Revision Date 1122014 1 Revision 1 Supersedes date 05112014 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING 1.1. Product identifier Product name CAS-No. 7722-84-1 EU Index No. 008-003-00-9 EC No. 231-75-0 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Manufacture of substances. Professional use Laboratory agent 1.3. Details of the supplier of the safety data sheet Supplier Industrial Chemicals Limited Hogg Lane Grays Essex RM17 5DU United Kingdom T:+44 (0)1375 389000 F:+44 (0)1375 389110 sds@icgl.co.uk 1.4. Emergency telephone number +44 (0)185 407333 (24-hour) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (EC 12722008) Physical and Chemical Hazards Not classified. Human health Acute Tox. 4 - H302;Skin Irrit. 2 - H315;Eye Dam. 1 - H318;STOT SE 3 - H335 Environment Not classified. Classification (199945EEC) Xn;R22. Xi;R3738, R41. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 1. 2.2. Label elements EC No. 231-75-0 Contains HYDROGEN PEROXIDE SOLUTION... % Label In Accordance With (EC) No. 12722008 Signal Word Hazard Statements Danger H302 Harmful if swallowed.
Precautionary Statements H315 Causes skin irritation. H318 H335 P271 P280 Supplementary Precautionary Statements 2.3. Other hazards P305+351+338 P270 P21 P24 Causes serious eye damage. May cause respiratory irritation. Use only outdoors or in a well-ventilated area. Wear protective glovesprotective clothingeye protectionface protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do not eat, drink or smoke when using this product. Avoid breathing vapourspray. Wash contaminated skin thoroughly after handling. P302+352 IF ON SKIN: Wash with plenty of soap and water. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 Immediately call a POISON CENTER or doctorphysician. P330 P32 Rinse mouth. Take off contaminated clothing and wash before reuse. P403+233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. 2 SECTION 3: COMPOSITIONINFORMATION ON INGREDIENTS 3.2. Mixtures HYDROGEN PEROXIDE SOLUTION... % 40-0% CAS-No.: 7722-84-1 EC No.: 231-75-0 Classification (EC 12722008) Ox. Liq. 1 - H271 Acute Tox. 4 - H302 Acute Tox. 4 - H332 Skin Corr. 1A - H314 STOT SE 3 - H335 Classification (7548EEC) R5 O;R8 C;R35 Xn;R2022 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 1. CAS-No. 7722-84-1 EU Index No. 008-003-00-9 EC No. 231-75-0 Gross Formula HOOH SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. General first aid, rest, warmth and fresh air. If respiratory problems, artificial respirationoxygen. Get medical attention. Ingestion Immediately rinse mouth and drink plenty of water (200-300 ml). DO NOT induce vomiting. Get medical attention immediately. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Continue to rinse for at least 15 minutes and seek medical attention. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Immediately transport to hospital or eye specialist. Obtain medical attention and bring these instructions. 4.2. Most important symptoms and effects, both acute and delayed
3 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. 5.2. Special hazards arising from the substance or mixture Hazardous combustion products Fire or high temperatures create: Oxygen. 5.3. Advice for firefighters Protective equipment for fire-fighters Wear self-contained breathing apparatus. SECTION : ACCIDENTAL RELEASE MEASURES.1. Personal precautions, protective equipment and emergency procedures Do not breathe vapour. Wear protective clothing as described in Section 8 of this safety data sheet..2. Environmental precautions Prevent entry into drains..3. Methods and material for containment and cleaning up Absorb with sand or other inert absorbent. Dispose of contaminated material as hazardous waste..4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapours and spray mists. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Storage tanks and day tanks must be vented to the outside atmosphere, using suitable piping. 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLSPERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes HYDROGEN PEROXIDE SOLUTION... % WEL 1 ppm 1.4 mgm3 2 ppm 2.8 mgm3 WEL = Workplace Exposure Limit. 8.2. Exposure controls Protective equipment
4 Respiratory equipment If ventilation is insufficient, suitable respiratory protection must be provided. Hand protection Protective gloves should be used if there is a risk of direct contact or splash. Eye protection Wear tight-fitting goggles or face shield. Skin protection Protection suit must be worn. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colourless liquid. Colour Colourless. Initial boiling point and boiling range 12 ( C) Melting point ( C) -40 Relative density 1.13 Vapour density (air=1) 1.17 Vapour pressure 3.11 kpa 30 9.2. Other information Mol. Weight 34 SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity No specific reactivity hazards associated with this product. 10.2. Chemical stability Stable under normal temperature conditions and recommended use. Slowly decomposes and releases oxygen. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. 10.5. Incompatible materials Materials To Avoid Powdered metal. Metals. Flammablecombustible material. Organics. 10.. Hazardous decomposition products Oxygen. Rapid heat release. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhalation Vapours irritate the respiratory system, and may cause coughing and difficulties in breathing. Ingestion May cause chemical burns in mouth and throat. Irritating. May cause nausea, stomach pain and vomiting. Skin contact Irritating to skin. Causes burns. Eye contact May cause severe irritation to eyes. Causes severe burns. Risk of corneal damage.
5 SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 12.. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADRRIDADN) 2014 UN No. (IMDG) 2014 UN No. (ICAO) 2014 14.2. UN proper shipping name Proper Shipping Name HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 0% hydrogen peroxide (stabilised as necessary) 14.3. Transport hazard class(es) ADRRIDADN Class Class 5.1: Oxidising substances. ADRRIDADN Subsidiary Risk 8 Transport Labels OXIDIZING AGENT 5.1 CORROSIVE 8 14.4. Packing group ADRRIDADN Packing group IMDG Packing group ICAO Packing group II II II 14.5. Environmental hazards Environmentally Hazardous SubstanceMarine Pollutant No.
14.. Special precautions for user Hazard No. (ADR) Tunnel Restriction Code 58 Oxidising substance (fire-intensifying), corrosive. (E) 14.7. Transport in bulk according to Annex II of MARPOL7378 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulationslegislation specific for the substance or mixture 15.2. Chemical Safety Assessment SECTION 1: OTHER INFORMATION Revision Comments Updated Section(s) 14, Issued By D.Kelly Revision Date 1122014 Revision 1 Supersedes date 05112014 Risk Phrases In Full R35 Causes severe burns. R8 Contact with combustible material may cause fire. R2022 Harmful by inhalation and if swallowed. R22 Harmful if swallowed. R5 Heating may cause an explosion. R3738 Irritating to respiratory system and skin. R37 Irritating to respiratory system. R41 Risk of serious damage to eyes. Hazard Statements In Full H318 Causes serious eye damage. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H332 Harmful if inhaled. H302 Harmful if swallowed. H271 May cause fire or explosion; strong oxidiser. H335 May cause respiratory irritation. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.