1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name PRINCE Anti-perspirant Deodorant Spray Entice Other Names (if applicable) Product Code Barcode Number Recommended Use Company Name ABN Street Address Telephone Number Supplier Code Other Emergency Phone Number 51886 26251462 Anti-perspirant Spray ALDI STORES (A Limited Partnership) 90 196 565 019 1 Sargents Road, MINCHINBURY, NSW 2770 +61 2 9675 9000 313 Australia - 13 11 26 (Poisons Information Centre) 2. HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. Extremely flammable aerosol. Pressurised container: May burst if heated. Label elements GHS label elements Signal Word Extremely flammable Hazard statement (s) Pressurised dispenser. Extremely flammable Precautionary statement (s) Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - no smoking. Keep out of reach of children. Other hazards Do not spray near eyes or face Do not apply to broken or irritated skin. Should irritation occur discontinue use. Use only as directed. Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. This document becomes uncontrolled once printed. Page 1 of 8
3. COMPOSITION / INFORMATION ON INGREDIENTS Substances Mixtures Components CAS Number Proportion Butane 106-97-8 45.65 Propane 74-98-6 20.75 Isobutane 75-28-5 16.60 Cyclopentasiloxane 541-02-6 5,237 Aluminum Chlorohydrate 12042-91-0 5,000 Cyclohexasiloxane 540-97-6 3,251 Triethyl Citrate 77-93-0 1,005 Isopropyl Myristate 110-27-0 1,005 Parfum diverse 0.992 Disteardimonium Hectorite 97280-96-1 0.500 Limonene 138-86-3 0.006 Aloe Barbadensis Leaf Extract 85507-69-3 0.002 This document becomes uncontrolled once printed. Page 2 of 8
This document becomes uncontrolled once printed. Page 3 of 8
4. FIRST AID MEASURES For advice, contact Poisons Information Centre (phone Australia 13 11 26) or a doctor (For each route of exposure provide indication of medical attention and special treatment needed including description of most important symptoms, acute and delayed) Inhalation No special measures are necessary Skin Contact No special measures are necessary Eye Contact Rinse immediately carefully and thoroughly with eye-bath or water Ingestion Rinse mouth immediately and drink plenty of water Note to Physician Treat symptomatically 5. FIRE FIGHTING MEASURES Hazards from combustion products Precautions for firefighters and special protective equipment Suitable / Unsuitable extinguishing material Flammable. Vapours can form explosive mixtures with air In case of fire: Wear self-contained breathing apparatus. Water spray jet, Carbon dioxide (CO2), Foam, Extinguishing powder 6. ACCIDENTAL RELEASE MEASURES Emergency procedures Methods and materials for containment and clean up Environmental precaution(s) Remove all sources of ignition Absorb wiht liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat recovered material as prescribed in the section on waste disposal. Do not allow uncontrolled discharge of product into the environment. Danger of explosion 7. HANDLING AND STORAGE Precautions for safe handling Conditions for safe storage Do not pierce or burn, even after use. Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away form heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National Exposure Standards. Biological Limit Values. Engineering Controls No special measures are necessary Personal Protective Equipment No special measures are necessary This document becomes uncontrolled once printed. Page 4 of 8
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour ph Specific Gravity or Density Vapour Pressure Vapour Density Percent Volatiles Boiling Point Range Freezing/ Melting Point Solubility Flash Point (include method detection) Flammability Limits Ignition Temperature Aerosol characteristic not determinded not determinded not determinded 83% -40 C not determinded easy soluble in water -80 C Lower explosion limits: 1 vol % / Upper explosion limits: 11 vol % Other 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Conditions to avoid Incompatible Materials Hazardous Decomposition Products Hazardous Reactions Flammable, Ignition hazard The product is stable under storage and normal ambient temperatures Keep away form sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form explosive mixtures with air. No information avvailable No known hazardous decomposition products Do not mix with other chemicals 11. TOXICOLOGICAL INFORMATION Health Effects Ingestion Eye Contact Skin Contact Inhalation Long term effects Acute Toxicity/ Chronic Toxicity: (ie LD 50 ) 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and Degradability Mobility Other Adverse Effects Bioaccumulation Potential Not environmentally hazardous The product has not been tested The product has not been tested The product has not been tested This document becomes uncontrolled once printed. Page 5 of 8
This document becomes uncontrolled once printed. Page 6 of 8
13. DISPOSAL CONSIDERATIONS Disposal methods (including container disposal) Special precautions for landfill or incineration Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation Classified as hazardous waste. Completely emptied packages can be recycled. 14. TRANSPORT INFORMATION Regulation UN Number Proper Shipping Name DG Class Label Additional Information ADG UN 1950 AEROSOLS 2 IMDG UN 1950 AEROSOLS 2 IATA UN 1950 AEROSOLS, flammable 2 2.1. 2.1. 2.1. Packing Group: - Packing Group: - Packing Group: - 15. REGULATORY INFORMATION Poisons Schedule (Australia only) APVMA Status TGA Status AICS Status 16. OTHER INFORMATION SDS Version Number 1.0 SDS Version Date 29/09/2015 Reason for issue Update Key/Legend to Abbreviations and Acronyms used in the SDS: Abbreviation/Acronym ADG AICS APVMA AQIS AS ASCC DG ERG Code IATA IMDG LD 50 NOHSC SDS STEL TGA TLV TWA UN Number Meaning Australian Code for the Transport of Dangerous Goods by Road and Rail Australian Inventory of Chemical Substances Australian Pesticides and Veterinary Medicines Authority Australian Quarantine and Inspection Service Australian Standard (as issued by Standards Australia) Australian Safety and Compensation Council Dangerous Goods Emergency Response Guidebook Code. The Emergency Response Guidebook is used by first responders (eg firefighters, police officers and ambulance personnel) when responding to a transportation emergency involving hazardous materials. International Air Transport Association International Maritime Dangerous Goods The median lethal toxicological dose, LD 50 is an abbreviation for Lethal Dose, 50%. of a toxic substance. This is the dose required to kill half the members of a tested population. National Occupational Health and Safety Commission Safety Data Sheet Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive exposures at the STEL. Therapeutic Goods Administration Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical agents to which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect. Time Weighted Average - The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week. UN numbers are four-digit numbers that identify hazardous substances, and articles (such as explosives, flammable liquids, toxic substances, etc.) in the framework of international transport. This SDS has been prepared by the ALDI Stores product supplier from current technical data and summarises at the date of issue their best knowledge of the health and safety information of the product, and in particular how to safely handle and use the product in the workplace. This SDS may only be reproduced in full. Summaries or excerpts from this SDS may not contain all the relevant information and thus are not permitted. This document becomes uncontrolled once printed. Page 7 of 8
ALDI Stores gives no warranty and makes no representation as to the accuracy, reliability or completeness of the information contained herein. The user should make their own determination in light of their own circumstances as to the suitability of this information and the safe conditions for the use of this product. To the extent permitted by law, ALDI Stores will not be liable for any loss, damage or expense arising from the use of this SDS, whether caused by the negligent act or omission of ALDI Stores or otherwise. End of SDS This document becomes uncontrolled once printed. Page 8 of 8