gal Initial boiling point & boiling range Flash Point (COC) 35 C (95 F) Evaporation rate Flammability (solid, gas) Upper/lower flammability Vapor Pressure Vapor density Relative density (g/cc) 1.7±0.05 Water Solubility Negligible Coefficient: n octanol/water Auto ignition temperature Viscosity Paste at Room Temperature Explosive Properties None Oxidizing Properties None % Volatile 10 15% Page 4 of 6
Freeman TUF Fil Aluminum w/o TiO 2 Section 10 Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions None. 10.4 Conditions to avoid Heat and open flames. 10.5 Incompatible materials Oxidizing agents, peroxides 10.6 Hazardous decomposition products Thermal oxidative decomposition can produce CO and CO 2. Section 11 Toxicological Information 11.1 Information on toxicological effects Acute Oral toxicity Low toxicity Acute Inhalation toxicity Low toxicity Acute Dermal toxicity Low toxicity Skin corrosion/irritation Skin irritant Serious eye damage/eye irritation Eye irritant Respiratory or skin sensitization Not a skin sensitizer Germ cell mutagenicity Carcinogenicity IARC Styrene (CAS #100 42 5) is considered a class 2B suspect human carcinogen.. ACGIH Styrene is not classifiable as a carcinogen. NTP Styrene is reasonably anticipated to be a human carcinogen. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen. Reproductive toxicity Not expected to be a hazard Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Not expected to be a hazard Section 12 Ecological Information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT & vpvb assessment Page 5 of 6
Freeman TUF Fil Aluminum w/o TiO 2 Section 13 Disposal Considerations 13.1 Disposal Use safety containers for disposal. Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and local regulations. 14.1 DOT Transportation Data (49 CFR 172.101) 14.2 Shipping Name Polyester Resin Kit Hazard Class: 3 ID No.: UN 3269 Packing Group: III Label: Consumer Commodity ORM D (gal.) Flammable Class 3 (3 gal.) Section 14 Transport Information Section 15 Regulatory Information 15.1 US Federal Regulations RCRA Hazardous Waste Number (40 CFR 261.33): Not listed RCRA Hazardous Waste Classification (40 CFR 261): Not classified CERCLA Hazardous Substance (40 CFR 302.4): Listed/unlisted specific per RCRA Sec. 3001 SARA 311/312 Codes: Chronic Health Hazard, Fire Hazard SARA Toxic Chemical (40 CFR 372.65): No components were identified TSCA Inventory Status: All ingredients listed on TSCA inventory requirements 15.2 State Regulations This product is not known to contain any components for which the State of California has found to cause cancer, birth defects or other reproductive harm. Talc (CAS #14807 96 6) and Styrene (CAS #100 42 5) are on the New Jersey and Pennsylvania Right to Know Lists. Section 16 Other Information 16.1 Disclaimer The following supersedes Buyer s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer s sole remedy and Seller s sole liability for any claims shall be Buyer s purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the human body is intended. Page 6 of 6