Safety Data Sheet Issuing Date 22-Sep-2015 Revision Date 22-Sep-2015 Version 3 1. Identification of the Substance/Preparation and of the Company/Undertaking Product Identifier Product Code 70301020 Product name KEYAZINE RHODAMINEB Recommended use of the chemical and restrictions on use Synonyms N/A Supplier's details Recommended use Uses advised against Industrial Use Only. Details of the Supplier of the Safety Data Sheet Keystone Corporate Office 2501 W Fulton Street Chicago, IL 60612 Ph 312-666-2015 Ph 1-800-522-4393 Emergency Telephone Number USA: 1-800-255-3924 China: (400-1)-400-120-0751 Other: Collect 1-813-248-0585 Classification Keystone Liquid Manufacturing and Technical Facility 2165 Highway 292 Inman, SC 29349 Ph 864 473-1601 2. Hazards Identification Serious eye damage/eye irritation Category 1 signal word DANGER EMERGENCY OVERVIEW hazard statements H318 - Causes serious eye damage appearance greenish powder Physical State Powder Odor mild or none precautionary statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician PAGE 1 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 Hazards Not Otherwise Classified (HNOC) OTHER INFORMATION Unknown Acute Toxicity 100 percent of the mixture consists of ingredient(s) of unknown acute toxicity 3. Composition/information on Ingredients Chemical Name CAS-No Weight % Trade secret Proprietary Proprietary 20-30 * First aid measures for different exposure routes 4. First aid measures Eye Contact Skin Contact INHALATION INGESTION Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Wash skin with soap and water. Move to fresh air. Clean mouth with water and drink afterwards plenty of water. Most important symptoms/effects, acute and delayed Main Symptoms Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. 5. Fire-fighting measures Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Keep away from heat and sources of ignition. Specific Hazards Arising from the Chemical Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with the skin and the eyes. Use personal protective equipment. For personal protection see section 8. Ensure adequate ventilation. Environmental Precautions PAGE 2 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 Environmental Precautions Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up Methods for containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Use personal protective equipment. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. Take up mechanically, placing in appropriate containers for disposal. Avoid dust formation. Clean contaminated surface thoroughly. 7. Handling and Storage Precautions for Safe Handling Advice on safe handling Avoid contact with skin, eyes and clothing. Do not breathe vapors/dust. In case of insufficient ventilation, wear suitable respiratory equipment. Wear personal protective equipment. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Provide appropriate exhaust ventilation at places where dust is formed. Do not eat, drink or smoke when using this product. Use personal protection recommended in Section 8. Conditions for safe storage, including any incompatibilities Technical measures/storage conditions Incompatible Products Store locked up. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Store in accordance with the particular national regulations. Store in accordance with local regulations. None known based on information supplied. 8. Exposure Controls/Personal Protection Control Parameters Exposure guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH DEXTRIN 10 mg/m 3 TWA Total dust 3 15 mg/m 3 TWA Total dust 5 9004-53-9 mg/m 3 Respirable mg/m 3 Respirable Exposure Controls Engineering Measures Showers Eyewash stations Ventilation systems. Apply technical measures to comply with the occupational exposure limits. Process enclosure and/or ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Tightly fitting safety goggles. Avoid contact with eyes. Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection. Skin and Body Protection. Wear protective gloves and protective clothing. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Regular cleaning of equipment, work area and clothing is recommended. Wear suitable gloves and eye/face protection. Wash hands before breaks and immediately after handling the product. Wear personal protective equipment. PAGE 3 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 9. Physical and Chemical Properties Physical and Chemical Properties Physical State appearance odor threshold Powder greenish powder Odor mild or none Property VALUES Remarks Method ph 4.00 melting point N/A Boiling point/boiling range Flash Point Evaporation Rate no data available flammability (solid, gas) no data available no data available Flammability Limits in Air Upper Flammability Limit Lower Flammability Limit vapor pressure Vapor Density Specific gravity N/A Solubility in Other Solvents Partition coefficient: n-octanol/water Autoignition Temperature No Data Available N/A decomposition temperature Kinematic viscosity No Data Available Dynamic viscosity Explosive Properties Oxidizing properties OTHER INFORMATION softening point Molecular Weight. VOC Content(%) density 10. Stability and Reactivity Reactivity no data available Chemical Stability Stable under recommended storage conditions. Hazardous Reactions None under normal processing Conditions to avoid Extremes of temperature and direct sunlight. incompatible materials None known based on information supplied. Hazardous decomposition products May emit toxic fumes under fire conditions. Information on Likely Routes of Exposure 11. Toxicological Information Product information Product does not present an acute toxicity hazard based on known or supplied information INHALATION Avoid breathing vapors or mists. PAGE 4 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 Eye Contact Skin Contact INGESTION Corrosive to the eyes and may cause severe damage including blindness. Avoid contact with skin. Not an expected route of exposure. Do NOT taste or swallow. Information on Toxicological Effects Symptoms Delayed and immediate effects as well as chronic effects from short and long-term exposure sensitization Germ cell mutagenicity carcinogenicity. Chemical Name ACGIH IARC NTP OSHA Proprietary Group 3 IARC: (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive Toxicity Specific target organ systemic toxicity (single exposure) Specific target organ systemic toxicity (repeated exposure) Aspiration Hazard Numerical Measures of Toxicity - Product information Unknown Acute Toxicity 100 percent of the mixture consists of ingredient(s) of unknown acute toxicity 12. Ecological Information ecotoxicity 100% of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and Degradability Bioaccumulation Other Adverse Effects 13. Disposal Considerations Waste treatment Waste Disposal Methods Contaminated Packaging Should not be released into the environment. Dispose of in accordance with local regulations. This material, as supplied, is not a hazardous waste according to state and federal regulations (40 CFR 261). Do not re-use empty containers. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION PAGE 5 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 DOT Description NOT REGULATED MEX IATA Description IMDG Description NOT REGULATED NOT REGULATED RID ADN 15. Regulatory Information International Inventories TSCA EINECS/ELINCS DSL NDSL PICCS ENCS IECSC AICS KECL NZIoC Not Determined Not Determined Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals REACH registration number Keystone has taken all relative steps to ensure REACH-Compliance. Please contact us with any REACH-Related questions at REACH@Keystone-Europe.CO.UK RESTRICTIONS - REACH TITLE VIII US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name SARA 313 - Threshold Values % Proprietary 1.0 SARA 311/312 Hazard Categories Acute health hazard YES. PAGE 6 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 Chronic health hazard NO. Fire hazard NO. Sudden Release of Pressure Hazard NO. Reactive Hazard NO. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Proprietary X X X International regulations CANADA WHMIS Note This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials HMIS Health Hazard 1 flammability 1 Physical hazard 0 PERSONAL PROTECTION F PAGE 7 / 8
70301020 / KEYAZINE RHODAMINEB Revision Date 22-Sep-2015 16. Other Information Revision Date Revision note Restrictions on use 22-Sep-2015 Contact Information Website WWW.DYES.COM. Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text End of Material Safety Data Sheet PAGE 8 / 8