JSR DYNARON 1320P PAGE : 1 DATE PREPARED : FEB. 14, 2003 MSDS NO. : DR1320P-E06 SECTION1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

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Transcription:

JSR DYNARON 1320P PAGE : 1 SECTION1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : JSR DYNARON 1320P PRODUCT DESCRIPTION : White or Yellow solid CONTACT ADDRESS : 100, Kawajiri-cho, Yokkaichi-shi, Mie, Japan ** EMERGENCY TELEPHONE NUMBERS ( FACSIMILE NUMBERS ) : HEAD OFFICE +81-3-5565-6614 ( +81-3-5565-6636 ) ( JAPAN STANDARD TIME; MONDAY - FRIDAY 9:15-17:45 ) JSR EUROPEAN OFFICE +32-16-832-848 ( +32-16-832-849 ) JSR AMERICA INC. +1-513-421-6166 ( +1-513-421-6148) **24Hr EMERGENCY TELEPHONE NUMBERS CHEMTREC OUTSIDE U.S.A. +1-703-527-3887 INSIDE U.S.A. 1-800-424-9300 NON EMERGENCY TELEPHONE NUMBER ( FACSIMILE NUMBER ) : +81-593-45-8597 ( +81-593-45-8101 ) SECTION 2 COMPOSITION / INFORMATION OF INGREDIENTS SUBSTANCE / MIXTURE : Substance CHEMICAL NAME : Hydrogenated Styrene Butadiene Rubber CAS REGISTRY NUMBER : 66070-58-4 ( Listed in the TSCA Inventory) UN CLASS AND UN NUMBER : This product is not hazardous as defined in 29 CFR1910.1200. SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW : Slight odor solid. The toxicological properties have not been fully investigated. May form flammable or explosive dust - air mixtures. May explode when heated. Keep away from heat, sparks and flame. Avoid contamination by any source. Avoid creation of dust. Handle with caution. POTENTIAL HEALTH EFFECTS INHALATION : SKIN CONTACT : EYE CONTACT :

JSR DYNARON 1320P PAGE : 2 INGESTION : MELT PROCESSING HEALTH EFFECTS : Molten material can cause severe burns. Processing fumes may cause irritation to the eyes, skin, and respiratory tract, and in cases of severe over-exposure, nausea and headache. MEDICAL RESTRICTIONS : There are no known human health effects aggravated by exposure to this product. However, certain sensitive individuals and individuals with respiratory impairments may be affected by exposure to components in the processing fumes. ENVIRONMENTAL EFFECTS : OSHA : None NTP : None SECTION 4 FIRST AID MEASURES INHALATION : Remove from exposure area to fresh air immediately. Perform artificial respiration if necessary. Keep person warm and quiet. Treat symptomatically and supportively. Get medical attention. SKIN CONTACT : Remove contaminated clothing and shoes. Wash with soap or mild detergent and large amounts of water until no evidence of chemical remains ( at least 15-20 minutes ). Get medical attention. EYE CONTACT : Wash eyes with large amounts of water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains ( at least 15-20 minutes ). Get medical attention. INGESTION : If vomiting occurs, keep head lower than hips to help prevent aspiration. Treat symptomatically and supportively. Get medical attention if needed. NOTE TO PHYSICIAN ANTIDOTE : No specific antidote. Treat symptomatically and supportively. MELT PROCESSING : When molten material contacts skin, cool the contact part thoroughly with water and seek medical attention. Do not use solvent for removal. For processing fume inhalation irritation, leave contaminated area and breathe fresh air. If coughing, difficult breathing or any other symptoms develop, seek medical attention at once, even if symptoms develop later. For skin contact with fume condensation, wash the contact part thoroughly with soap and water. If irritation develops, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES FIRE AND EXPLOSION HAZARD : Slight fire hazard when exposed to heat or flame. FIRE EXTINGUISHING MEDIA : Dry chemical, carbon dioxide, water spray or regular foam ( 1993 Emergency Response

JSR DYNARON 1320P PAGE : 3 Guidebook, RSPA P5800.6 ) For large fires, use water spray, fog or regular foam ( 1993 Emergency Response Guidebook, RSPA P5800.6 ) FIREFIGHTING : Move container from fire area if you can do it without risk. Do not scatter spilled material with high - pressure water streams. Dike fire - control water for later disposal ( 1993 Emergency Response Guidebook, RSPA P5800.6, Guide Page 31 ). Use agents suitable for type of surrounding fire. Avoid breathing hazardous vapors, keep upwind. HAZARDOUS COMBUSTION PRODUCTS : Thermal decomposition may release acrid smoke and irritating fumes. SECTION 6 ACCIDENTAL RELEASE MEASURES OCCUPATIONAL SPILL : Sweep up and place in suitable containers. Do not flush spilled material into sewer. Keep unnecessary people away. SECTION 7 HANDLING AND STORAGE Observe all federal, state and local regulations when storing this substance. Store away from incompatible substances. HANDLING : (1)Make efforts to keep the workplace clean and tidy, and avoid using fire. (2)Since there is possibility of volatile matter generating during work, it may cause irritation to the eyes. (3)After work, before smoking or eating, wash the hands well, and gargle. (4)Do not process the substance, at a temperature of 230 or over. STORAGE: (1)In order to prevent deterioration, avoid the following. 1Exposure to the direct sun rays. 2High Temperature, High Humidity 3Outdoor Storage Even in the case of indoor storage, avoid storing in high-temperature area or near UVemitting lights such as the incandescent lamps and mercury lamps. (2) In case of bulk shipments, in order to prevent crumbling of the bulk cargo, keep the height as low as possible. SECTION 8 EXPOSURE CONTROL / PERSONAL PROTECTION EXPOSURE LIMITS : No occupational exposure limits established by OSHA, ACGIH, or NIOSH. VENTILATION : Provide local exhaust ventilation. Ventilation equipment should be explosion - proof if explosive concentrations of dust, vapor or fume are present. EYE PROTECTION : Employee should wear splash - proof or dust - resistant safety goggles to prevent eye contact with this substance. Emergency eye wash : Where there is any possibility that an employee s eyes may be exposed to this substance, the employer should provide an eye wash fountain within the immediate work area for emergency use. CLOTHING : Employee should wear appropriate protective ( impervious ) clothing and equipment to

