R Industries (R Industries New Zealand) hemwatch Hazard Alert ode: 0 hemwatch: 74-1508 Version No: 2.1.1.1 Safety Data Sheet according to HSNO Regulations Issue Date: 19/01/2017 Print Date: 26/08/2018 S.GHS.NZL.EN SETION 1 IDENTIFIATION OF THE SUBSTANE / MIXTURE AND OF THE OMPAN / UNDERTAKING Product Identifier Product name Synonyms Other means of identification Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use according to manufacturer's directions. leaning agent for automobile paint surfaces. Details of the supplier of the safety data sheet Registered company name R Industries (R Industries New Zealand) Address 10 Highbrook Drive East Tamaki Auckland New Zealand Telephone +64 9 272 2700 Fax +64 9 274 9696 Website www.crc.co.nz Email customerservices@crc.co.nz Emergency telephone number Association / Organisation Emergency telephone numbers Other emergency telephone numbers NZ Poisons entre 0800 POISON (0800 764 766) 111 (NZ Emergency Services) SETION 2 HAZARDS IDENTIFIATION lassification of the substance or mixture lassification Determined by hemwatch using GHS/HSNO criteria Label elements Hazard pictogram(s) SIGNAL WORD NOT APPLIABLE Hazard statement(s) Precautionary statement(s) Prevention Precautionary statement(s) Response
Precautionary statement(s) Storage Precautionary statement(s) Disposal SETION 3 OMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures AS No %[weight] Name 68439-50-9 <0.1 balance alcohols 12-14 ethoxylated Ingredients determined not to be hazardous SETION 4 FIRST AID MEASURES Description of first aid measures Eye ontact Skin ontact Inhalation Ingestion If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information entre or a doctor. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SETION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Advice for firefighters Fire Fighting Fire/Explosion Hazard Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Non combustible. Not considered a significant fire risk, however containers may burn. SETION 6 AIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Minor Spills lean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. ontrol personal contact with the substance, by using protective equipment. ontain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills Minor hazard. lear area of personnel. Alert Fire Brigade and tell them location and nature of hazard. ontrol personal contact with the substance, by using protective equipment as required. Personal Protective Equipment advice is contained in Section 8 of the SDS. SETION 7 HANDLING AND STORAGE Precautions for safe handling Safe handling Other information Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. When handling DO NOT eat, drink or smoke. Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. onditions for safe storage, including any incompatibilities Suitable container Storage incompatibility Polyethylene or polypropylene container. Packing as recommended by manufacturer. heck all containers are clearly labelled and free from leaks. None known SETION 8 EXPOSURE ONTROLS / PERSONAL PROTETION ontrol parameters OUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA EMERGEN LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 Ingredient Original IDLH Revised IDLH alcohols 12-14 ethoxylated Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Personal protection Eye and face protection Skin protection Hands/feet protection Body protection Other protection No special equipment for minor exposure i.e. when handling small quantities. OTHERWISE: Safety glasses with side shields. ontact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. See Hand protection below No special equipment needed when handling small quantities. OTHERWISE: Wear general protective gloves, e.g. light weight rubber gloves. See Other protection below No special equipment needed when handling small quantities. OTHERWISE: Overalls. Barrier cream. Eyewash unit.
Recommended material(s) GLOVE SELETION INDEX Glove selection is based on a modified presentation of the: "Forsberg lothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Respiratory protection Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Selection of the lass and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important. Material BUTL NATURAL RUBBER NEOPRENE PVA PI Required minimum protection factor Maximum gas/vapour concentration present in air p.p.m. (by volume) Half-face Respirator up to 10 1000 A-AUS / lass1 P2 Full-Face Respirator - VITON * PI - hemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion : Poor to Dangerous hoice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. up to 50 1000 - A-AUS / lass 1 P2 up to 50 5000 Airline * - up to 100 5000 - A-2 P2 up to 100 10000 - A-3 P2 100+ Airline** * - ontinuous Flow ** - ontinuous-flow or positive pressure demand A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(hn), B3 = Acid gas or hydrogen cyanide(hn), E = Sulfur dioxide(so2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 deg) SETION 9 PHSIAL AND HEMIAL PROPERTIES Information on basic physical and chemical properties Appearance Opaque liquid with a pleasant odour; miscible with water. Physical state Liquid Relative density (Water = 1) 1.0 Odour Partition coefficient n-octanol / water Odour threshold Auto-ignition temperature ( ) ph (as supplied) 7-8 Decomposition temperature Melting point / freezing point ( ) Initial boiling point and boiling range ( ) Viscosity (cst) as for water 100 approx Molecular weight (g/mol) Flash point ( ) Taste Evaporation rate as for water Explosive properties Flammability Oxidising properties Upper Explosive Limit (%) Surface Tension (dyn/cm or mn/m) Lower Explosive Limit (%) Volatile omponent (%vol) Vapour pressure (kpa) as for water Gas group Solubility in water (g/l) Miscible ph as a solution (1%) Vapour density (Air = 1) as for water VO g/l SETION 10 STABILIT AND REATIVIT Reactivity See section 7 hemical stability Possibility of hazardous reactions Product is considered stable and hazardous polymerisation will not occur. See section 7 onditions to avoid See section 7 Incompatible materials See section 7
