SAFETY DATA SHEET. Paraffin Wax 422. Date: 18/04/2016 Page 1 of 5. Manchester, Tel: +44 (0) M12 5DL. Fax: + 44 (0)

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Transcription:

Date: 18/04/2016 Page 1 of 5 1 IDENTIFICATION OF SUBSTANCE 1.1 Product Identifier: Identification on the label/ Trade name: 1.2 Relevant Identified uses of the substance and uses advised against: 1.2.1 Identified uses: Processing aid. 1.2.2 Uses advised against: 1.3 Details of the Supplier of the material safety data sheet: J. Allcock & Sons Ltd., Textile Street, West Gorton, Email: ja@allcocks.co.uk Manchester, Tel: +44 (0)161 223 7181 M12 5DL. Fax: + 44 (0)161 223 0173 2 HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture: 2.1.1 Classification: Does not contain any components which are hazardous according to the Dangerous Substance Directive (67/548/EC) or CLP Regulation 1272/2008/EC 2.1.2 The most important adverse effects: 2.1.2.1 The most important adverse physiochemical effects: 2.1.2.2 The most important adverse human health effects: Unlikely to cause eye irritation. Unlikely to cause skin irritation. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. 2.1.2.3 The most important adverse environmental effects: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. 2.2 Label Elements: 2.3 Other hazards Does not require a hazard warning label in accordance with Dangerous Substance Directive (67/548/EC) or CLP Regulation 1272/2008/EC. Hazard Pictograms: None. Signal Word(s): Hazard Statement: Precautionary statement: 3 COMPOSITION / INFORMATION ON INGREDIENTS Substance/Mixture: Substance Name CAS# % by weight REACH No. Classification Paraffin Wax 8002-74-2 100 There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section. 4 FIRST-AID MEASURES 4.1 Description of first aid measures: 4.1.1 In case of inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. 4.1.2 In case of skin contact: Wash the affected parts of the body with soap and water. No emergency measure are necessary but if adverse skin effects follow, refer for medical attention. 4.1.3 In case of eyes contact: Flush eyes immediately with fresh water for at least 15 minutes while holding eyelids open. No emergency measure are necessary but fi adverse eye effects follow, refer for medical attention.

Date: 18/04/2016 Page 2 of 5 4.1.4 In case of ingestion: Do no induce vomiting. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 4.2 Most important symptoms and effects, both acute and delayed 4.2.1 Potential acute health effects: Inhalation - over-heated wax can produce fumes which may be irritant when breathed in. Skin Contact - may cause slight irritation to skin. Ingestion - no known significant effects or critical hazards Eye Contact - may cause slight irritation to eyes 4.3 Indication of any immediate medical attention and special treatment needed In contact with or splashed by hot molten liquid: Skin Contact - cool the skin immediately with cool water. Treat burns according to their severity. To avoid damage to the skin no attempt should be made to remove paraffin wax firmly adhering to the skin. In case of circumferential burns splitting of paraffin wax ring may be considered to prevent tourniquet effect. Obtain medical attention. Never try to remove the material with solvents. Contact with eyes - cool the area immediately with cold water. Seek advice of an ophthalmologist. 5 FIRE-FIGHTING MEASURES 5.1 Extinguishing Media: 5.1.1 Suitable extinguishing media: Foam, dry chemical carbon dioxide, water mist. 5.1.2 Unsuitable extinguishing media: 5.2 Specific Hazards arising from the substance or mixture: During a fire, toxic gases (carbon monoxide, nitrous gases) may be generated by thermal decomposition or combustion. 5.3 Advice for fire-fighters: Only suitably trained personnel should attempt to tackle fires. Do not stay in the danger zone without respiratory protective equipment and protective clothing. 6 ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: 6.1.1 For non-emergency personnel: Surfaces may become slippery after spillage. 6.1.2 For emergency responders: Surfaces may become slippery after spillage. 6.2 Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water sources. 6.3 Methods of containment and cleaning up: Absorb and scrape up. Absorbent materials: sand or active clay. 6.4 Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. 7 HANDLING AND STORAGE 7.1 Precautions for safe handling: 7.1.1 Protective measures: Avoid skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. Recommended temperature for handling is 60-80 C. 7.1.2 Advice on general occupational hygiene: 7.2 Conditions for safe storage, including any incompatibilities: Keep containers tightly closed. Storage class:

