SECTION 1. Identification Product Identifier Product Name: Gorilla Construction Adhesive Synonyms: None Intended Use of the Product Construction Adhesive Name, Address, and Telephone of the Responsible Party The Gorilla Glue Company 4550 Red Bank Expressway Cincinnati, Ohio 45227 513-271-3300 www.gorillatough.com Emergency Telephone Number Emergency Number: 1-800-420-7186 (Prosar) SECTION 2. Hazards Identification Classification of the substance or mixture Not classified. Label Elements No labelling applicable. Other Hazards Other hazards not contributing to the classification: Methyl alcohol is formed during curing. Use product with adequate ventilation. Quartz is known to cause cancer when inhaled for extended period of time. However, Quartz in this matrix is not considered inhalable as it is bound into the matrix. Therefore hazards associated to quartz are not expected to be present. Unknown Acute Toxicity (GHS-US) Not available. SECTION 3. Composition / Information on Ingredients Mixture Component CAS Number % Silica, Quartz 14808-60-7 0.1 1 Methyl alcohol can be formed through hydrolysis and be released during the curing process. Page 1 of 7
SECTION 4. First Aid Measures Description of first aid measures General: In all cases of doubt, or when symptoms persist, seek medical advice/attention. Bring the Safety Data Sheet or label on the dispenser / package. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. Seek medical attention if you feel unwell. Skin Contact: Immediately wash skin thoroughly with plenty of warm water and soap and follow up by rinsing with water for at least 15 minutes. Call a Poison Center or seek medical attention if you feel unwell. Remove contaminated clothing and wash before reuse. Eye Contact: Immediately flush eyes with water for at least 15 minutes. Remove contact lenses if Ingestion: present and easy to do. Continue rinsing. Seek medical attention. Do not induce vomiting and ensure the passageway is not blocked. Seek medical attention. Most important symptom and effects, both acute and delayed General: May cause irritation. Inhalation: May cause irritation. Methyl alcohol is released during the curing process. Repeated inhalation may be harmful. Skin Contact: May cause irritation. Eye Contact: May cause irritation. Ingestion: Ingestion may be harmful or have adverse effects. Chronic Symptoms: Not Applicable. Indication of any immediate medical attention and special treatment needed If medical advice is needed, have product container or label at hand. SECTION 5. Firefighting Measures Extinguishing media Suitable extinguishing media: Dry chemical, foam, carbon dioxide, water fog. Unsuitable extinguishing media: Do not use a heavy stream of water. Use of a heavy stream of water may spread fire. Special hazards arising from the substance or mixture Fire Hazard: Not flammable under stable conditions. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. Page 2 of 7
Advice for firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Do not allow run-off from firefighting to enter drains/water courses. Protection During Firefighting: Do not enter fire area without the proper protective equipment, including respiratory protection. Hazardous Combustion Products: Carbon oxides. Reference to Other Sections Refer to Section 9 for flammability properties. SECTION 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. For Non-Emergency Personnel Protective Equipment: Use appropriate personal equipment (PPE) when necessary. Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with the proper protection. Emergency Procedures: Keep area ventilated. Environmental precautions Do not allow product to enter drains or watercourses. Methods and material for containment and cleaning up For Containment: No specific measures are necessary. Methods for Cleaning up: Dispose of waste safely and in accordance with local, state, and federal regulations. Reference to other sections See Section 8 for Exposure Control and Personal Protection. See Section 13 for Disposal Considerations. SECTION 7. Handling and Storage Precautions for safe handling Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, smoking, or working. Conditions for safe storage, including any incompatibilities Storage Conditions: Store in a dry, cool and well ventilated place. Store away from heat. Incompatible Materials: None known. Specific end use(s) Construction Adhesive Page 3 of 7
