Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1 Page 1 of 1 ENDU PTFE D148A sds no. : 364308 Revision: 03.02.2010 printing date: 24.03.2010 1. Identification of the substance/preparation and of the company/undertaking Trade name: ENDU PTFE D148A Intended use: Dry film lubricant Company name: Henkel Nederland Acheson B.V. Haven Noordzijde 6 9679 TC Scheemda Netherlands Phone: +31 (597) 670 500 Fax-no.: +31 (597) 670 599 E-mail address of person responsible for Safety Data Sheet: ua-productsafety.uk@uk.henkel.com Emergency information: 24 Hours Emergency Tel: +44 (0)20 8312 0291 2. Hazards identification R11 Highly flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product is classified as hazardous within the meaning of the valid (EU) preparation directive. Base substances of preparation: organic solvent Pigment 3. Composition / information on ingredients Declaration of ingredients according to (EC) No 1907/2006:
ENDU PTFE D148A Page 2 of 2 Hazardous components CAS-No. Ethyl acetate 141-78-6 2-methoxy-1-methylethyl acetate Xylene - mixture of isomeres trizinc bis(orthophosphate) 7779-90-0 EINECS ELINCS content Classification 205-500-4 10-25 % F - Highly flammable; R11 Xi - Irritant; R36 R66 R67 203-603-9 10-25 % R10 215-535-7 1-5 % Xn - Harmful; R20/21 Xi - Irritant; R38 R10 231-944-3 < 1 % N - Dangerous for the environment; R50/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. Inhalation: Fresh air, consult doctor. 4. First aid measures Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. In case of adverse health effects seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Combustion behaviour: In case of fire toxic gases can be released. Suitable extinguishing media: foam, extinguishing powder, carbon dioxide. water spray jet 5. Fire fighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet Special protection equipment for firefighters: Wear self-contained breathing apparatus. In case of fire, keep containers cool with water spray. General information: Keep away from sources of ignition and naked flames. Personal precautions: Take great care to avoid inhalation of the aerosol. Wear protective equipment. Ensure adequate ventilation. Avoid contact with skin and eyes. See advice in chapter 8 Environmental precautions: Do not empty into drains / surface water / ground water. Do not allow to enter the ground / soil. 6. Accidental release measures
ENDU PTFE D148A Page 3 of 3 Clean-up methods: Wipe up using absorbent material and subject to waste incineration. 7. Handling and storage Handling: Ensure good ventilation/suction at the workplace. Open and handle container with care. Avoid naked flames, sparking and sources of ignition. Avoid skin and eye contact. Take measures to prevent the build-up of electrostatic charges. Do not spray against flames or glowing bodies. Keep away from sources of ignition - no smoking. Storage: Ensure good ventilation/extraction. No particular measures required. 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis UK s Ingredient ppm mg/m3 Type Category Remarks ETHYL ACETATE 200 Time Weighted Average 141-78-6 ETHYL ACETATE 400 Short Term Exposure 141-78-6 1-METHOXYPROPYL ACETATE 100 548 Short Term Exposure 1-METHOXYPROPYL ACETATE Skin designation: Can be absorbed through the 1-METHOXYPROPYL ACETATE 50 274 Time Weighted Average 2-METHOXY-1- METHYLETHYLACETATE 100 550 Short Term Exposure 2-METHOXY-1- METHYLETHYLACETATE 2-METHOXY-1- METHYLETHYLACETATE XYLENE, MIXED ISOMERS, PURE XYLENE, MIXED ISOMERS, PURE XYLENE, MIXED ISOMERS, PURE XYLENE, O-, M-, P- OR MIXED ISOMERS XYLENE, O-, M-, P- OR MIXED ISOMERS XYLENE, O-, M-, P- OR MIXED ISOMERS CHROMIUM (I) COMPOUNDS (AS CR) 1308-38-9 CHROMIUM METAL, INORGANIC CHROMIUM() COMPOUNDS AND INORGANIC CHROMIUM(I) COMPOUNDS (INSOLUBLE) 1308-38-9 Skin designation: 50 275 Time Weighted Average 50 221 Time Weighted Average 100 442 Short Term Exposure Skin designation: 50 220 Time Weighted Average Skin designation: 100 441 Short Term Exposure 0,5 Time Weighted Average 2 Time Weighted Average Can be absorbed through the Can be absorbed through the Can be absorbed through the