Date: 18/04/2016 Page 3 of 5 7.3 Specific end use(s): 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters: TWA TLV (ACGIH): 2 mg/m 3 (paraffin wax fumes). However in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. 8.2 Exposure controls: 8.2.1 Appropriate engineering controls: No special controls needed. 8.2.2 Individual protection measures: Eye/face protection: No special precautions are needed beyond clean working conditions and safe handling practices. Hand protection: No special precautions are needed beyond clean working conditions and safe handling practices. PVC or nitrile gloves may be suitable. Body protection: No special precautions are needed beyond clean working conditions and safe handling practices. Respiratory protection: Inhalation of the vapour, fumes or mists should be avoided by safe working practices and good ventilation. 8.2.3 Environmental exposure controls: 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties: Appearance: Off White to Light tan/weak Physical state: Liquid (at elevated temperature) Solid (at ambient temperature) Odour: Typical ph: Neutral Melting point/range ( C): 56-58 Boiling point/range ( C): Initial boiling point > 300 Flash point ( C): >150, (ASTM D92, COC) Upper/lower flammability/explosive limits: Not known Vapour pressure, kpa: Negligible Relative Density (g cm -3 ) @ 15 C 0.83-0.86 Solubility: Auto-ignition temperature ( C): >200 Viscosity (mm 2 s -1, cst): @ 100 C 4.0 10 STABILITY AND REACTIVITY 10.1 Reactivity: This product is not reactive under normal storage and handling conditions (see section 7). 10.2 Chemical stability: Under normal storage and handling conditions, this product is stable. May react with strong oxidising agents, especially at high temperatures. 10.3 Possibility of hazardous reactions: <1 mg/l in water Soluble in Petroleum Ether, Ethyl Acetate. No specific hazardous reactions are expected to occur 10.4 Conditions to avoid: The product is combustible when heated > 300 C. 10.5 Incompatible materials: May react with strong oxidants. 10.6 Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce carbon monoxide, nitrous gases and irritating fumes.

Date: 18/04/2016 Page 4 of 5 11 TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects: Acute toxicity: Petroleum waxes are generally regarded as non-toxic, relatively harmless and not irritating under normal usage. Studies on related substances, i.e base oils and waxes, indicate: LD50 (Oral): > 2g / kg LD50 (Dermal): > 2 g/ kg Skin corrosion/irritation: Unlikely to cause skin irritation. Serious eye damage/irritation: Unlikely to cause eye irritation. Ingestion: Ingestion is unlikely to cause adverse systematic health effects. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. 12 ECOLOGICAL INFORMATION 12.1 Toxicity: No known significant effects or critical hazards 12.2 Persistence and degradability: This product is not readily biodegradable 12.3 Bioaccumulative potential: Data not available 12.4 Mobility in soil: Data not available 12.5 Results of PBT and vpvb assessment: This substance does not fulfil the criteria for being classed as a PBT or vpvb substance. 12.6 Other adverse effects: No other adverse effects are observed. 13 DISPOSAL CONSIDERATIONS 13. 1 Waste treatment methods: Transport to authorised waste location, or incinerate under controlled conditions (EU Directives 2000/76/EC and 1999/31EC apply). European Waste Catalogue No. 050199/130899. 14 TRANSPORT INFORMATION 14.1 General: 14.2 UN-no: None. 14.3 Transport hazard class(es) 14.3.1 RID/ADR: 14.3.2 IMO: 14.3.3 IATA/ICAO: 15 REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

Date: 18/04/2016 Page 5 of 5 Regulations No. 2037/2000 (Ozone depletors), No. 850/2004 (POPs) and No. 689/2008 (Export/import of dangerous chemicals) not applicable for this substance. 15.2 Chemical safety assessment: Chemical safety assessments for substance were not carried out. 16 OTHER INFORMATION Issued by: J. Allcock & Sons Ltd. SDS No.: WEB01 Date: 18/04/2016 For any further information please contact J. Allcock & Sons Ltd. *the*current*state*of*scientific*and*technical*knowledge.*dated:23/05/12