1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Nubifer Y-805K, Nubifer Y-806K Nubifer Y-905K, Nubifer Y-910K Nubifer Y-820K Chemical description : Zinc Ferrite brown spinel REACH nr. : 01-2119457570-39 1.2. Relevant identified uses of the substance or mixture and uses advised against Use : Colouring agents, pigments. 1.3. Details of the supplier of the safety data sheet Company identification 1.4. Emergency telephone number : NUBIOLA GROUP Pablo Iglesias 98-100 08908 L'Hospitalet de Llobregat (Barcelona) SPAIN Tel. - 0034-93 - 343 57 50 nuproducts.safety@nubiola.com Phone number : +0034 933 435 750 [ Office hours ] 2. Hazards identification 2.1. Classification of the substance or mixture Classification (Regulation (EC) No 1272/2008 (CLP/GHS)) Not classified. 2.2. Label elements Labelling (Regulation (EC) No 1272/2008 (CLP/GHS)) Not classified. 2.3. Other hazards Other hazards : The substance does not fulfil the criteria to be identified as PBT or vpvb substance according to Annex XIII of Regulation REACH. 3. Composition/information on ingredients Substance / Mixture : Substance. Zinc ferrite brown spinel, Pigment Yellow 119 C.I. 77496 CAS No :68187-51-9 EC No :269-103-8 Revised edition no : 3 Page : 1
3. Composition/information on ingredients (continued) Hazardous component(s) Composition Index No :--- REACH Ref. :01-2119457570-39 : This product is not hazardous. : (Zn,Fe) Fe2O4 Substance name Contents CAS No EC No Index No REACH Ref. Classification Zinc ferrite brown spinel, : 68187-51-9 269-103-8 ----- 01-2119457570-39 Not classified (DSD/DPD) Pigment Yellow 119 C.I. 77496 ---------------------------------- Not classified (GHS) Contains no other components or impurities which will influence the classification of the product. 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Assure fresh air breathing. Allow the victim to rest. If you feel unwell, seek medical advice (show the label where possible). : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs : Get medical advice. : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Do not induce vomiting. Rinse mouth. Obtain emergency medical attention. If you feel unwell, seek medical advice. 4.2. Most important symptoms and effects, both acute and delayed Symptoms relating to use : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Water spray. Dry powder. Carbon dioxide. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers. 5.2. Special hazards arising from the substance or mixture Hazardous combustion products : Under fire conditions, hazardous fumes will be present. 5.3. Advice for fire-fighters Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Revised edition no : 3 Page : 2
6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders Special precautions For non-emergency personnel : Ventilate area. Equip cleanup crew with proper protection. : Recover the cleaning water for later disposal. : Evacuate unnecessary personnel. 6.2. Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Clean up methods : Ventilate area. On land, sweep or shovel into suitable containers. Minimize generation of dust. 6.4. Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. : Provide adequate ventilation to minimize dust concentrations. 7.2. Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, dry, well-ventilated place. Keep container closed when not in use. Storage temperature: 0-50 C. : Strong acids. Strong bases. 7.3. Specific end use(s) Specific end use(s) : Industrial uses: Uses of substances as such or in preparations at industrial sites. 8. Exposure controls / personal protection 8.1. Control parameters Occupational Exposure Limits : TWA: 10 mg Fe/m³ (8 hours, Inhalable Dust) TWA: 3 mg Fe/m³ (8 hours, Respirable Dust) 8.2. Exposure controls Personal protection Respiratory protection Hand protection Eye protection : Avoid all unnecessary exposure. : Where excessive dust may result, wear approved mask. FFP2 (EN149) : In case of repeated or prolonged contact wear gloves. : Chemical goggles or safety glasses. Revised edition no : 3 Page : 3
8. Exposure controls / personal protection (continued) Others : When using, do not eat, drink or smoke. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C : Powder. Colour : Yellow. Odour : Odourless. Odour threshold ph : 6-10 (10 % w/w) [ASTM D1208-78 ] Melting point [ C] : >1000 C Critical temperature [ C] Auto-ignition temperature [ C] Flammability (solid, gas) : Not flammable. [UN Test 1] Flash point [ C] Boiling point [ C] (Solid) Evaporation rate Vapour density Density at 20ºC [g/cm3] : approx. 5.0 g/cm3 [ASTM D-153-82] Solubility in water : Insoluble. (< 0,005 mg/l) Viscosity at 40 C [mm2/s] (Solid) Explosive properties : Not explosive. Oxidising properties : Not oxidizing. 10. Stability and reactivity 10.1. Reactivity Reactivity 10.2. Chemical stability : No hazardous reaction known under normal conditions of use. Chemical stability : Stable under normal conditions. 10.3. Possibility of hazardous reactions Hazardous reactions 10.4. Conditions to avoid : No hazardous reaction known under normal conditions of use. Conditions to avoid : Decomposes above 1000 C 10.5. Materials to avoid Materials to avoid : Strong acids. Strong bases. 10.6. Hazardous decomposition products Revised edition no : 3 Page : 4
10. Stability and reactivity (continued) SAFETY DATA SHEET Hazardous decomposition products : None under normal conditions. 11. Toxicological information 11.1. Information on toxicological effects Acute toxicity - LD50 (oral, rat) [mg/kg] : > 5000 mg/kg [OECD TG420 / B.1] Irritation : Non-irritating. Sensitization : No sensitizing potential. Mutagenicity : No experimental or epidemiological evidence exists. Carcinogenicity : No experimental or epidemiological evidence exists. Reproductive toxicity : No experimental or epidemiological evidence exists. Specific target organ toxicity (STOT) : No experimental or epidemiological evidence exists. single exposure Specific target organ toxicity (STOT) : No experimental or epidemiological evidence exists. repeated exposure Aspiration hazard 12. Ecological information 12.1. Toxicity Acute toxicity - EC50 48 h - Daphnia [mg/l] : > 10000 mg/l [OECD TG202 / C.2] - LC0 96 h - Fish [mg/l] : > 100000 mg/l (Danio rerio) [OECD 203] 12.2. Persistence - degradability Persistence - degradability 12.3. Bioaccumulative potential Bioaccumulative potential 12.4. Mobility in soil Mobility in soil 12.5. Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT or vpvb substance according to Annex XIII of Regulation REACH. 12.6. Other adverse effects Environmental precautions : Avoid release to the environment. WGK (Germany) : 0 Revised edition no : 3 Page : 5
13. Disposal considerations SAFETY DATA SHEET 13.1. Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. 14. Transport information 14.1. Land transport (ADR-RID) : Not regulated. 14.2. Sea transport (IMDG) : Not regulated. 14.3. Air transport (ICAO-IATA) : Not regulated. 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII REACH Authorisation - Annex XIV : Ensure all national/local regulations are observed. : None. : None. 15.2. Chemical Safety Assessment Chemical Safety Assessment : It has been carried out. 16. Other information Revision : Revision - See : Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Recommended uses and restrictions : See product bulletin for detailed information. Further information : For professional use only. The contents and format of this safety data sheet are in accordance with REACH Regulation (EC) No 1907/2006 and Regulation (EU) No 453/2010. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Revised edition no : 3 Page : 6
End of document Revised edition no : 3 Page : 7