Title: PFA PRODUCTS Page: 1 Of 5 SECTION I- Identification of Product HMIS RATING: Health- 0 Flammability- 0 Reactivity- 0 PRODUCT NAME: NORTON PFA Film, CHEMFLUOR PFA Tubing, CHEMWARE PFA Bottles OTHER/GENERIC NAMES: Perfluoroalkoxy Polymer, PFA FORM: Transparent or Translucent plastic film, tubing, rod. PRODUCT USE: High temperature film laminates, release liners, chemical resistance applications, high purity fluid handling, non-stick surface coverings, lab ware. MANUFACTURERS NAME/ADDRESS: Saint-Gobain Performance Plastics Corp. 150 Dey Road, Wayne, NJ 07470 USA EMERGENCY TELEPHONE NO.: CHEM-TEL Inc. US: 1-800-255-3924 Worldwide + 01-813-248-0585 TECHNICAL ASSISTANCE TELEPHONE NO.: 973-696-4700 SECTION II- Composition/Information on Ingredients Ingredient Name CAS Number Weight % Fluorinated Ethylene Perfluoroalkyl Vinyl Ether Copolymer 26655-00-5 100% This product as supplied is not considered hazardous as defined in the US Code of Federal Regulations, 29CFR 1910.1200. This product is considered an "article" as supplied for its intended and foreseen use. All components appear on TSCA Inventory. This product contains no substances at or above the reporting threshold under Section 313 of Title III of the US EPA Superfund Amendments and Reauthorization Act of 1986 and US Code of Federal Regulations, 40CFR part 372, based on available data. SECTION III- Hazards Identification EMERGENCY OVERVIEW: No special dangers are known. Use within specified processing parameters, high temperatures could evolve irritating and/or toxic fumes. Potential Health Hazards: SKIN: Not anticipated under recommended usage conditions. Nuisance dust may be encountered during machining operation, mechanical irritation. EYES: Not anticipated under recommended usage conditions. INHALATION: Not anticipated under recommended usage conditions. May cause flu-like symptoms if thermal decomposition products are inhaled ( polymer-fume-fever ), chills, fever, and headache. INGESTION: Not anticipated under recommended usage conditions. DELAYED EFFECTS: None Ingredients found on one of the OSHA designated carcinogen lists are listed below: None listed
Title: PFA PRODUCTS Page: 2 Of 5 Section IV- First Aid Measures SKIN: Not anticipated under recommended usage conditions. For hot product, immediately immerse in or flush affected area with large amounts of cold water. Cover with clean cotton sheeting or gauze and seek medical advice. EYES: Not anticipated under recommended usage conditions. If necessary, flush eyes with plenty of water. If symptoms persist or injury is suspected, seek medical advice. INHALATION: Not anticipated under recommended usage conditions. Remove victim to fresh air. If not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. INGESTION: Not anticipated under recommended usage conditions. Treat symptomatically. Seek medical attention. If unconscious, do not give anything by mouth. If vomiting occurs, prevent aspiration. ADVICE TO PHYSICIAN: Expect influenza-like symptoms if thermal decomposition products are inhaled: chills, fever, headache, shortness of breath, coughing. This is known as polymer fume-fever and will pass after 24 to 48 hours providing no further exposure occurs. SECTION V- Fire Fighting Measures Flammable Properties FLASH POINT: Does not flash FLASH POINT METHOD: N/A AUTO IGNITION TEMPERATURE: Not known UPPER FLAME LIMIT (volume % in Air): N/A LOWER FLAME LIMIT (volume % in Air): N/A OXYGEN INDEX: N/A EXTINGUISHING MEDIA: Water, foam, carbon dioxide, dry chemical. UNUSUAL FIRE AND EXPLOSIVE HAZARDS: Does not burn without external source of fuel. SPECIAL FIRE FIGHTING PRECAUTIONS/INSTRUCTIONS: In an extreme fire situation, protection from hydrogen fluoride should be employed. Toxic Fluorine compounds may be evolved in fire. SECTION VI- Accidental Release Measures IN CASE OF SPILLS OR OTHER RELEASE: Sweep or pick up and dispose of in a solid waste container.
