Changes Between API STD 521 6th Ed and 5th Ed Cataloged

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Changes Between API STD 521 6th Ed and 5th Ed Cataloged Dustin Smith Smith & Burgess LLC 7600 W Tidwell, Houston, TX Dustin.Smith@smithburgess.com John Burgess Jarrett Doe Smith & Burgess LLC 7600 W Tidwell, Houston, TX Smith & Burgess LLC grants AIChE permission for itself and its designated agents to reproduce, sell, or distribute this paper. Copyright to this paper is retained by Smith & Burgess LLC, from whom permission to reproduce must be obtained by any other party. All information deemed reliable but may not be applicable to any given installation. Any risk assessment or safety analysis should be independently verified by a qualified engineer. Prepared for Presentation at American Institute of Chemical Engineers 2015 Spring Meeting 11th Global Congress on Process Safety Austin, Texas April 27-30, 2015 UNPUBLISHED AIChE shall not be responsible for statements or opinions contained in papers or printed in its publications

Changes Between API STD 521 6th Ed and 5th Ed Cataloged Dustin Smith John Burgess Jarrett Doe Smith & Burgess LLC 7600 W Tidwell, Houston, TX Dustin.Smith@smithburgess.com Keywords: API STD 521, PSM Compliance, Relief Systems Design, ASME Pressure Relief Device Design, Analysis Overpressure Abstract API STD 521, Pressure-relieving and Depressuring Systems, is perhaps the most thorough published guideline on how to size relief devices and flare systems. This paper reviews the differences between the 6 th Edition of API STD 521 (Published in 2014) and the 5 th edition (Published in 2007). The authors will review changes and highlight several new requirements that are deemed critical to relief systems design. The paper is based on a comprehensive review of the two editions and is a valuable resource for any engineer or process designer who needs to be knowledgeable of the latest relief systems recommendations. 1. Background This paper provides the reader with a summarized listing of the changes between the current (6 th edition) and past (5 th edition) of API Standard 521, Petroleum and natural gas industries Pressure-relieving and depressuring systems (hereafter referred to as 521") [1, 2]. This API document provides guidance for determining overpressure scenarios, determining the required relief rate for sizing a relief device, and criteria and considerations for sizing a disposal system. As Table 1 shows, a considerable amount of guidance has been added to the 6 th edition of 521. Table 1. Summary of Guidance in the 6 th /5 th Editions of API STD 521 Items 5 th Edition (2007) 6 th Edition (2014) Should Appears 515 611 Shall Appears 137 154 Pages 196 248 ISO Co-branded Yes No The 5 th edition was co-branded as an International Organization for Standards (ISO 23251) and American Nation Standards Institute (ANSI) standard. The current (as of the time of writing) 6 th Edition is neither an ISO nor ANSI standard. Note: Do not add page numbers. Do not refer to page numbers when referencing different portions of the paper

In addition, a special note was added to ensure that the users knew relief systems design and engineering problems are installation specific, and need to be designed/engineered by a competent person knowledgeable in the art of pressure relief system design. 1.1 Terms and usage The following familiarizes the reader of this paper with acronyms and terms that may be encountered. 1.1.1 SCPRS The API Committee on Refinery Equipment (CRE) subcommittee that is responsible for 521 is the Subcommittee on Pressure-Relieving Systems (SCPRS). 1.1.2 Section References Section numbers that are prefaced by reference the API standard and not this paper. Unless otherwise mentioned, the section numbers referred to are for the 6 th ed. of 521. 2. Summary of changes The changes are broken down into the following categories. The remainder of this paper will follow the order shown in the following table. Table 2. Organization of the Summary of the Changes. Paper Section Topic Items 2.1 Moved Material 104 2.1 Clarified 12 2.2 New Definitions 14 2.3 Deleted 9 2.4 Equation Modifications 2 2.5 New Sections 24 2.6 Additional Requirements or Guidance 29 Total 194 2.1 Moved Material / Clarified The SCPRS spent a lot of time trying to organize and clarify this standard. This work was performed to ensure a more useful resource for the end users. As a result a majority of the changes are text moving from one section to another. These changes are numerous, pervasive and do not change the guidance. Therefore, they are not further elaborated in this paper.

