Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Glass Cleaner Product dilution information : 3.13 % - 6.25 % Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park, NSW Australia 2113 1 800 022 002 Emergency telephone number : 1800 205 506, +64 7 958 2372 Issuing date : 23.10.2015 Section: 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 4 Serious eye damage/eye : Category 2A irritation Specific target organ toxicity - : Category 3 (Central Nervous System) single exposure Not a hazardous substance or mixture. GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Warning : Combustible liquid Causes serious eye irritation. May cause drowsiness or dizziness. : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/ eye protection/ face protection. Response: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously 910578-01 1 / 9
with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Storage: Store in a well-ventilated place. Keep container tightly closed. Disposal: Dispose of contents/ container to an approved waste disposal plant. Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) GLYCOLS -Glycolethers 1569-01-3 10-30 monoethanolamine 141-43-5 1-5 sulfuric acid, mono-c10-16-alkyl esters, sodium salts 68585-47-7 1-5 Chemical Name CAS-No. Concentration: (%) GLYCOLS -Glycolethers 1569-01-3 1-5 Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Rinse with plenty of water. : Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766). Rinse mouth. Get medical attention if symptoms occur. If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. 910578-01 2 / 9
In case of eye contact In case of skin contact If swallowed : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766). If inhaled : Get medical attention if symptoms occur. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) metal oxides : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. 910578-01 3 / 9
Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Use only with adequate ventilation. Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Wash hands thoroughly after handling. : Keep away from heat and sources of ignition. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 C to 50 C Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration monoethanolamine 141-43-5 TWA 3 ppm 7.5 mg/m3 VLE 6 ppm 15 mg/m3 Basis AU OEL AU OEL Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : Safety glasses with side-shields : Impervious gloves : No special protective equipment required. : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. 910578-01 4 / 9
Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Colour : blue light blue Odour : pungent pungent ph : 10.7, 100 % 10.4-10.5 Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density : 0.996 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : 62 C closed cup Section: 10. STABILITY AND REACTIVITY 910578-01 5 / 9
Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Heat, flames and sparks. : Acids : No decomposition if stored and applied as directed. Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye irritation. : Inhalation may cause central nervous system effects. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact : Redness, Pain, Irritation : Dizziness, Drowsiness 910578-01 6 / 9
Ingestion Inhalation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity : Acute toxicity estimate : > 2,000 mg/kg : 4 h Acute toxicity estimate : > 5 mg/l : Acute toxicity estimate : > 2,000 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Components Toxicity to fish Components Toxicity to daphnia and other aquatic invertebrates : This product has no known ecotoxicological effects. : GLYCOLS -Glycolethers 96 h LC50 Fish: > 100 mg/l : monoethanolamine 48 h EC50 Daphnia: 65 mg/l sulfuric acid, mono-c10-16-alkyl esters, sodium salts 48 h EC50 Daphnia: 1.37 mg/l Persistence and degradability no data available Bioaccumulative potential 910578-01 7 / 9
no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ADG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Not intended for transport. Section: 15. REGULATORY INFORMATION National regulatory information Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated The components of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : 910578-01 8 / 9
On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : Section: 16. OTHER INFORMATION Sources of key data used to compile the Safety Data Sheet Globally Harmonized System of Classification and Labelling of Chemicals (GHS) IARC: (International Agency for Research on Cancer) US. National Toxicology Program (NTP) Report on Carcinogens ECHA List of Publishable Substances Registered EU HPVCs (High Production Volume Chemicals) Issuing date : 23.10.2015 Date of first issue : 23.10.2015 version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 910578-01 9 / 9