MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Revision date 02-02-2012 Version # 01 CAS # Mixture Product code 47106, 47107 Product use Anti-fog agent Manufacturer Telephone Distributor E-mail General Assistance Emergency Telephone USA Europe, Middle East, Africa Asia Pacific Access code Kwick Paint Products 6040 Russell Detroit, MI48211 1-87-8800 Pittsburgh Glass Works, LLC 0 Isabella Street Suite 500 Pittsburgh, PA 15212 US info@pgwglass.com 1-800-861-4999 1-760-476-962 +1-760-476-961 +1-760-476-960 225 2. Hazards Identification Physical state Appearance Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Potential environmental effects Liquid. Clear liquid. WARNING! FLAMMABLE LIQUID AND VAPOR. Causes eye irritation. This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). Eye contact. Skin. Causes eye irritation. Prolonged or repeated contact may dry skin and cause irritation. Vapors may cause drowsiness and dizziness. May cause discomfort if swallowed. Skin. Eyes. Respiratory system Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.. Composition / Information on Ingredients CAS # Percent Water 772-18-5 75 Ethanol 64-17-5 11 Isopropyl alcohol 67-6-0 5 Polymodified seloxane complex NA 5 Sodium dodecylbenzenesulfon ate 25155-0-0 4 Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 1 / 7
4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice Immediately flush eyes with plenty of water for at least 15 minutes. Remove any contact lenses. Continue rinsing. Get medical attention. Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Use soap if available. Get medical attention if irritation develops or persists. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Get medical attention if symptoms occur. Treat symptomatically. Keep victim warm. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Fire fighting equipment/instructions Specific methods Hazardous combustion products Flammable liquid and vapor. Vapors may cause a flash fire or ignite explosively. Vapors may travel considerable distance to a source of ignition and flash back. Prevent build-up of vapors or gasses to explosive concentrations. Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Self-contained breathing apparatus operated in positive pressure mode and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Move container from fire area if it can be done without risk. Carbon oxides. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Local authorities should be advised if significant spillages cannot be contained. Keep people away from and upwind of spill/leak. Keep out of low areas. Ventilate closed spaces before entering them. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not contaminate water. Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas. Eliminate all ignition sources. Use water spray to disperse vapors and dilute spill to a nonflammable mixture. Prevent runoff from entering drains, sewers, or streams. Dike for later disposal. Large Spills: Dike far ahead of spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Other information Never return spills to original containers for re-use. Clean up in accordance with all applicable regulations. 7. Handling and Storage Handling Storage Wear protective clothing as described in Section 8 of this safety data sheet. Avoid breathing mists or vapors. Avoid contact with skin and eyes. Do not taste or swallow. Do not eat, drink or smoke when using the product. Use only with adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wash thoroughly after handling. Keep away from heat, sparks, and flame. Store in accordance with local/regional/national/international regulation. Keep only in the original container in a cool, well-ventilated place. Protect from direct sunlight. Store away from incompatible materials (see Section 10 of the MSDS). Keep away from food, drink and animal feedingstuffs. Keep container tightly closed. Do not store in open or unlabelled containers. Keep out of the reach of children. 2 / 7
8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit s Ethanol (64-17-5) STEL Isopropyl alcohol (67-6-0) STEL US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Ethanol (64-17-5) PEL 1900 mg/m Isopropyl alcohol (67-6-0) PEL 980 mg/m Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Ethanol (64-17-5) 1880 mg/m Isopropyl alcohol (67-6-0) STEL 984 mg/m 492 mg/m Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Ethanol (64-17-5) STEL Isopropyl alcohol (67-6-0) STEL Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Ethanol (64-17-5) STEL Isopropyl alcohol (67-6-0) STEL Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Ethanol (64-17-5) 1880 mg/m Isopropyl alcohol (67-6-0) STEL 120 mg/m 500 ppm 98 mg/m Mexico. Occupational Exposure Limit s Ethanol (64-17-5) 1900 mg/m Isopropyl alcohol (67-6-0) STEL 1225 mg/m 500 ppm 980 mg/m Engineering controls Personal protective equipment Eye / face protection Skin protection Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control sources of dust, mist or vapor. Provide eyewash station. Wear safety glasses with side shields (or goggles). Full body suit and boots are recommended when handling large volumes or in emergency situations. For prolonged or repeated skin contact use suitable protective gloves. The use of nitrile-latex gloves is recommended. Suitable gloves can be recommended by the glove supplier. / 7