JSR DYNARON 1320P PAGE : 4 prevent repeated or prolonged skin contact with this substance. GLOVES : Employee should wear appropriate protective gloves to prevent contact with this substance. RESPIRATOR : The following respirators are recommended based on information found in the PHYSICAL DATA, TOXICITY and HEALTH EFFECTS sections. They are ranked in order from minimum to maximum respiratory protection. The specific respirator selected must be based on contamination levels found in the work place, must be based on the specific operation, must not exceed the working limits of the respirator and must be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration ( NIOSH - MSHA ). Any dust and mist respirator. Any air - purifying respirator with a high - efficiency particulate filter. Any powered air - purifying respirator with a dust and mist filter. Any powered air - purifying respirator with a high - efficiency particulate filter. Any type C supplied - air respirator operated in the pressure - demand or other positive pressure - demand or other positive pressure or continuous - flow mode. Any self - contained breathing apparatus. FOR FIREFIGHTING AND OTHER DANGEROUS TO LIFE OR HEALTH CONDITIONS : Any self - contained breathing apparatus that has a full facepiece and is operated in a pressure - demand or other positive - pressure mode. Any supplied - air respirator that has a full facepiece and is operated in a pressure - demand or other positive - pressure mode in combination with an auxiliary self - contained breathing apparatus operated in pressure - demand or other positive - pressure mode. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES SPECIFIC GRAVITY : 0.89 ODOR : Slight odor SOLUBILITY IN WATER : Insoluble BOILING POINT : VAPOR PRESSURE : MELTING POINT : INITIAL BOILING POINT : VOLATILITY : SECTION 10 PHYSICAL HAZARD ( STABILITY & REACTIVITY ) REACTIVITY : Stable under normal temperature and pressure. CONDITIONS TO AVOID : May burn but does not ignite readily. Avoid contact with strong oxidizers, excessive heat, sparks, or open flame. INCOMPATIBILITIES : OXIDIZERS ( STRONG ) : Fire and explosion hazard. HAZARDOUS DECOMPOSITION : Thermal decomposition may release acrid smoke and irritating fumes. SECTION 11 TOXICOLOGICAL INFORMATION CARCINOGEN STATUS : No data available. ACUTE TOXICITY LEVEL : No data available.

JSR DYNARON 1320P PAGE : 5 TARGET EFFECTS : No data available. ADDITIONAL DATA : Industrial products may contain trace impurities and additives which may cause toxic effects or allergic reactions. HEALTH EFFECTS : INHALATION : SKIN CONTACT : EYE CONTACT : INGESTION : SECTION 12 ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY : No data available. DEGRADABILITY : No data available. OTHERS : The material does not contain substances listed in the harmful substances of U.S. EPA 33/50 Program and substances listed in Montreal Protocol on Substances that deplete the Ozone Layer. Please refer to Section 6 for information regarding accidental release and Section 15 for regulatory reporting information. SECTION 13 DISPOSAL CONSIDERATIONS Observe all federal, state and local regulations when disposing of this substance. Please refer to Section 5, 6, and 15 for disposal and regulatory information. SECTION 14 TRANSPORT INFORMATION Cover the substance with sheets in order to prevent mingling of foreign matters, wetting, and exposure to the direct sun rays. In case of bulk cargoes, in order to prevent crumbling, keep the height as low as possible, and fix it firmly in place. SECTION 15 REGULATORY INFORMATION CERCLA SECTION 103 ( 40 CFR 302.4 ) : None SARA SECTION 302 ( 40 CFR 355.30 ) : None SARA SECTION 304 ( 40 CFR 355.40 ) : None SARA SECTION 313 ( 40 CFR 372.65 ) : None CALIFORNIA PROPOSITION 65 : None

JSR DYNARON 1320P PAGE : 6 SECTION 16 OTHER INFORMATION It is your own responsibility to examine and confirm if the material which is the subject of this data sheet ( Material )meets or suits any regulation or restriction in your country or of your local authority. To the best of our knowledge, the information contained herein is accurate. However, neither JSR nor any of its subsidiaries assumes any liability whatsoever for the accuracy of completeness of the information contained herein. The precautionary measures in handling the Material as mentioned herein are based upon an assumption that the Material is handled in an ordinary way. In case of special handling extra or different safety measures suitable therefor need to be taken. Final determination of safety and suitability of the Material for your intended use is your sole responsibility. The Material may present unknown hazards, and therefore should be handled with adequate caution. Although certain hazards are described herein, neither JSR nor any of its subsidiaries guarantees that they are the only hazards which exist in relation to the Material. Export of the Material may require an export license from the Japanese government and shall be made in strict compliance with Foreign Exchange and Foreign Trade Control Law of Japan. End of MSDS