SECTION 8. Exposure controls / personal protection Control parameters Quartz USA ACGIH ACGIH TWA (mg/m 3 ) 0.025 mg/m 3 (respirable fraction) USA ACGIH ACGIH TWA (mg/m 3 ) A2 Suspected Human Carcinogen USA OSHA OSHA PEL (STEL)(mg/m 3 ) 250 mppcf/% SiO2+5, 10 mg/m 3 /% SiO2+2 USA NIOSH NIOSH REL (TWA)(mg/m 3 ) 0.05 mg/m 3 (respirable dust) USA IDLH US IDLH (mg/m 3 ) 50 mg/m 3 (respirable dust) Mexico OEL TWA (mg/m 3 ) 0.1 mg/m 3 (respirable fraction) Alberta OEL TWA (mg/m 3 0.025 mg/m 3 (respirable particulate) British Columbia OEL TWA (mg/m 3 ) 0.025 mg/m 3 (respirable) Manitoba OEL TWA (mg/m 3 ) 0.025 mg/m 3 (respirable fraction) New Brunswick OEL TWA (mg/m 3 ) 0.1 mg/m 3 (respirable fraction) Newfoundland & Labrador OEL TWA (mg/m 3 ) 0.025 mg/m 3 (respirable fraction) Nova Scotia OEL TWA (mg/m 3 ) 0.025 mg/m 3 (respirable fraction) Nunavut OEL TWA (mg/m 3 ) 0.1 mg/m 3 (respirable mass) 0.3 mg/m 3 (total mass) Northwest Territories OEL TWA (mg/m 3 ) 0.1 mg/m 3 (respirable mass) 0.3 mg/m 3 (total mass) Ontario OEL TWA (mg/m 3 ) 0.10 mg/m 3 (designated substance regulation-respirable) Prince Edward Island OEL TWA (mg/m 3 ) 0.025 mg/m 3 (respirable fraction) Quebec VEMP (mg/m 3 ) 0.1 mg/m 3 (respirable dust) Saskatchewan OEL TWA (mg/m 3 ) 0.05 mg/m 3 (respirable fraction) Yukon OEL TWA (mg/m 3 ) 300 particle/ml Exposure controls Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Provide sufficient ventilation. Ensure all national/local regulations are observed. Personal Protective Equipment: Gloves. Safety Glasses. Materials for Protective Clothing: Chemical resistant materials and fabrics are recommended, but not required. Hand Protection: Chemical resistant gloves. Eye Protection: Chemical goggles or safety glasses. Skin and Body Protection: Wear suitable protective clothing. Page 4 of 7
Respiratory Protection: Other Information: Use a NIOSH approved respirator or self-contained breathing apparatus when needed. When using, do not eat, drink or smoke. SECTION 9. Physical and Chemical Properties Physical State Paste Color White ph No data available Odor Musty Density 1.7 g/cc Odor Threshold No data available Specific Gravity No data available Boiling Range/Point ( C/F) No data available Melting Point ( C/F) Not applicable Flash Point (PMCC) ( C/F) >93 C (>200 F) Vapor Pressure No data available Evaporation Rate (BuAc=1) No data available Flammability (solid / gas) Not applicable Vapor Density (Air = 1) No data available Viscosity No data available VOC (g/l) No data available Auto-Ignition Temperature No data available VOC (%) 2 Decomposition Temperature No data available Partition Coefficient Not applicable Upper Explosive Limit Not applicable (n-octanol/water) Lower Explosive Limit Not applicable Solubility in Water Non-soluble SECTION 10. Stability and Reactivity Reactivity: None known. Chemical stability: Stable when stored and handled correctly (see Section 7). Possibility of hazardous reactions: Hazardous polymerization will not occur. Conditions to avoid: Avoid extreme high and low temperatures. Incompatible materials: Strong acids. Hazardous decomposition products: Carbon oxides (CO, CO2). SECTION 11. Toxicological Information Information on toxicological effects Acute Toxicity: LD50 and LC50: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Teratogenicity: Carcinogenicity: Specific Target Organ Toxicity (Repeated Exposure): Specific Target Organ Toxicity (Single Exposure): Page 5 of 7
Reproductive Toxicity: Aspiration Hazards Inhalation: Skin Contact: Eye Contact: Ingestion: Chronic Symptoms: None expected under normal use. May cause skin irritation. May cause eye irritation. Ingestion may be harmful or have adverse effects. Not Applicable SECTION 12. Ecological Information Toxicity: Persistence and degradability: Bioaccumulative potential: Mobility in soil: Other adverse effects: Avoid release into the environment. SECTION 13. Disposal Considerations Waste disposal recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial, and international regulations. SECTION 14. Transportation information Department of transportation (DOT): Not regulated for transport Marine transport (IMDG): Not regulated for transport International Air transport (IATA): Not regulated for transport Transportation of Dangerous Goods (TDG- Canada): Not regulated for transport Mexico Transport: Not regulated for transport SECTION 15. Regulatory information US Federal Regulations Toxic Substance Control Act All components of this product are in compliance with the inventory listing requirements of the US Toxic Substance Control Act (TSCA) Chemical Substance Inventory. US State Regulations California Proposition 65 The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: Page 6 of 7
WARNING: This product contains chemicals known to the State of California to cause cancer. Massachusetts, New Jersey or Pennsylvania Right to Know Substance List Component CAS Number % Quartz 14808-60-7 < 1 SECTION 16. Other information This document is written in accordance with SDS requirements set forth by OSHA Hazard Communication Standard 29 CFR 1910.1200. The information presented in this Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied, statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted for the user s information and consideration only. Any use or disposal of this product must be determined by the user to be in accordance with applicable federal, state, provincial and local laws and regulations. Page 7 of 7