Electrical Solutions Corporation 2368 Eastman Ave, Suite 13, Ventura, CA Phone (805) ~ Fax (805)

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Gas Chromatograph Operation Gas Company GC Initial setup - 6 Feb 2007 The Gas Company Gas Chromatograph (GC) data now come into Wonderware and can be accessed from the Gas Chrom button on the Wonderware Menu Bar. The Gas Chromatograph page displays all the alarms and shutdowns associated with the gas chromatograph, as well as the analog values of the most important gas stream components. (More data can be found on the Detail page). The Gas Company GC takes samples roughly every 8 minutes. (The actual sample rate seems to fluctuate in a 5-part cycle: 495 seconds, 495 seconds, 511 seconds, 495 seconds, 404 seconds and then repeating...) If the GC sample indicates that any of the gas values are above their Gas Company shutdown setpoints, then the Gas Quality Shutdown bit is set and an alarm is generated, but the Gas Shipping Valve does not shut down, yet: it takes (2) bad samples to close the valve and (1) good sample to open it back up. If the second sample is also bad, then the Gas Shipping Valve closes. ALARMS There are 4 alarms which are provided to give the operators a better understanding of what is going on with the GC. These are for information only. No operator action is required. Low Helium (this is used to purge / calibrate the GC) Low Cal Gas (this will invalidate the daily GC calibration) AC Power (active only after a power failure when the UPS has totally drained) GC Fail (this is a type of equipment failure) SHUTDOWNS NON-LATCHING A non-latching shutdown occurs when gas quality is out of spec for 2 cycles of the Gas Company gas chromatograph. After the first cycle, an alarm is generated to alert operators to the out-of-spec condition. After the second cycle, the Shipping Valve is closed. After one good cycle, the valve is reopened. Component Shutdown Setpoint O 2 2000 ppm CO 2 3 % Total Inerts 4 % Dry BTU High 1150 Dry BTU Low 970 Benzene 200 ppm H 2 S 4 ppm Electrical Page 1 of 6 Date Printed 01/07/08

SHUTDOWNS LATCHING Critical shutdowns do not require 2 cycles of the GC before they shutdown. In fact, they are not related to the GC at all. They indicate a serious condition which MUST be resolved. The Shipping Valve will be immediately closed and locked-out. This type of a latching shutdown requires that the operators call the Gas Co. A service technician will be dispatched. Once he has verified that the equipment is operating correctly he will reset the shutdown and the Shipping Gas Valve will open as long as the gas quality is good. High H2S Shutdown (this come from the Del Mar) H2S Fail (this also comes from the Del Mar) Odorant Shutdown (this comes from the YZ Odorant Injection skid Electrical Page 2 of 6 Date Printed 01/07/08

1. The H button opens the Historical Trend window. 2. The Detail button opens the Detail window showing additional, non-critical, values for the gas stream, e.g., methane or ethane. 3. The Gas Chrom button opens this window (the Gas Chromatograph window). 4. Seconds Since Last Update counts the number of seconds since the PLC numbers have changed. If the PLC loses communications with the GC this number will just keep counting. Usually this number resets to 0 after 400-500 seconds. 1. The analog values of O2, CO2, Inerts, BTU, Benzene, and H2S are shown in blue. When any of these values rises above the Venoco alarm setpoints, the background changes to yellow and a process alarm is initiated. 2. There are 2 separate solenoid valves at the gas shipping area which control the same shutdown valve. If either of these SOVs are activated, the appropriate box will appear in red and the display will read Closed. Electrical Page 3 of 6 Date Printed 01/07/08

1. The Alarm and Clear setpoints are driven by the company PLC. These are hard-coded into the PLC, but they can be changed by the programmer if Operations decides that different setpoints will provide for better operator control. 2. The background color for the analog values is determined by the company alarm setpoints, not the Gas Co. shutdown setpoints. 3. When any of these analog values exceed the Gas Co. shutdown setpoints, an alarm is generated, and the Gas Quality background changes to red. The text changes from Normal to Shutdown. 4. This means that at least 1 bad sample has been detected, NOT that the sales gas valve is closed! Electrical Page 4 of 6 Date Printed 01/07/08

1. The Shutdown setpoints for Gas Quality are driven by the Gas Co. gas chromatograph. These setpoints are not adjustable. If any of the analog values rises above its setpoint, the GC trips the Gas Quality Shutdown Bit. 2. When this happens, the background for the Gas Quality shutdown turns red. This will happen after the first bad sample to the GC, but the Gas Quality SOV will still show Open until after the 2 nd bad sample. 3. After the second bad sample, the Gas Quality SOV will show Closed. 4. Once the Gas Quality at the GC clears the Gas Quality SOV will show Open and the Gas Quality will again show Normal. 5. At least one analog value will probably still be yellow. It will stay yellow until it drops below the Alarm Clear setpoint. Electrical Page 5 of 6 Date Printed 01/07/08

Helium, Cal Gas, AC Power, and GC Fail are Gas Co. alarms and are only provided to give the operators a better understanding of what is going on with the GC. No operator action is required. 1. The Gas Quality Shutdown is a non-latching shutdown. It takes 2 bad samples to close, 1 good sample to open. The valve opens automatically. 2. The High H2S Shutdown, H2S Fail, and Odorant Shutdown are all latching shutdowns. Operators need to call the Gas Co. and have them come out and reset their equipment before the Gas Shipping Valve will reopen. 3. I believe all 3 latching shutdowns will close the H2S SOV, but I am not sure. Need to verify with the Gas Co. Electrical Page 6 of 6 Date Printed 01/07/08