2.2 New Definitions The 6 th edition of API STD 521 has had additional definitions added into 3.1 Terms and Definitions. The following terms have been defined. 3.1.5 availability 3.1.8 blowdown drum 3.1.16 choke valve 3.1.19 combustion efficiency 3.1.20 confined fire 3.1.36 fuel-controlled fire 3.1.44 lift-off (Substituted for blow-off) 3.1.49 molecular mass 3.1.51 open fire 3.1.58 pressure-relief device 3.1.60 pressure system 3.1.69 required relief rate 3.1.70 risk 3.1.85 ventilation-controlled fire A few of the definitions have been further discussed in this paper. The reader of this article is encouraged to further read the standard to get the official definition which is not included herein. 2.2.1 Confined Fire / Open Fire The SCPRS introduced a new definition, concept, and requirements. These specify that if a fire is confined, the heat flux requirements are higher than an open pool fire (see 4.4.13.3). The open pool fire is the historical fire method in 521. 2.2.2 Risk In the 5 th edition, risk was addressed throughout the document and specifically in Annex E. The 6 th edition provides the first definition for use in 521 and related relief device decisions. 2.3 Deleted The following items were addressed in the 5 th edition of 521, but have not been included in the 6 th edition. The section numbers refer to the 5 th edition. 3.7 blowdown (Definition) 3.9 breaking-pin device (Definition) 3.17 closed disposal system (Definition) 3.37 huddling chamber (Definition) 3.46 marked burst pressure (Definition) 3.53 pin device (Definition) 3.71 shear pin device (Definition) 7.3.1.2 design of relief device inlet piping The SCPRS deleted the design of relief systems inlet piping from API 521 as it is covered in API STD 520 Part II.

2.4 Equation Modifications The following equations were modified between the 5 th and 6 th editions. 2.4.1 Estimation of Purge Gas Requirements (Eq. 46/47 6 th Ed.) The Ci term is for the volume fraction of a component in the purge gas and has been changed from a percentage to a fraction. This is for Equations 46/47 in 5.7.6.2 in the 6 th edition (Equations 59/60 in 7.3.3.3.3 in the 5 th edition). 2.4.2 Equation determining the droplet Velocity in a Flare Knockout Drum (Eq. 55-57, 6 th Ed.) In the 6 th edition, the density of the vapor term has been added to the equation determining the droplet velocity in a flare knockout drum. This applies to Equations 55-57 in 5.7.9.5 in the 6 th edition (Equations 37-39 in 7.3.2.1.2 in the 5 th edition). Note that these this change was included in the 5 th edition with the May 2008 Addendum. 2.5 New Sections The following sections were added or significantly modified between the 5 th and 6 th editions. 2.5.1 Additional Considerations Involving Pumps ( 4.4.2.2) The 6 th edition provides new guidance on overpressure protection for pumps. centrifugal pumps don't require overpressure protection. In general, 2.5.2 Additional Considerations Involving Reciprocating Compressors ( 4.4.2.3) The 6 th edition provides new guidance on overpressure protection for reciprocating compressors. 2.5.3 Choke Valve Failure ( 4.4.8.6) The 6 th edition provides new guidance on overpressure protection specifically related to choke valves failing. 2.5.4 Estimating the Required Relief Rate from Check Valve Failure ( 4.4.9.3.3) The 6 th edition provides new guidance on estimating the required relief rate from a failed check valve. One method is based on the size of the valve and the other is based on the normal forward flow. 2.5.5 Reciprocating Compressor Rod Packing Failure ( 4.4.9.4) The 6 th edition provides new guidance on overpressure protection for reciprocating compressors specifically related to the failure of rod packing and how to estimate the required relief rate.

2.5.6 Alternative Method to Estimate Overpressure from External Fire ( 4.4.13.2.4.4) The 6 th edition provides new guidance on overpressure protection from fire in the event that a fluid phase change does not occur. 2.5.7 Confined Pool Fires ( 4.4.13.3) The 6 th edition provides new guidance on estimating the required relief rate from a fire inside a building or in a confined area. The methods in the previous (5 th and older) editions of 521 predict a lower relief rate for these cases. 2.5.8 Additional Considerations for Plate and Frame Exchanger ( 4.4.14.4) The 6 th edition provides new guidance on overpressure protection for plate and frame exchangers. In general, full plate failure is not considered likely but a failure from a hole caused by corrosion should be considered. 2.5.9 Overpressure Prevention during Maintenance ( 4.4.16) The 6 th edition includes a new section providing guidance for considering overpressure protection during maintenance activities. 2.5.10 Initiation of Depressuring ( 4.6.2) The 6 th edition provides a new section with descriptive information and considerations for initiating an emergency depressuring system including a fire and gas detection system. 2.5.11 Depressuring Low Temperature Considerations ( 4.6.3) The 6 th edition provides a new section with descriptive information on the potential for autorefrigeration from depressuring some process systems. 2.5.12 Flare and Outlet Piping Acoustic Fatigue ( 5.5.12) The 6 th edition provides a new requirement with the addition of substantive new guidance and requirements on evaluating acoustic fatigue in flare headers primarily based on the work of Carucci and Mueller [3, 4]. This section adds an additional requirement for flare systems design based on past incidents. 2.5.13 Flame Stability ( 5.7.2.4) The 6 th edition provides a new section with descriptive information on flare flame stability and common language to describe flame instability.

