CYLINDER VALVE GUIDELINES TD 12/15/E

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CYLINDER VALVE GUIDELINES MIDDLE EAST GASES ASSOCIATION (MEGA) European Business Center, Office BC 25 Dubai Investments Park, PO Box: 166 Dubai-UAE Tel: +971-4-8135525 / Fax: +971-4-8135575 / E-mail: info@megases.org, www.megases.org

CYLINDER VALVE GUIDELINES Disclaimer All technical publications of MEGA, including codes of practice, safety procedures and any other technical information contained in such publications were obtained from sources believed to be reliable and are based on technical information and experience currently available to MEGA and others at the date of their issuance. Where MEGA recommends reference to use of its publications by its members, such reference to or use MEGA s publications by its members or third parties are purely voluntary and not binding. MEGA or its members make no guarantee of the results and assume no liability or responsibility in connection with the reference to or use of information or suggestions contained in MEGA s publications. MEGA has no control whatsoever on, performance or non-performance, misinterpretation, proper or improper use of any information or suggestions contained in MEGA s publications by any person or entity (including MEGA members), and MEGA expressly disclaims any liability in connection obtain the latest edition. MEGA 2015 MEGA grants permission to reproduce this publication provided that MEGA is acknowledged as the source. Page 2 of 8

TABLE OF CONTENTS 1. INTRODUCTION 4 2. SCOPE & PURPOSE 4 2.1. Scope 4 2.2. Purpose 4 3. TERMS & DEFINITIONS 4 3.1. Medical Gas 4 3.2. Industrial Gas 4 3.3. ISO 5 3.4. Specialty Gas 5 4. CYLINDER VALVE SELECTION PRINCIPLES 5 4.1. International Standards 5 4.2. Valve Standards commonly Used in the Middle East 5 4.2.1. Industrial Gases 5 4.2.2. Medical Gases 5 4.2.3. Specialty Gases 5 4.2.4. List of Standard Connections 6 4.2.5. Safety Guidelines 7 5. REFERENCES 8 Page 3 of 8

1. INTRODUCTION Across the Middle East, there are no clear standards or regulations for the selection of cylinder valves for different gases. There are several reasons for this. Historically, much of the equipment that gases are supplied for has been imported, so that customers have asked for cylinder valves in accordance with the equipment they are using, or the systems they are familiar with from their home countries. As well, some gases and gas mixtures were, and still are being, imported from overseas and are been supplied in accordance with the regulations of their country of origin. Lastly, there are transitory cylinders, such as cylinders on board of ships or used by the military, that come into and go out of the Middle East, but may require refilling while in the Middle East. There are potential hazards associated with filling a product into cylinders with an inappropriate valve connections, including loss of production, property damage and injury to personnel. 2. SCOPE & PURPOSE 2.1. Scope The scope of this document is to outline the minimum standards to be followed for Industrial and Medical gases in cylinders. 2.2. Purpose The purpose of this document is to provide guidance to all gas cylinder fillers and suppliers for the selection and use of cylinder valve outlets. 3. TERMS & DEFINITIONS For the purposes of this document, the following terms and definitions apply: 3.1. Medical Gas Any gas or mixture of gases intended to be administered to patients for therapeutic, diagnostic or prophylactic purposes, with or without pharmacological action, or to be used for surgical tools, and covers both medicinal and medical gases, and included in the European or US Pharmacopeia standards. 3.2. Industrial Gas Gas or gas mixtures used in wide range of industrial applications and general usage. Page 4 of 8

3.3. ISO International Standards Organization 3.4. Specialty Gas Specialty Gases include rare gases, chemical gases, gases of high purity and high precision mixture gases. 4. CYLINDER VALVE SELECTION PRINCIPLES 4.1. International Standards There are numerous valve standards published and in use around the world. The three major standards used in the Middle East are BS ( British Standard, United Kingdom ), CGA ( Compressed Gas Association, USA and Canada) and DIN ( Deutsche Industrie Norm, German Institute for Standardization). Other countries, including Argentina, Australia, Brazil, France, Italy and the Netherlands, to name some major ones, also have their own standards. 4.2. Valve standards commonly used in the Middle East 4.2.1. Industrial Gases The standard most commonly used for industrial gases in most countries of the Middle East is BS, except in Saudi Arabia, where, for historical reasons, the CGA standard is used. 4.2.2. Medical Gases The standard most commonly used standard for medical gases in the Middle East is BS, except in Saudi Arabia, where, for historical reasons, the CGA standard is used. The one exception are small medical cylinders, for which all countries utilize CGA pin-indexed connections and yoke style regulators. 4.2.3. Specialty Gases The standard most commonly used for specialty gases in the Middle East is BS, except in Saudi Arabia, where, for historical reasons, the CGA standard is used. The DIN standard is also used with some frequency. Page 5 of 8

