: CPR Log Cleaner and Brightener

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Transcription:

Date of issue: 08/28/2015 Revision date: 08/28/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product code : CPR Log Cleaner and Brightener : Not available 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Sashco Inc 10300 E. 107th Place Brighton, CO 80601 - USA T 303.286.7271 info@sashco.com 1.4. Emergency telephone number Emergency number : 800.535.5053 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Oxidizing solid 2 Acute Toxicity 4 (Oral) Eye Irritation 2A 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : : Cleaning, Brightening Agent for Wood Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS03 GHS07 : May intensify fire; oxidizer. Harmful if swallowed. Causes serious eye irritation : Keep away from heat. Keep/Store away from clothing, combustible materials. Take any precaution to avoid mixing with combustibles. Wear protective gloves/eye protection/face protection. Wash hands thoroughly after handling Do not eat, drink or smoke when using this product. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Dispose of contents/container to in accordance with local/regional/national/international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Sodium percarbonate (CAS No) 15630-89-4 40-70 Disodium carbonate (CAS No) 497-19-8 15-40 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of 1910.1200. 08/28/2015 EN (English) Page 1

SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. : If irritation occurs, flush skin with plenty of water. Get medical attention if irritation persists. : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Rinse mouth. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause respiratory tract irritation. : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. : Harmful if swallowed. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : CO2, foam or Water fog. : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard : May intensify fire; oxidiser. Products of combustion may include, and are not limited to: oxides of carbon. : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Fight fire remotely due to the risk of explosion. : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures 6.2. Methods and material for containment and cleaning up For containment Methods for cleaning up 6.3. Reference to other sections : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). : Scoop up material and place in a disposal container. See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions : Hazardous waste due to potential risk of explosion. : Avoid contact with skin and eyes. Avoid breathing dust. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Take any precaution to avoid mixing with combustibles. Use only in well-ventilated areas. : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. : Proper grounding procedures to avoid static electricity should be followed. : Keep out of the reach of children. Keep container tightly closed. Keep in fireproof place. Store at room temperature away from direct sunlight or other heat sources. 08/28/2015 EN (English) 2/5

Incompatible materials : Heat sources. Combustible materials. Strong oxidizers. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Sodium percarbonate (15630-89-4) ACGIH OSHA Disodium carbonate (497-19-8) ACGIH OSHA 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls Other information : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. : Wear chemically resistant protective gloves. : Wear safety glasses with side shields or goggles. : Wear suitable protective clothing. : In case of insufficient ventilation to maintain airborne fly ash levels below the exposure limits, wear suitable NIOSH-approved, properly fitted respiratory equipment. : Maintain levels below Community environmental protection thresholds. : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Powder Colour : white Odour : No odor Odour threshold ph in a 10% solution : 10.5 Melting point Freezing point Boiling point Flash point Relative evaporation rate (butylacetate=1) Flammability (solid, gas) : Not flammable Explosive limits Explosive properties Oxidising properties : May intensify fire; oxidiser. Vapour pressure Relative density : 1.3 (Bulk density) Relative vapour density at 20 C Solubility Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 08/28/2015 EN (English) 3/5

9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May intensify fire; oxidizer. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if swallowed. CPR Log Cleaner and Brightener LD50 dermal rabbit LC50 inhalation rat Sodium percarbonate (15630-89-4) Disodium carbonate (497-19-8) LC50 inhalation rat > 300 but 2000 mg/kg No data available No data available 1034 mg/kg 4090 mg/kg 2300 mg/m³/2h Skin corrosion/irritation Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause respiratory tract irritation. : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. : Harmful if swallowed. May cause stomach distress, nausea or vomiting. : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 08/28/2015 EN (English) 4/5

12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations Additional information SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT UN-No.(DOT) Proper Shipping Name (DOT) : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Dispose of contents/container to in accordance with local/regional/national/international regulations. : Hazardous waste due to potential risk of explosion. : UN1479 Transport hazard class(es) (DOT) : 5.1 Hazard labels (DOT) : : Oxidizing solid, n.o.s. (Sodium percarbonate) Packing group (DOT) : II Additional information Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations 15.2. US State regulations CPR Log Cleaner and Brightener State or local regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Date of issue : 08/28/2015 Revision date : 08/28/2015 Other information : None. Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. 08/28/2015 EN (English) 5/5