Title: PFA PRODUCTS Page: 3 Of 5 SECTION VII- Handling and Storage NORMAL HANDLING: Product is physiologically inert and non-toxic at normal temperatures. Above 270 o C, some decomposition of PFA products can be expected with evolution of gaseous and particulate products, which are toxic if inhaled. This can give rise to a characteristic syndrome with influenza type symptoms known as polymer fume fever. These symptoms subside within 24-48 hours away from further exposure with no long-term effects. Keep away from ignition sources- do not smoke while using Fluoropolymers. STORAGE RECOMMENDATIONS: Store in a clean, dry, dust free environment to maintain material cleanlinesspreferably in its original packaging. SECTION VIII- Exposure Controls/Personal Protection VENTILATION: Ensure good ventilation or exhaust if there is the possibility of fumes being evolved. Not required if material is used within specified processing parameters. FIRE AND EXPLOSION: Not applicable PERSONAL PROTECTIVE EQUIPMENT: None required if material is used within specified processing parameters. Normal safety equipment should always be used in an industrial environment. ADDITIONAL RECOMMENDATIONS: Heat resistant clothing and skin covering when working with hot product. Do not smoke while handling material. Keep tobacco products away from sources of contamination: hands and clothes. EXPOSURE GUIDELINES/LIMITS: Not applicable OTHER EXPOSURE LIMITS FOR POTENTIAL DECOMPOSITION PRODUCTS: Not available. SECTION IX- Physical and Chemical Properties APPEARANCE: Transparent or translucent film, tubing, or rod PHYSICAL STATE: Solid ODOR: Odorless SPECIFIC GRAVITY (H 2 O = 1): 2.12-2.17 SOLUBILITY IN WATER (weight %): Insoluble PH: Not applicable BOILING POINT: Not applicable MELTING POINT: 302-310 o C VAPOR PRESSURE: Not applicable VAPOR DENSITY: Not applicable EVAPORATION RATE: Not applicable % VOLATILES: <1% IGNITION TEMPERATURE: N/A FLASH POINT: Does not flash THERMAL DECOMPOSITION: See Section X.
Title: PFA PRODUCTS Page: 4 Of 5 SECTION X- Stability and Reactivity CHEMICAL STABILITY: Stable. Thermal degradation can begin at 270 o C. INCOMPATIBILITIES/REACTS: Reacts with molten alkali metals and interhalogen compounds. Will burn in atmosphere of 95% oxygen when an ignition source is present. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition will evolve hydrogen fluoride and perfluoroolefins. HAZARDOUS POLYMERIZATION: Will not occur. SECTION XI- Toxicological Information GENERAL: No potential health hazards when used within processing guidelines. Fluoropolymers are physiologically inert and are considered non-toxic. IMMEDIATE (ACUTE) EFFECTS: See section III. DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS: None known TOXICITY OF PRODUCT: Non-toxic when used within recommended guidelines. OTHER DATA: None. SECTION XII- Ecological Information No known harmful effects on the environment. SECTION XIII- Disposal Considerations Clean material may be recycled. Dispose of Fluoropolymer material as solid waste according to local regulations. Dispose of packaging as solid waste according to local regulations. This information relates only to uncontaminated product. If used in a process, which contaminates product, then disposal considerations should be re-evaluated.
Title: PFA PRODUCTS Page: 5 Of 5 SECTION XIV- Transport Information DOT designation: Not hazardous UN No.: Not determined ICAO/IATA: Not hazardous There is no known transportation requirements associated with this material in the form supplied based on currently available data. SECTION XV- Regulatory Information There is no known regulatory requirements associated with this material in the form supplied based on currently available data. SECTION XVI- Other Information This material safety data sheet was prepared in compliance with US OSHA Hazard Communication Standard 29CFR 1910.1200 and the European Council Directive 91/155/EEC, 67/548 and 88/379/EEC as well as their relevant amendments, on the approximation of laws, regulations and administrative provisions relative to the classification, packaging and labeling of dangerous substances and preparations. The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof; however, Saint-Gobain Performance Plastics Corporation makes no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assumes no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user s own assessment of workplace risks as required by other health and safety legislation.