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Transcription:

Section 1 - Product and Company Identification Hot Shot Ant & Roach Plus Germ Killer 2 Unscented Hot Shot Ant & Roach Plus Germ Killer 2 Fresh Floral Scent Hot Shot Ant & Roach Plus Germ Killer 2 Lemon Scent EPA Reg..: 9688-317-8845 Product Use: Crawling Bug Aerosol Manufacturer: Chemsico Div. of United Industries Corp. St. Louis, MO 63114 1-800-917-5431 Section 2 - Hazards Identification Conforms to Hazard Communication Standard 29 CFR 1910.1200. Classification of Substance or Mixture: Flammable aerosol Category 2 GHS Label Elements Hazard pictogram: Signal word: Hazard statements: Precautionary Statements: WARNING Flammable aerosol Compressed gas contents under pressure; may burst if heated Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Contents under pressure. Do not store near heat or open flame. Do not puncture or incinerate container. Exposure to temperatures above 130 F may cause bursting. Section 3 - Composition / Information on Ingredients Page 1 Composition comments: This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). NOTE: reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. ACTIVE COMPONENT CAS# PERCENTAGE Cypermethrin 52315-07-8 0.100% Prallethrin 23031-36-9 0.025% Alkyl dimethyl benzyl ammonium chlorides 85409-23-0 0.055% Alkyl dimethyl ethylbenzyl ammonium chlorides 68391-01-5 0.055%

Petroleum distillates, light 64742-47-8 4.000% 1-butoxy-2-propanol 5131-66-8 6.000% Isobutane 75-28-5 1.620% Propane 74-98-6 2.880% OTHER COMPONENT CAS# PERCENTAGE Other N/A 85.465% te: Ingredients not identified are not hazardous. Section 4 - First Aid Measures Eye contact: Skin contact: Inhalation: Ingestion: te to Physician: General advice: ne required Flush with large amounts of cool water. Wash with soap and water. Remove contaminated clothing and wash before reuse. Obtain medical attention if irritation persists. Prolonged or repeated skin contact may cause allergic reaction in some individuals. t an inhalation hazard. t an ingestion hazard. ne If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. Section 5 - Fire Fighting Measures Flammable properties: NFPA classification: Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Pressurized aerosol container NFPA level 1 aerosol Water fog, foam, CO 2, dry chemical Aerosol product container may burst in heat of fire. Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus. Hazardous combustion products: Explosion data: Sensitivity to static discharge: Personal precautions: ne known Keep unnecessary personnel away. Do not touch or walk through spilled material. HMIS ratings: Health Hazard 0 Fire Hazard 2 Reactivity 0 Page 2

Section 6 - Accidental Release Measures Personnel precautions: For emergency responders: Environmental precautions: Methods for containment and cleaning up: Remove all sources of ignition. Wear personnel protective equipment. Wash thoroughly after handling. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Stop leak if without risk. Move containers from spill area. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. Section 7 - Handling and Storage Precautions for safe handling: Storage: Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with skin, eyes and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not store above 50 C (122 F). Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. Section 8 - Exposure Controls / Personal Protection Engineering controls: Eye/Face protection Personal protective equipment: Hand protection: Skin and body protection: Respiratory protection: General ventilation normally adequate. ne required ne required ne required ne required Page 3

General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. Section 9 - Physical & Chemical Properties Appearance: Color: Form: Odor: Odor threshold: Physical state: Clear Light yellow to water-white Aerosol ph: 7-7.5 Freezing point: 32 F Boiling point: 212 F Flash point: Flame Extension Flammability limits in air, lower, % by volume: Flammability limits in air, upper, % by volume: Vapor pressure: Vapor density: Specific gravity: 0.978 Octanol/water coefficient: Auto-ignition temperature: Chemical stability: Conditions to avoid: Incompatible materials: Aromatic solvent (slight) Pressurized liquid 119 0 F (liquid portion) 0 (level 1 aerosol) Section 10 - Chemical Stability & Reactivity Information Stable under recommended storage conditions. Do not mix with other chemicals. Avoid strong oxidizers. Hazardous decomposition products: ne known. Possibility of hazardous reactions: Section 11 - Toxicological Information Hazardous polymerization does not occur. Effects of acute exposure Eye: Skin: Inhalation: Page 4 n-irritating (Category IV) Allergic reaction possible. LD 50 > 5000 mg/kg LC 50 > 2mg/L (EPA Tox category IV)

Ingestion: Sensitization: Chronic effects/ Carcinogenicity: Mutagenicity: Reproductive effects: Teratogenicity: Ecotoxicity: LD 50 > 5000 mg/kg May cause allergic reaction after repeated contact. Section 12 - Ecological Information Environmental effects: Aquatic toxicity: Persistence / degradability: Bioaccumulation / accumulation: Partition coefficient: Mobility in environmental media: Chemical fate information: Toxic to aquatic organisms Section 13 - Disposal Considerations Waste codes: Disposal instructions: Waste from residues / unused products: Contaminated packaging: t Available Dispose in accordance with all applicable regulations. t Available t Available Section 14 - Transportation Information U.S. Department of Transportation (DOT): U.S. Federal regulations: IATA: UN-1950, Aerosols, 2.1 IMDG: Aerosols, Flammable, 2.1, UN-1950, Limited Quantity This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. UN-1950, Aerosols, Flammable (Cypermethrin), 2, Marine Pollutant Section 15 - Regulatory Information Page 5

29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): CERCLA (Superfund) reportable quantity: t Available Hazard categories Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard Delayed Hazard Fire Hazard Pressure Hazard Reactivity Hazard Section 302 extremely hazardous Substance: Section 311 hazardous chemical: Clean Air Act (CAA): Clean Water Act (CWA): State regulations: t Available t Available INVENTORY STATUS Inventory Country(s) or region name on inventory (yes/no)*: Disclaimer: N/A, Regulated by EPA Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. SECTION 16 - OTHER INFORMATION Issue date: 10/26/15 Prepared by: United Industries Corp. (800) 242-1166 Page 6