Process Safety Value and Learnings Central Valley Chemical Safety Day March 20, 2014

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Process Safety Value and Learnings Central Valley Chemical Safety Day March 20, 2014 Randy Bennett Sr. Staff Health & Safety Engineer Process Safety Management Group Aera Energy LLC

Key Points Process Safety compliance experience and risks A look at one Process Safety leverage point Future direction and activities

Process Safety is: A practice for ensuring containment of chemicals and other hazardous substances. The PSM practice allows for the proactive identification, evaluation and mitigation of releases that could occur as a result of failures in process, procedure or equipment.

Experience and risks Flixborough, England, June 1, 1974 Mexico City, Mexico, November 19, 1984 Bhopal, India, December 3, 1984 Piper Alpha Platform, North Sea, July 6, 1988 Texas City Refinery, March 3, 2005 Deepwater Horizon / Macondo, April 20, 2010

Key Elements of Process Safety Process safety information Process hazard analysis Operating procedures Training Contractors Pre-startup safety review Mechanical integrity Hot work permit Management of change Incident investigation Emergency planning and response Compliance audits Employee participation

Leverage point : Incident investigations Process Safety incident investigations incident that resulted in, or could reasonably have resulted in a catastrophic release of highly hazardous chemical in the workplace.. To get ahead of potential PS program health problems (LOPC or abnormal situation reporting): Follow API 754 Release Reporting Guidelines Consider prompt self-reporting of : any LOPC fire or evidence of fire explosion and/or over overpressure resulting in distortion critical process alarm, including ESD activations failure of safety critical equipment (SCE) encroachment NDE results < Tmin

Leverage point : Incident investigations Vociferously read and digest post incident reports of others to look for parallels that could occur in your operations Longford Incident 9/25/1998 Australia* Corporate headquarters should maintain safety departments, which can exercise effective control over the management of major hazards All major changes, both organizational and technical, must be subject to careful risk assessment Alarm systems must be designed so that warnings of trouble do not get dismissed as normal (normalized) Frontline operators must be provided with appropriate supervision and back up from technical expert Routine reporting systems must highlight safety-critical information Communication between shifts must highlight safety-critical information Incident reporting systems must specify relevant warning signs. They should provide feedback to reporters and opportunities for reporters to comment on feedback Reliance on lost-time injury data in major hazard industries itself a major hazard A focus on safety culture can distract attention from the management of major hazards Maintenance cutbacks foreshadow trouble Auditing to be good enough to identify bad news and ensure it gets to the top Companies should apply the lessons of other disasters * Excerpts from Royal Commission on Longford Gas Plant Disaster and Lessons from Longford Andrew Hopkins 5/2000

Leverage point : Incident investigations Grangemouth 5/29/2000 Incident Scotland* BP Group and Complex Management did not detect and intervene early enough on deteriorating performance; Lesson 1 - Major accident hazards should be actively managed to allow control and reduction of risks. Control of major accident hazards requires a specific focus on process safety management over and above conventional safety management. Lesson 2 - Companies should develop key performance indicators (KPI s) for major hazards and ensure process safety performance is monitored and reported against these parameters. Wider Messages for Industry Message 1 - Major hazard industries should ensure that the knowledge available from previous incidents both within their own organization and externally are incorporated into current safety management systems. Message 2 - Operators should give increased focus to major accident prevention into order to ensure serious business risk is controlled and to ensure effective corporate governance. * Major Incident Investigation Report BP Grangemouth Scotland 8/18/2003 Health and Safety Executive

Leverage Point : Incident Investigations Texas City refinery incident (Baker Report)* A. BP s incident goal of no accidents, no harm to people emphasized personnel safety, but not process safety. BP interpreted improving personnel injury rates as an indication of acceptable process safety performance B. BP s corporate safety management system does not ensure timely compliance with internal process safety standards (equipment standards, rupture disks under relief valves, critical alarms and ESD s, area classification, and near miss investigation). C. BP primarily used injury rates to measure process safety performance; its reliance on injury rates significantly hindered its perception of process risk (see corporate safety culture).bp has not instituted effective root cause analysis procedures to identify systemic causal factors that may contribute to future accidents. BP s PSM system likely results in under reporting of incidents and or near misses D.BP has sometimes failed to address promptly and track to completion process safety deficiencies identified during hazard assessments, audits, inspections, and incident investigations. Especially apparent with overdue mechanical integrity inspection / testing. (See process safety management systems) * The Report of the BP U.S. Refineries Independent Safety Review Panel January 2007

Despite some significant progress with process safety indicator in the downstream oil industry, in the offshore sector BP, Transocean, industry associations, and the regulator had not effectively learned critical lessons of Texas City and other serious process incidents at the time of the Macondo blowout. Chemical Safety Board (CSB) Team public hearing July 24, 2012

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A way forward: inherently safe design Minimize: Reducing the amount of hazardous material present at any one time, e.g. by using smaller batches Substitute: Replacing one material with another of less hazard, e.g. cleaning with water and detergent rather than a flammable solvent Moderate: Reducing the strength of an effect, e.g. having a cold liquid instead of a gas at high pressure, or using material in a dilute rather than concentrated form Simplify: Designing out problems rather than adding additional equipment or features to deal with them. Only fitting options and using complex procedures if they are really necessary

An example of ISD under evaluation Current as is situation: Water plants currently using 35% Hydrochloric Acid for water treatment If LOPC of 35% HCL, significant onsite and potential offsite impacts could occur To be condition: consider replacement or moderation of material in use

Evaluation of options: HCL vapor pressure 250 Vapor Pressure mm Hg vs Concentration % 200 150 100 50 35% Concentration (current) Vapor Pressure mmhg vs Concentration % 0 25-28% (proposed) 20 30 32 34 36 38

Release modeling benefits

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