1. PRODUCT AND COMPANY IDENTIFICATION Product name : Sapphire 700 Stain Part Number(s) : 928-40022 Brand : LI-COR Supplier : LI-COR, Inc. 4647 Superior Street P.O. Box 4425 Lincoln, NE 68504 USA Telephone : (402) 467-0700 Toll Free Number : (800) 447-3576 Fax : (402) 467-0841 Emergency Phone # Information : 24 Hour Phone (CHEMTREC) (800) 424-9300 (215) 781-9255 Preparation Information : LI-COR, Inc. (800) 447-3576 2. HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards Carcinogen, Target Organ Effect GHS Classification Carcinogenicity (Category 1B) GHS Label elements, including precautionary statements Pictogram Signal Word Hazard statement(s) H350 Precautionary statement(s) P201 P308 + P313 HMIS Classification Health hazard: 2 Chronic Health Hazard: * Flammability: 0 Physical hazards: 0 NFPA Rating Health hazard: 2 Fire: 0 Danger May cause cancer Obtain special instructions before use IF exposed or concerned: Get medical advice/ attention Page 1 of 7
Reactivity Hazard: 0 Potential Health Effects Inhalation Skin Eyes Ingestion May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. May be harmful if swallowed. Safety Data Sheet 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Molecular Weight : : Component Classification Concentration Stain EC-No. Index-No. Carc. 1B; H350 0.1-1 % For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIREFIGHTING MEASURES Conditions of flammability Not flammable or combustible. Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for firefighters Wear self-contained breathing apparatus for firefighting if necessary. Page 2 of 7
Hazardous combustion products Hazardous decomposition products formed under fire conditions. - Nature of decomposition products not known. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid inhalation of vapour or mist. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Eye protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Impervious clothing; the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Page 3 of 7
Hygiene measures General industrial hygiene practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Liquid Safety data ph Melting point/freezing point Boiling point Flash point Ignition temperature Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: n-octanol/water Relative vapour density Odour Odour Threshold Evaporation rate 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Conditions to avoid Materials to avoid Page 4 of 7
Hazardous decomposition products Other decomposition products - Hazardous decomposition products formed under fire conditions. - nature of decomposition products not known. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 Inhalation LC50 Dermal LD50 Other information on acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Eyes: Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: ACGIH: NTP: OSHA: Reproductive toxicity Teratogenicity 2B- Group 2B: Possibly carcinogenic to humans No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Aspiration hazard Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Page 5 of 7
Ingestion Skin Eyes May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Safety Data Sheet Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Additional Information RTECS: Not available 12. ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment Other adverse effects 13. DISPOSAL CONSIDERATIONS Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a Chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION DOT (US) Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods Page 6 of 7
15. REGULATORY INFORMATION OSHA Hazards Carcinogen, Target Organ Effect SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components The following components are subject to reporting levels established by SARA Title III, Section 313: Stain CAS No. SARA 311/312 Hazards Chronic Health Hazard Massachusetts Right To Know Components Stain Pennsylvania Right To Know Components Water Stain New Jersey Right To Know Components Water 7732-18-5 7732-18-5 Stain California Prop. 65 Components WARNING! This product contains a chemical known to the State of California to cause cancer. Stain 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Carc H350 Further information Carcinogenicity May cause cancer. Prepared By LI-COR, Inc. Safety and Compliance Department 4647 Superior Street, Lincoln, NE 68504 (402) 467-0700 Page 7 of 7