Re-Tek SAFETY DATA SHEET

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Transcription:

Re-Tek SAFETY DATA SHEET SECTION 1. Identification Product identifier: Soft Landing Rubber Mulch Substances Cured Black SBR Rubber +5 Buffings Trade name / designation: SBR Rubber Strands (Cured) Uses of the substance Playground fill and Landscape application Details of the supplier of the safety data sheet: Re-Tek Inc. 3320 Cleaton Rd. Central City, KY 42330 Fax# 502-415-7299 Emergency contact : 270-757-1919 SECTION 2. Hazard Identification GHS Classification of substance Hazardous Materials Descriptions and Proper Shipping Name: Hazardous Class: Chemical Family: Formula: Precautionary statements Effects of Overexposure: Threshold Limit Value: Permissible Exposure Limit: None SECTION 3. Composition/Information on Ingredients

Name CAS Registry No. % NR 80 44 CIS-Polybutadine 20 11 HAF Black 60 33 Oil (Softener) 10 5.5 Stearic Acid 2 1.1 Wax 2 1.1 Zinc Oxide 3 1.7 Sulfur 2 1.1 NOBS.7.4 ANTIOZ. 2 1.1 SECTION 4. First Aid Measures Eye: If eyes become irritated from hot vapors or dust, flush with water for 10-15 minutes If irritation persist, get medical attention. Skin: Change soiled clothes and wash hands and other exposed skin surface thoroughly with soap and water. If irritation persist, consult doctor. Inhalation: Inhalation under ambient and ventilated processing conditions is normally not a problem. If vapors from hot product are inhaled, immediately remove from exposure. If symptoms persist, call a physician. If breathing stops, provide artificial respiration. Ingestion: Not a likely route of entry. No known ill effects. Rinse mouth thoroughly and drink plenty of water. Get immediate medical attention if symptoms occur. SECTION 5. Firefighting measures Extinguishing Media: Water, Foam, or Dry Chemical Extinguisher. Water maybe ineffective but maybe used to cool fire exposed containers, structures, and to protect

personnel. Special Fire Fighting Procedures: Firefighter to wear Self-Contained breathing Apparatus with full mask and full protective clothing. Unusual Fire/Explosion Hazard: Dangerous when exposed to heat or flame due to inhalation risk. Product does not present any known explosion hazard. No determined flash point. Combustion products: Dangerous when exposed to heat and/or exposure to nitrogen containing materials can form higher amounts of nitrosoamines. Which are believed to present a health hazard and are carcinogens in animals. SECTION 6. Accidental release measures Spill Procedures: Manual sweep or shovel. Repackage uncontaminated product. Otherwise no unusual hazards. Dispose of contaminated products in accordance all applicable federal, state, and local regulations for non-hazardous waste. SECTION 7. Handling and storage Avoid getting in eyes. Use good personal hygiene practices. Wash hands and other exposed skin surfaces thoroughly before eating, drinking, or smoking. Mechanical exhaust required for hot processing such as curing or extrusion. Store in a cool, dry place out of direct sunlight, otherwise no special precautions known to be needed for storage. SECTION 8. Exposure controls/personal protection Exposure limits Chemical Name ACGIH OSHA Carbon Black 3.5 mg/m 3 3.5 mg/m 3

Sulfur None Established None Established Zinc Oxide 2mg/m 3 (Respirable Fraction) 5mg/m 3 (Respirable Fraction) Component Engineering controls: Provide adequate ventilation. When product used under normal temperature conditions, standard indoor air quality ventilation needed. If heated for extrusion, local exhaust ventilation in combination with general ventilation maybe necessary to control air contaminants to their exposure limits. Employees must avoid inhaling fumes from hot rubber processing. Respiratory Protections: No protection is ordinarily required under normal conditions and sufficient ventilation. During hot rubber processing use NIOSH approved respirator. Eye Protection: Safety goggles/glasses should be worn. Hand Protection: Gloves should be worn for prolonged contact. Thermal gloves when material is heated. Skin Protection: Minimize skin contact. SECTION 9. Physical and chemical properties Appearance and Odor: Black Strands-Characteristic Rubber Odor Solubility in Water: Not Soluble Specific Gravity: 1.20+/-.05 (Water = 1.0) Boiling Point Vapor Pressure & Density: Evaporation Rate: Percent Volatile by Volume: ph Flashpoint Not determined SECTION 10. Stability and reactivity This product is stable under normal temperature and pressure controls.

Thermal decomposition products are hazardous. Benzene, Xylene, Carbon Dioxide and Carbon Monoxide. Hazardous Polymerization will not occur. SECTION 11. Toxicological information Routes of entry: Eye Contact, Skin Contact, Inhalation, Ingestion The Carbon Black is encapsulated in the polymer matrix that minimizes the potential for exposure by inhalation or skin contact. The IARC has rated carbon black as a 2B carcinogen, or possibly carcinogenic to humans. NTP, OSHA and ACGIH have not determined Carbon Black to be carcinogenic. The principal components used in this product have been reacted and are no longer present in their original form. The finished polymerized product is an inert rubber and exposure to the original constituents would not be expected under normal conditions. Burning this material or exposing it to temperatures >300 C can generate irritating and toxic fumes. Health effects from these fumes can range from transient to severe eye, skin and respiratory irritation, pulmonary edema, headache, nausea, drowsiness as well as a variety of other effects. Some decomposition products are toxic if absorbed through the skin in sufficient quantities. SECTION 12. Ecological information This product is stable at ambient temperature and pressure and is not readily biodegradable. It has low potential for bioaccumulation and is not toxic to fish. SECTION 13. Disposal considerations This product is a RCRA non-hazardous waste. Disposal should be in accordance with all regulations applicable to the disposal of nonhazardous waste. SECTION 14. Transport Information

No specific transport required. SECTION 15. Regulatory information This product is manufactured in compliance with all provisions of the Toxic Substance Control Act. SECTION 16. OTHER The information accumulated herein is believed to be accurate, but it is not warranted to be. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances.