Safety Data Sheet Revision Number: 011.1 Issue date: 11/30/2017 1. PRODUCT AND COMPANY IDENTIFICATION Product type: Cleaner Item number: M00539 Restriction of Use: identified Region: United States Company address: Henkel Corporation Henkel Way One Rocky Hill, Connecticut 06067 Contact information: Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW CAUSES SERIOUS EYE IRRITATION. EYE IRRITATION HAZARD CLASS PICTOGRAM(S) HAZARD CATEGORY 2A Precautionary Statements Prevention: Response: Storage: Disposal: Wash affected area thoroughly after handling. Wear eye and face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Not prescribed Not prescribed Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Diethylene glycol monobutyl ether 112-34-5 80-90 Dipropylene glycol monomethyl ether 34590-94-8 5-10 Glycol ether Proprietary 5-10 2-Butoxyethanol 111-76-2 0.1-1 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. Page 1 of 6
4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. Wash clothing before reuse. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Get immediate medical attention. Symptoms: See Section 11. Notes to physician: This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Contains flammable solvent. Oxides of carbon. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Evacuate personnel to safe areas. Remove all sources of ignition. Ventilate area. Wear suitable protective clothing, gloves and eye/face protection. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: Storage: Use only in well-ventilated areas. Keep away from heat, spark and flame. Wear suitable protective clothing, gloves and eye/face protection. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 6
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Diethylene glycol monobutyl ether Dipropylene glycol monomethyl ether 10 ppm TWA Inhalable fraction and vapor. 150 ppm STEL (SKIN) 100 ppm TWA (SKIN) 100 ppm (600 mg/m3) PEL 50 ppm TWA 75 ppm STEL Glycol ether 50 ppm (240 mg/m3) 2-Butoxyethanol 20 ppm TWA PEL (SKIN) Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Ensure adequate ventilation, especially in confined areas. Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Colorless Odor: Mild, Solvent Odor threshold: ph: Not applicable Vapor pressure: 0.04 mbar (20 C (68 F)) Boiling point/range: 225 C (437 F) Melting point/ range: Not determined Specific gravity: 0.95 Vapor density: Heavier than air. Flash point: 105 C (221 F) Flammable/Explosive limits - lower: 0.85 % Flammable/Explosive limits - upper: 24.6 % Autoignition temperature: 225 C (437 F) Flammability: Not applicable Evaporation rate: Solubility in water: Soluble Partition coefficient (n-octanol/water): VOC content: 100 % Viscosity: Decomposition temperature: Page 3 of 6
10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable under recommended storage conditions. Will not occur. Oxides of carbon. Irritating organic vapours. Strong oxidizing agents. Keep away from open flames, hot surfaces and sources of ignition. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Inhalation of processing fumes may be harmful. May cause skin irritation. Causes serious eye irritation. Not a relevant route of exposure. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Diethylene glycol monobutyl ether Dipropylene glycol monomethyl ether Oral LD50 (Rabbit) = 2,200 mg/kg Oral LD50 (Rat) = 4,500 mg/kg Oral LD50 (Rat) = 5,660 mg/kg Oral LD50 (Rat) = 7,292 mg/kg Oral LD50 (Mouse) = 2,400 mg/kg Oral LD50 (Rat) = 6,600 mg/kg Oral LD50 (Rat) = 6,560 mg/kg Dermal LD50 (Rabbit) = 2,700 mg/kg Dermal LD50 (Rabbit) = 4,120 mg/kg Oral LD50 (Rat) = 5.35 g/kg Dermal LD50 (Rabbit) = 9.5 g/kg Blood, Central nervous system, Irritant, Kidney Irritant Glycol ether Irritant 2-Butoxyethanol Oral LD50 (Rat) = 560 mg/kg Oral LD50 (Mouse) = 1.2 g/kg Oral LD50 (Rabbit) = 0.32 g/kg Oral LD50 (Rat) = 1.48 g/kg Oral LD50 (Mouse) = 1,519 mg/kg Dermal LD50 (Rabbit) = 400 mg/kg Inhalation LC50 (Rat, 4 h) = 486 ppm Hazardous Component(s) NTP Carcinogen IARC Carcinogen Blood, Central nervous system, Irritant, Kidney, Liver OSHA Carcinogen (Specifically Regulated) Diethylene glycol monobutyl ether No No No Dipropylene glycol monomethyl ether No No No Glycol ether No No No 2-Butoxyethanol No No No 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6
13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated Not regulated 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimis above reporting de minimis. Immediate Health, Delayed Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Diethylene glycol monobutyl ether (CAS# 112-34-5). 2-Butoxyethanol (CAS# 111-76-2). No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Product Safety and Regulatory Affairs Issue date: 11/30/2017 Page 5 of 6
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6