SAFETY DATA SHEET 1. Identification Product identifier Other means of identification None. Recommended use Marking. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company name ITW Marking and Coding Address 1 Missouri Research Park Drive St. Charles, MO 633045685 USA Telephone 6363002000 / 8005262531 Contact person Customer Service Emergency phone number 8005355053 (US only) +13523233500 international 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Gases under pressure Serious eye damage/eye irritation Specific target organ toxicity, repeated exposure Not classified. Compressed gas Category 2B Category 2 (Kidney) Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Contains gas under pressure; may explode if heated. Causes eye irritation. May cause damage to organs (Kidney) through prolonged or repeated exposure. Wash thoroughly after handling. Do not breathe mist or vapor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Protect from sunlight. Store in a wellventilated place. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. None. 3. Composition/information on ingredients Mixtures Chemical name Water Diethylene glycol Dipropylene glycol butyl ether Other components below reportable levels CAS number % 7732185 7097 111466 5 <10 29911282 15 8.26 928305 Version #: 01 Revision date: Issue date: 04September2015 1 / 7
4. Firstaid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Firefighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Selfcontained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. Use standard firefighting procedures and consider the hazards of other involved materials. This product is not flammable. Heat may cause the containers to explode. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during cleanup. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for reuse. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Contents under pressure. Do not puncture or incinerate container. Do not expose to heat. Avoid contact with eyes. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Use care in handling/storage. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Storage temperature: between 2 and 49 C. Store away from incompatible materials (see Section 10 of the SDS). 928305 Version #: 01 Revision date: Issue date: 04September2015 2 / 7
8. Exposure controls/personal protection Occupational exposure limits US. Workplace Environmental Exposure Level (WEEL) Guides Components Diethylene glycol (CAS 111466) Biological limit values Appropriate engineering controls Type TWA Value 10 mg/m3 No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes. Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Other Wear suitable protective clothing. Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece. In case of insufficient ventilation, wear suitable respiratory equipment. Seek advice from local supervisor. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color According to product specification. Odor Characteristic. Odor threshold ph 7.5 at 20 C. Melting point/freezing point Initial boiling point and boiling 473 F (245 C) range Flash point 294.8 F (146.0 C) Evaporation rate Flammability (solid, gas) Non flammable. Upper/lower flammability or explosive limits Flammability limit lower 0.7 % v/v (%) Flammability limit upper 22 % v/v (%) Explosive limit lower (%) Explosive limit upper (%) Vapor pressure 23 hpa at 20 C. Vapor density Relative density Solubility(ies) Solubility (water) Fully miscible. Partition coefficient (noctanol/water) Autoignition temperature Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 928305 Version #: 01 Revision date: Issue date: 04September2015 3 / 7
Decomposition temperature Viscosity Other information Density 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 1.01 g/cm3 at 20 C. The product is stable and nonreactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Contact with incompatible materials. Avoid exposing aerosol containers to high temperatures or direct sunlight. Strong oxidizing agents. Carbon oxides. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. Prolonged inhalation may be harmful. Skin contact Prolonged or repeated contact may dry skin and cause irritation. Eye contact Causes eye irritation. Ingestion May cause discomfort if swallowed. Symptoms related to the Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Causes eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity NTP Report on Carcinogens OSHA Specifically Regulated Substances (29 CFR 1910.10011050) Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity Not classified. single exposure Specific target organ toxicity May cause damage to organs (Kidney) through prolonged or repeated exposure. repeated exposure Aspiration hazard Not an aspiration hazard. Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 928305 Version #: 01 Revision date: Issue date: 04September2015 4 / 7
Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects No data is available on the degradability of this product. The product is miscible with water. May spread in water systems. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Special precautions for user Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code UN1950 Aerosols, nonflammable, (each not exceeding 1 L capacity) Not applicable. Read safety instructions, SDS and emergency procedures before handling. 306 None None UN1950 Aerosols, nonflammable Not applicable. No. 2L Read safety instructions, SDS and emergency procedures before handling. UN1950 AEROSOLS Not applicable. No. FD,SU Read safety instructions, SDS and emergency procedures before handling. Not established. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. 928305 Version #: 01 Revision date: Issue date: 04September2015 5 / 7
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) OSHA Specifically Regulated Substances (29 CFR 1910.10011050) CERCLA Hazardous Substance List (40 CFR 302.4) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard Delayed Hazard Fire Hazard No Pressure Hazard Reactivity Hazard No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK Substance List US. New Jersey Worker and Community RighttoKnow Act US. Pennsylvania Worker and Community RighttoKnow Law Diethylene glycol (CAS 111466) US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada NonDomestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 928305 Version #: 01 Revision date: Issue date: 04September2015 6 / 7
16. Other information, including date of preparation or last revision Issue date 04September2015 Revision date Version # 01 HMIS ratings Health: 1* Flammability: 1 Physical hazard: 2 NFPA ratings 1 1 0 Disclaimer ITW Marking and Coding cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. 928305 Version #: 01 Revision date: Issue date: 04September2015 7 / 7