2.5.14 Noise from Smokeless Flaring ( 5.7.3.2.11) The 6 th edition provides a new section with descriptive information on the issues associated with noise caused when adding assist fluid to attempt smokeless flaring. 2.5.15 Pilot Ignition Systems and monitoring ( 5.7.7.3 and 5.7.7.4) The 6 th edition provides new sections with descriptive information on pilot ignition systems and methods for monitoring pilots. These sections refer the users to API STD 537 for additional guidance. [5] 2.5.16 Flare Knockout Drum ( 5.7.9.1) The 6 th edition provides a new section with descriptive information in regards to the location of a flare knockout drum. 2.5.17 Risk of Overfilling Flare Knockout Drum ( 5.7.9.6) The 6 th edition provides new requirements that shall be considered (i.e. are required) in reference to flare knockout drums being overfilled (or those that have the potential to be overfilled). 2.5.18 Production Facility Flare Knockout Drums ( 5.7.9.8) The 6 th edition provides a new section giving guidance for knock out drum sizing due to the special nature of production facilities. 2.5.19 Siting Considerations for Flares ( 5.7.10) The 6 th edition provides a new section with guidance associated with facility siting concerns for flares (topography and dispersion). 2.5.20 Alternative Analytical Method (Fire, Annex A.3) The 6 th edition provides a new section that provides an alternative means to estimate the heat loads from an external fire. The analytical method can apply to situations where the guidance in the main body may not be applicable (e.g. vapor/jet fires). 2.6 Additional Requirements or Guidance The following existing sections were modified in ways that, in the opinion of the Authors, provide additional requirements or guidance. If the reader of this paper designs or audits relief systems, then he or she is encouraged to purchase a copy of the 6 th edition of API STD 521 to ensure designs are per the most recent guidance. The information contained herein is insufficient for design.

2.6.1 Operator Error/ Response Criteria ( 4.2.5) The Operator Error and Effect of Operator Response sections ( 4.2.3 and 5.4) in the 5 th edition combined to create 4.2.5 with additional recommendations for operator response in overpressure protection. Identifies criteria for deciding to consider operator intervention for relief systems design. 2.6.2 Inadvertent Valve Opening ( 4.4.9.2) The 5 th edition sections on Inadvertent Valve Opening and Opening Manual Valves ( 4.3.3 and 5.17) were combined and new guidance on relief rate determination provided. Clarification that opening of multiple valves may be credible under certain circumstances was added. 2.6.3 Check Valve Leakage or Failure ( 4.4.9.3) The 6 th edition moved this section and provides new guidance on determining the required relief rate. The wording is less strong (as compared to the 5 th Edition) and additional guidance on inspection and testing of check valves is provided. 2.6.6 Relief Systems Documentation Requirements ( 4.7) In the 6 th edition, the Relief System Design Documentation section was overhauled. The language from the 5 th edition was softened to ensure the guidance was not confused as a requirement. Additional suggestions on nature, type, and goal of relief system design documentation were included. 2.6.7 Level Instrumentation ( 4.4.7.3) The section providing guidance on level instrumentation was moved and four additional criteria for consideration of level valve independence were added. 2.6.8 Depressuring Systems Design Criteria ( 4.6.5) The 6 th edition provides a new requirement that the discharge location of a depressuring system shall be a safe location. 2.6.9 Liquid Overfilling ( 4.4.7) The 6 th edition provides more concrete language around evaluating the design of systems for overpressure protection from liquid overfilling. 2.6.11 Header Segregation ( 5.4.4) The 6 th edition consolidated the guidance related to header segregation and added a list of criteria to consider when designing a flare system with for multiple relief devices, all of which are recommendations (should).

