SAFETY DATA SHEET FIRST MARK RESTROOM CLEANER WITH BLEACH Section 1. Chemical product and company identification Product name Recommended use and restrictions FIRST MARK RESTROOM CLEANER WITH BLEACH Cleaning product Use only for the purpose on the product label. Product dilution information Not applicable Supplier's information Performance Food Group 125 Westcreek Pkwy Richmond, VA 23238 (888) 311-7372 ~ Fax (84) 784-576 Code Date of issue 91194-3 14 Nov 213 EMERGENCY HEALTH INFORMATION 1-8-535-553 Section 2. Hazards identification GHS Classification CORROSIVE TO METALS - Category 1 GHS label elements Signal word Symbol Warning Hazard statements May be corrosive to metals. Precautionary statements Prevention Response Storage Disposal Other hazards Keep only in original container. Absorb spillage to prevent material damage. Store in corrosive resistant container with a resistant inner liner. See section 13 for waste disposal information. None known. Section 3. Composition/information on ingredients Substance/mixture Mixture Hazardous ingredients Concentration Range (%) CAS number sulfuric acid, monooctyl ester, sodium salt 1-5 142-31-4 Page 1/6
FIRST MARK RESTROOM CLEANER WITH BLEACH 14 Nov 213 Section 3. Composition/information on ingredients Hazardous ingredients Section 4. First aid measures Eye contact No known effect after eye contact. Rinse with water for a few minutes. Skin contact No known effect after skin contact. Rinse with water for a few minutes. Inhalation No special measures required. Treat symptomatically. Ingestion Get medical attention if symptoms occur. Concentration Range (%) CAS number Protection of firstaiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. See toxicological information (section 11) Section 5. Fire-fighting measures Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Specific fire-fighting methods Special protective equipment for fire-fighters Personal precautions Environmental precautions Methods for cleaning up Use water spray, fog or foam. Section 6. Accidental release measures In a fire or if heated, a pressure increase will occur and the container may burst. Decomposition products may include the following materials carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Page 2/6
FIRST MARK RESTROOM CLEANER WITH BLEACH 14 Nov 213 Section 7. Handling and storage Handling Storage Control parameters Hygiene measures Wash thoroughly after handling. Keep out of reach of children. Store between the following temperatures and 4 C Section 8. Exposure controls/personal protection Ingredient name None. Appropriate Good general ventilation should be sufficient to engineering controls control worker exposure to airborne contaminants. Personal protection Eye protection No protective equipment is needed under normal use conditions. Hand protection No protective equipment is needed under normal use conditions. Skin protection No protective equipment is needed under normal use conditions. Respiratory A respirator is not needed under normal and protection intended conditions of product use. Physical state Color Melting point Boiling point Evaporation rate (butyl acetate = 1) Vapor pressure Vapor density Relative density Solubility Exposure limits Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Section 9. Physical and chemical properties Liquid. Colorless Odor ph Fragrance-like 11.8 to 13 (1%) Flash point > 1 C Product does not support combustion. Explosion limits Flammability (solid, gas) >1 C (>212 F) 1.6 to 1.26 (Water = 1) Easily soluble in the following materials cold water and hot water. Page 3/6
FIRST MARK RESTROOM CLEANER WITH BLEACH 14 Nov 213 Section 9. Physical and chemical properties Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Odor threshold Viscosity Stability Possibility of hazardous reactions Hazardous decomposition products Kinematic (room temperature) cm 2 /s ( cst) Section 1. Stability and reactivity Conditions to avoid No specific data. Materials to avoid Extremely reactive or incompatible with the following materials metals and acids. Section 11. Toxicological information Route of exposure Symptoms Eye contact No specific data. Skin contact No specific data. Inhalation Ingestion Acute toxicity Eye contact Skin contact Inhalation Ingestion Toxicity data The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Product/ingredient name sulfuric acid, monooctyl ester, sodium salt LD5 Dermal Rabbit >5 mg/kg LD5 Oral Rat 2175 mg/kg Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Skin contact, Eye contact, Inhalation, Ingestion No specific data. No specific data. Page 4/6
FIRST MARK RESTROOM CLEANER WITH BLEACH 14 Nov 213 Section 12. Ecological information Ecotoxicity Aquatic and terrestrial toxicity Product/ingredient name Result Species Exposure sulfuric acid, monooctyl ester, sodium salt Acute EC5 31 mg/l Daphnia 48 hours Other adverse effects Disposal methods Section 13. Disposal considerations RCRA classification Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Unused product is D2 (Corrosive) Section 14. Transport information Not intended for transport. Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG IMO/IMDG Classification Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 32/34/311/312 extremely hazardous substances No listed substance SARA 32/34 emergency planning and notification No listed substance SARA 313 Product name CAS number Concentration Form R - Reporting requirements California Prop. 65 No listed substance No listed substance Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards Page 5/6
FIRST MARK RESTROOM CLEANER WITH BLEACH 14 Nov 213 Section 16. Other information National Fire Protection Association (U.S.A.) Flammability Health Instability/Reactivity Special Date of issue Prepared by 14 Nov 213 Regulatory Affairs 1-8-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 6/6