ENDU PTFE D148A Page 4 of 4 Engineering controls: Ensure good ventilation/suction at the workplace. Respiratory protection: if there is atomisation Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (R; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (R; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. Skin protection: Wear suitable protective clothing. General protection and hygiene measures: Keep away from food, beverages and animal feed. Immediately remove soiled or soaked clothing. Do not eat, drink or smoke while working. Avoid skin and eye contact. 9. Physical and chemical properties General characteristics: Appearance Odor: liquid Liquid Green Solvent Phys./chem. properties: ph-value Not applicable Boiling point 77 C (170.6 F) Flash point -4 C (24.8 F) Viscosity (dynamic) 100-200 mpa.s (Epprecht (rotary viscosity); Instrument: Epprecht TVB; 20 C (68 F); speed of rotation: 200 min-1) VOC content 48,7 % (1999/13/EC) Conditions to avoid: None if used for intended purpose. Materials to avoid: Reaction with oxidants. Hazardous decomposition products: In case of fire toxic gases can be released. 10. Stability and reactivity
ENDU PTFE D148A Page 5 of 5 11. Toxicological information Inhalative toxicity: The toxicity of the product is due to its narcotic effect after inhalation. Irritating to respiratory system cannot be excluded after longer or repeated exposure. Skin irritation: Prolonged or repeated skin contact can lead to skin degreasing and hence to skin irritation. Eye irritation: Irritating to eyes. 12. Ecological information Ecotoxicity: Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Ecotoxicity: Hazardous components CAS-No. trizinc bis(orthophosphate) 7779-90-0 Species Exposure Value Value time type Trout family (Salmonidae) 96 h LC 50 0,09 mg/l General ecological information: Do not empty into drains / surface water / ground water. 13. Disposal considerations Product disposal: Waste incineration with the approval of the responsible local authority. Waste code(ewc ): The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. 080111 Road transport ADR: 14. Transport information Classification code: F1 Hazard ident. number: 33 Technical name: Tunnelcode: (D/E) Special provision 640D
ENDU PTFE D148A Page 6 of 6 Railroad transport RID: Classification code: F1 Hazard ident. number: 33 Technical name: Tunnelcode: Inland water transport ADN: Special provision 640D Classification code: F1 Hazard ident. number: Technical name: Special provision 640D Marine transport IMDG: EmS: F-E,S-E Seawater pollutant: - Proper shipping name: Air transport IATA: Packaging instructions (passenger) 305 Packaging instructions (cargo) 307 Proper shipping name: Flammable liquid, n.o.s. (Ethyl acetate,methoxy propyl Indication of danger: F - Highly flammable Xi - Irritant 15. Regulations - classification and identification
ENDU PTFE D148A Page 7 of 7 Risk phrases: R11 Highly flammable. R36 Irritating to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S23 Do not breathe vapour/spray. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S29 Do not empty into drains. S38 In case of insufficient ventilation, wear suitable respiratory equipment. In case of fire, use waterspray, powder, foam or carbon dioxide S56 Dispose of this material and its container to hazardous or special waste collection point. National regulations/information (Great Britain): Remarks Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, e.g COSHH Essentials. EH40 Occupational Exposure Limits Chemicals (Hazard Information & Packaging for Supply) Regulations. The Personnel Protective Equipment at Work Regulations. The Carriage of Dangerous Goods by Road Regulations. The Health & Safety at Work Act 1974. (Note: Use latest editions/amendments of above referenced documents.) 16. Other information The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R10 Flammable. R11 Highly flammable. R20/21 Harmful by inhalation and in contact with R36 Irritating to eyes. R38 Irritating to R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.