Respiratory protection General hygiene considerations Use a NIOSH/MSHA approved air purifying respirator as needed to control exposure. Consult with respirator manufacturer to determine respirator selection, use, and limitations. Use positive pressure, air-supplied respirator for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow respirator protection program requirements (OSHA 1910.14 and ANSI Z88.2) for all respirator use. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. Do not get in eyes. Avoid contact with skin. Do not get this material on clothing. When using, do not eat, drink or smoke. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice. 9. Physical & Chemical Properties Appearance Clear liquid. Color Clear. Odor Alcohol odor. Odor threshold Physical state Liquid. Form Liquid. ph Melting point Freezing point Boiling point Flash point 58 F (14.4 C) Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity 0.994 Solubility (water) Soluble Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Stable at normal conditions. Contact with incompatible materials. Heat and direct sunlight. Strong oxidizers, strong acids, and strong bases. No hazardous decomposition products are known. Hazardous polymerization does not occur. 11. Toxicological Information Acute effects Sensitization Causes eye irritation. This material has a low potential to cause allergic skin reactions; however, cases of human skin sensitization have been reported. Chronic effects Prolonged or repeated contact may dry skin and cause irritation. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH Carcinogens A4 Not classifiable as a human carcinogen. Epidemiology 4 / 7
Mutagenicity Neurological effects Reproductive effects 12. Ecological Information Ecotoxicity Environmental effects Persistence and degradability Bioaccumulation / Accumulation Partition coefficient (n-octanol/water) Mobility in environmental media No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Vapors may cause drowsiness and dizziness. This product is not reported to cause reproductive effects in humans. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 1. Disposal Considerations Waste codes D001: Waste Flammable material with a flash point <140 F Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near this container. 14. Transport Information DOT UN number UN1987 Labels required Additional information: Special provisions 172, B1, IB, T4, TP1, TP29 Packaging exceptions 4b, 150 Packaging non bulk 20 Packaging bulk 242 ERG number 127 IATA UN number 1987 Additional information: ERG code L IMDG UN number 1987 EmS No. F-E, S-D TDG 5 / 7
UN number Additional information: Special provisions UN1987 16 15. Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D) Not regulated. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 02.4) Sodium dodecylben zenes ulfonate: 1000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 02 extremely hazardous substance (40 CRF 55, Appendix A) Section 11/12 (40 CFR 70) Drug Enforcement Administration (DEA) (21 CFR 108.11-15) Canadian regulations WHMIS status WHMIS classification WHMIS labeling Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No No Yes Not controlled This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Controlled B2 - Flammable/Combustible D2B - Other Toxic Effects-TOXIC State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance Sodium dodecylbenzenesulfonate (CAS 25155-0-0) US - Massachusetts RTK - Substance: Listed substance Sodium dodecylbenzenesulfonate (CAS 25155-0-0) US - New Jersey Community RTK (EHS Survey): Reportable threshold 500 LBS US - New Jersey RTK - Substances: Listed substance Sodium dodecylbenzenesulfonate (CAS 25155-0-0) US - Pennsylvania RTK - Hazardous Substances: Listed substance Sodium dodecylbenzenesulfonate (CAS 25155-0-0) 16. Other Information Further information HMIS is a registered trade and service mark of the NPCA. 6 / 7
HMIS ratings Health: 2 Flammability: Physical hazard: 0 NFPA ratings Health: 1 Flammability: Instability: 0 Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PGW, and to recommend precautionary measures for the storage and handling of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Issue date 02-02-2012 7 / 7