Hazardous decomposition products See section 5 SETION 11 TOXIOLOGIAL INFORMATION Information on toxicological effects Inhaled Ingestion Skin ontact Eye hronic The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by E Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. Not normally a hazard due to non-volatile nature of product The material has NOT been classified by E Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material is not thought to produce adverse health effects or skin irritation following contact (as classified by E Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Although the liquid is not thought to be an irritant (as classified by E Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn). Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by E Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of course. TOXIIT IRRITATION alcohols 12-14 ethoxylated Legend: TOXIIT IRRITATION Oral (rat) LD50: >8000 mg/kg [2] Eye (rabbit): irritant * Skin (rabbit): irritant * 1. Value obtained from Europe EHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTES - Register of Toxic Effect of chemical Substances ALOHOLS 12-14 ETHOXLATED No significant acute toxicological data identified in literature search. Humans have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as soaps, detergents and other cleaning products. Exposure to these chemicals can occur through swallowing, inhalation, or contact with the skin or eyes. Studies of acute toxicity show that relatively high volumes would have to occur to produce any toxic response. No death due to poisoning with alcohol ethoxylates has ever been reported. Both laboratory and animal testing has shown that there is no evidence for alcohol ethoxylates (AEs) causing genetic damage, mutations or cancer. No adverse reproductive or developmental effects were observed. Tri-ethylene glycol ethers undergo enzymatic oxidation to toxic alkoxy acids. They may irritate the skin and the eyes. At high oral doses, they may cause depressed reflexes, flaccid muscle tone, breathing difficulty and coma. Death may result in experimental animal. The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin. * BASF anada ** [Henkel INFO 1450373] Acute Toxicity Skin Irritation/orrosion Serious Eye Damage/Irritation Respiratory or Skin sensitisation Mutagenicity arcinogenicity Reproductivity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard Legend: Data available but does not fill the criteria for classification Data available to make classification Data to make classification SETION 12 EOLOGIAL INFORMATION Toxicity ENDPOINT TEST DURATION (HR) SPEIES VALUE SOURE Not Available Not Available Not Available
ENDPOINT TEST DURATION (HR) SPEIES VALUE SOURE alcohols 12-14 ethoxylated Legend: L50 96 Fish 0.876mg/L 2 E50 72 Algae or other aquatic plants 0.13mg/L 2 NOE 720 Fish 0.11-0.28mg/L 2 Extracted from 1. IULID Toxicity Data 2. Europe EHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. EETO Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air No Data available for all ingredients No Data available for all ingredients Bioaccumulative potential Ingredient Bioaccumulation No Data available for all ingredients Mobility in soil Ingredient Mobility No Data available for all ingredients SETION 13 DISPOSAL ONSIDERATIONS Waste treatment methods Product / Packaging disposal Recycle wherever possible. onsult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017 Disposal Requirements Not applicable as substance/ material is non hazardous. SETION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant HAZHEM NO Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (IAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-ode / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Transport in bulk according to Annex II of MARPOL and the IB code SETION 15 REGULATOR INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture This substance is to be managed using the conditions specified in an applicable Group Standard HSR Number Group Standard HSR002530 leaning Products (Subsidiary Hazard) Group Standard 2017 ALOHOLS 12-14 ETHOXLATED(68439-50-9) IS FOUND ON THE FOLLOWING REGULATOR LISTS
New Zealand Hazardous Substances and New Organisms (HSNO) Act - lassification of hemicals New Zealand Inventory of hemicals (NZIo) Hazardous Substance Location Subject to the Health and Safety at Work (Hazardous Substances) Regulations 2017. Hazard lass Quantity beyond which controls apply for closed containers ertified Handler Subject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017. Quantity beyond which controls apply when use occurring in open containers lass of substance Quantities Refer Group Standards for further information Tracking Requirements National Inventory Status National Inventory Australia - AIS anada - DSL anada - NDSL hina - IES Europe - EINE / ELINS / NLP Japan - ENS Korea - KEI New Zealand - NZIo Philippines - PIS USA - TSA Legend: Status N (alcohols 12-14 ethoxylated) N (alcohols 12-14 ethoxylated) = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets) SETION 16 OTHER INFORMATION Revision Date 19/01/2017 Initial Date Other information Ingredients with multiple cas numbers Name alcohols 12-14 ethoxylated AS No 68439-50-9, 103819-01-8 lassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the hemwatch lassification committee using available literature references. The SDS is a Hazard ommunication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. Definitions and abbreviations P-TWA: Permissible oncentration-time Weighted Average P-STEL: Permissible oncentration-short Term Exposure Limit IAR: International Agency for Research on ancer AGIH: American onference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit IDLH: Immediately Dangerous to Life or Health oncentrations OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BF: Biooncentration Factors BEI: Biological Exposure Index This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the opyright Act, no part may be reproduced by any process without written permission from HEMWATH. TEL (+61 3) 9572 4700.