2.6.12 Pipe Anchors, Guides, and Supports ( 5.5.16) The 6 th edition updates and consolidates information on Pipe Anchors, Guides, and Supports into a section of the same name providing additional guidelines to design effective pipe anchors and supports. 2.6.13 Flaring Guidance on Smokeless Requirements ( 5.7.3.1) The 6 th edition provides additional guidance as to when the user is to and how the user should specify the smokeless requirements for a flare. 2.6.14 Flares with Smoke Suppression ( 5.7.3.2) The 6 th edition provides additional guidance on how flares achieve smokeless operation and/or suppress the generation of smoke. 2.6.15 Ground Flares ( 5.7.4.1) Additional guidance provided on the design, specification, and operation of ground flares including a reference to API STD 537 for more detailed description. 2.6.16 Steam Injection for Smokeless Operation ( 5.7.3.2.2) The notes for Table 14 (Table 11 in 5 th edition) are updated to ensure that the user is properly specifying and designing the steam injection for smokeless flare operation. 2.6.17 General Purge Requirements ( 5.7.6) The section is updated and organized to include all design aspects of purging a disposal system to reduce the possibility of flashback. 2.6.18 Seal Drum Design ( 5.7.8.7) The 6 th edition provides new equation / criteria to determine the minimum required diameter for a vertical seal drum and minimum free liquid surface area of a horizontal seal drum (Equations 50 and 51). 2.6.19 Flare Knockout Drum ( 5.7.9.2) The 6 th edition provides new guidance "In general, vapor outlet nozzles should not be fitted with any devices (e.g. deflection plates). which is opposite of previous guidance. This is due to an incident where a flare drum internal blocked the flare system of a platform on the Visund field. For more information on this incident see the PSA investigation online [6].

2.6.20 Flare Liquid Separation Droplet Size ( 5.7.9.4) The 6 th edition provides additional guidance for different types of flares that can handle different liquid loading and droplet sizes. 2.6.20 Vent Stacks ( 5.8.8) The 6 th edition provides additional guidance given for vent tips in applications where existing space and other restrictions have to be considered. 2.6.21 Sizing of Vent Stacks ( 5.8.10.3.1) The 6 th edition provides updates to the calculation of noise level for vent stacks. If the reader is designing a vent stack they should be warned that the Vent Stacks section ( 5.8.10) contains shall 8 different times. 2.6.23 Sample Calculations (Annex C) The 6 th edition provides all the sample calculations in a single location, Annex C. 2.6.24 High-integrity Protection Systems (Annex E) The 6 th edition changes the ASME Boiler and Pressure Vessel Code exception that allows instrumentation in lieu of relief devices from Code Case 2211-1 to UG-140. This was adopted in the 2008 addendum to the 2007 publication of ASME B&PVC Section VIII Division I. [7] The author has previously written more information on the specific requirements to use instrumentation / system design instead of relief devices in accordance with UG-140. [8] 3. Conclusion The 6 th Edition of API STD 521 has been reformatted and updated. This document has changed extensively from the previous addition. The following lists the largest changes (in the view of the authors) for this document: Guidance on Flare Knockout Drum internals is opposite of previous editions of this standard. New requirements for acoustically induced vibrations are included. Confined external fires are defined and guidance is provided.

4. References [1] API Standard 521, FIFTH ED., JANUARY 2007 (w/ ERRATA JUNE 2007) ADDENDUM, MAY 2008 ISO 23251 (Identical), Petroleum and natural gas industries Pressure-relieving and depressuring systems [2] API Standard 521, SIXTH ED., JANUARY 2014, Petroleum and natural gas industries Pressure-relieving and depressuring systems [3] V. A. Carucci and R. T. Mueller, Acoustically Induced Piping Vibration in High Capacity Pressure Reducing Systems, ASME 82-WA/PVP-8; 1982. [4] J. Cowling, Design Strategies for Acoustically Induced Vibration in Process Piping, INTER-NOISE 2012 Proceedings, August 9 22, 2012, New York, available from Institute of Noise Control Engineering of the USA (INCE/USA) [5] API Standard 537, Flare Details for General Refinery and Petrochemical Service [6] PSA completes investigation of Visund incident, June 2006, http://www.psa.no/news/psacompletes-investigation-of-visund-incident-article2733-878.html (accessed March. 15, 2015) [7] American Society of Mechanical Engineers. 2007 ASME Boiler & Pressure Vessel Code: Section VIII,Division I. with 2008 Addendum [8] Smith, D. J. (2014), Safety instrumented systems in lieu of pressure relief valves. Proc. Safety Prog., 33: 345 349. doi: 10.1002/prs.11681