SAFETY DATA SHEET FIRST MARK ECO PINK PINK DISH DETERGENT Section 1. Chemical product and company identification Product name Recommended use and restrictions FIRST MARK ECO PINK PINK DISH DETERGENT Manual Warewashing Detergent Use only for the purpose on the product label. Product dilution information.5% Supplier's information Code Date of issue Section 2. Hazards identification Performance Food Group 125 West Creek Parkway Richmond VA 23238 (84) 484-77 ~ Fax (84) 484-7976 915647 2 Feb 213 EMERGENCY HEALTH INFORMATION 1-8-535-553 GHS Classification GHS label elements Signal word SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B AQUATIC TOXICITY (ACUTE) - Category 3 Warning Not classified. No signal word. Hazard statements Causes eye irritation. Harmful to aquatic life. Precautionary statements Prevention Response Storage Disposal Other hazards Avoid release to the environment. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical attention. No other specific measures identified. See section 13 for waste disposal information. None known. Wash thoroughly after handling. Get medical attention if symptoms appear. No other specific measures identified. See section 13 for waste disposal information. None known. Section 3. Composition/information on ingredients Substance/mixture Mixture Hazardous ingredients Concentration Range (%) CAS number SODIUM CHLORIDE 1-5 7647-14-5 poly(oxy-1,2-ethanediyl),.alpha.-sulfo-.omega.-hydroxy-, 1-5 68585-34-2 c1-16-alkyl ethers, sodium salts COCAMINE OXIDE <1. 61788-9-7 Page 1/6
FIRST MARK ECO PINK PINK DISH DETERGENT 2 Feb 213 Section 3. Composition/information on ingredients Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in quantities requiring reporting, in accordance with local regulations. Section 4. First aid measures Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists. Skin contact No known effect after skin contact. Rinse with water for a few minutes. Inhalation No special measures required. Treat symptomatically. Ingestion Get medical attention if symptoms occur. Protection of firstaiders Notes to physician See toxicological information (section 11) Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Specific fire-fighting methods Special protective equipment for fire-fighters No known effect after eye contact. Rinse with water for a few minutes. No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Section 5. Fire-fighting measures Personal precautions Environmental precautions Methods for cleaning up Use water spray, fog or foam. Section 6. Accidental release measures In a fire or if heated, a pressure increase will occur and the container may burst. This material is harmful to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Decomposition products may include the following materials halogenated compounds metal oxide/oxides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Page 2/6
FIRST MARK ECO PINK PINK DISH DETERGENT 2 Feb 213 Section 7. Handling and storage Handling Storage Control parameters Hygiene measures Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep out of reach of children. Keep container tightly closed. Store between the following temperatures 5 and 5 C Section 8. Exposure controls/personal protection Ingredient name None. Appropriate Good general ventilation should be sufficient to engineering controls control worker exposure to airborne contaminants. Personal protection Eye protection No protective equipment is needed under normal use conditions. Hand protection No protective equipment is needed under normal use conditions. Skin protection No protective equipment is needed under normal use conditions. Respiratory A respirator is not needed under normal and protection intended conditions of product use. Physical state Color Odor Fragrance-like ph 7 to 1 (1%) Flash point > 1 C Melting point Boiling point Evaporation rate (butyl acetate = 1) Vapor pressure Vapor density Relative density Solubility Wash thoroughly after handling. Keep out of reach of children. Exposure limits Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. A respirator is not needed under normal and intended conditions of product use. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Section 9. Physical and chemical properties Explosion limits (solid, gas) Liquid. pink >1 C (>212 F) 1.24 to 1.44 (Water = 1) Easily soluble in the following materials cold water and hot water. Liquid. Clear Fragrance-like 6 to 8 > 1 C Page 3/6
FIRST MARK ECO PINK PINK DISH DETERGENT 2 Feb 213 Section 9. Physical and chemical properties Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Odor threshold Viscosity Stability Possibility of hazardous reactions Hazardous decomposition products Section 1. Stability and reactivity Conditions to avoid Materials to avoid Route of exposure Ingestion Acute toxicity Eye contact Skin contact Inhalation Ingestion Toxicity data Section 11. Toxicological information The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Skin contact, Eye contact, Inhalation, Ingestion Symptoms Eye contact Adverse symptoms may include the following irritation watering redness Skin contact Inhalation Causes eye irritation. Product/ingredient name Result Species Dose sodium chloride LC5 Inhalation Dusts Rat >1.5 mg/l and mists LD5 Dermal Rabbit >1 mg/kg LD5 Oral Rat 3 mg/kg poly(oxy-1,2-ethanediyl),.alpha.-sulfo-. LD5 Dermal Rat >2 mg/kg omega.-hydroxy-, c1-16-alkyl ethers, sodium salts LD5 Oral Rat >25 mg/kg amines, coco alkyldimethyl, n-oxides LD5 Dermal Rat >2174 mg/kg LD5 Oral Rat 846 mg/kg Page 4/6
FIRST MARK ECO PINK PINK DISH DETERGENT 2 Feb 213 Section 11. Toxicological information Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Section 12. Ecological information Ecotoxicity This material is harmful to aquatic life. Aquatic and terrestrial toxicity Product/ingredient name Result Species Exposure sodium chloride Acute LC5 584 mg/l Fish 96 hours poly(oxy-1,2-ethanediyl),.alpha.-sulfo-.omega.- Acute LC5 28 mg/l Fish 96 hours hydroxy-, c1-16-alkyl ethers, sodium salts amines, coco alkyldimethyl, n-oxides Acute LC5 <1 mg/l Fish 96 hours Other adverse effects Section 13. Disposal considerations Disposal methods Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG IMO/IMDG Classification Not intended for transport. Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 32/34/311/312 extremely hazardous substances No listed substance SARA 32/34 emergency planning and notification No listed substance SARA 313 Product name CAS number Concentration Form R - Reporting requirements California Prop. 65 No listed substance No listed substance Page 5/6
FIRST MARK ECO PINK PINK DISH DETERGENT 2 Feb 213 Section 16. Other information Hazardous Material Information System (U.S.A.) Health * 1 Health Physical hazards Physical hazards National Fire Protection Association (U.S.A.) Health 1 Instability/Reactivity Health Instability/Reactivity Special Special Date of issue Prepared by 2 Feb 213 Regulatory Affairs 1-8-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 6/6