4.2.4. List of standard connections Below, for reference, are the most common connection valve connection outlet standards for the three most commonly used standards. BS 341 (British Standard) Connector type Connector description Generic gas property Example gases or mixtures components BS 341 No. 3 G 5/8" INT Inert Argon, Nitrogen, Inert Mixes BS 341 No. 3 G 5/8" INT Oxidiser Oxygen, Air BS 341 No. 4 G 5/8" LH INT Flammable Acetylene, Hydrogen BS 341 No. 4 G 5/8" LH INT Flammable Carbon Monoxide, Methane, Natural Gas BS 341 No. 6 G 5/8" Toxic Chlorine, Hydrogen Chloride BS 341 No. 7 G 5/8" LH Flammable Refrigerants Flammable Refrigerants BS 341 No. 8 W 0.860" x 14 TPI Non Flammable Carbon Dioxide BS 341 No. 10 G 1/2" Toxic Ammonia BS 341 No. 12 G 1/2" Toxic Sulphur Dioxide BS 341 No. 13 W 11/16" - 20 TPI Oxidiser Nitrous Oxide BS 341 No. 14 G 3/8" Toxic Hydrogen Cyanide, Nitric Oxide BS 341 No. 15 G 3/8" LH Toxic Carbonyl Sulphide, Hydrogen Sulphide North American Standard Connector type Connector description Generic gas property Example gases or mixtures components CGA 240 3/8" - 18 NPT Toxic Ammonia CGA 296 0.803" - 14 UNS INT Oxidising Mixtures Oxygen Mix > 23% CGA 320 0.825" - 14 NGO Non Flammable Carbon Dioxide CGA 326 0.825" - 14 NGO Oxidiser Nitrous Oxide CGA 330 0.825" - 14 NGO LH Toxic Hydrogen Sulphide CGA 346 0.825" - 14 NGO Oxidiser Air, Breathing and Industrial Grades CGA 350 0.825" - 14 NGO LH Flammable Hydrogen, Methane CGA 510 0.825" - 14 NGO LH INT Flammable Propane CGA 540 0.903" - 14 NGO Oxidiser Oxygen CGA 580 0.965" - 14 NGO INT Inert Argon, Nitrogen, Inert Mixes CGA 590 0.965" - 14 NGO LM INT Oxidiser Air, Specialty Gas Grades CGA 660 1.030" - 14 NGO Toxic Nitric Oxide, Phosgene CGA 680 1.030" - 14 NGO LH High Pressure > 3000 psig Nitrogen, Argon, Inert Mixes CGA 705 1.125" - 14 UNS LH Toxic Ammonia Page 6 of 8

DIN 477 (Deutsche Industrie Norm) Connector type Connector description Generic gas property Example gases or mixtures components DIN 477 No. 1 W 21.8 x 1/14" LH Flammable Hydrogen, Propane DIN 477 No. 2 W 21.8" x 1/14" LH Flammable Propane DIN 477 No. 3 Yoke Flammable Acetylene DIN 477 No. 3.1 M 24 x 2" LH Flammable Acetylene DIN 477 No. 5 W 1" x 1/8" LH Toxic Carbon Monoxide DIN 477 No. 6 W 21.8 x 1/14" Various Argon, Helium, Carbon Dioxide DIN 477 No. 7 G 5/8" Toxic Sulphur Dioxide DIN 477 No. 8 W 1" x 1/8" Toxic Boron Trichloride DIN 477 No. 9 G 3/4" Oxidiser Oxygen DIN 477 No. 10 W 24.32 x 1/14" RH Inerts Nitrogen DIN 477 No. 11 G 3/8" Oxidiser Nitrous Oxide (>3 l size) DIN 477 No. 12 G 3/4" INT Oxidiser Nitrous Oxide (<3 l size) DIN 477 No. 13 G 5/8" INT Non Flammable Air DIN 477 No. 14 M 19 x 1.5 LH Various Mixtures COMMON PIN - INDEXED MEDICAL CYLINDER VALVE YOKE CONNECTIONS CGA Outlet 870 Oxygen 880 Carbon Dioxide & Oxygen Mixtures (CO 2 not over 7.5%) 890 Helium & Oxygen Mixtures (Helium not over 80.5%) 910 Nitrous Oxide 930 Helium/Helium & Oxygen Mixtures (Helium over 80.5%) 940 Carbon Dioxide/Carbon Dioxide & Oxygen Mixtures (CO 2 over 7.5%) 950 Medical Air - Up to 3000 PSI 960 Nitrogen - Up to 3000 PSI 965 Nitrous Oxide & Oxygen Mixture (N 2 O 47.5% to 52.5%) NOTE : the above lists show only the most common assigned connections. ALWAYS consult the original document for proper selection, or for gases and gas mixtures not included. 4.2.5. Safety Guidelines MEGA recommends the following safety guidelines to be followed 1. Encourage the use of the outlet standards that are normally and widely used in the country in which the customer will use the gas. For example, CGA standards for Saudi Arabia, BS standards in other countries. 2. If asked for a specific outlet on a specific gas or gas mixture, consult the original technical regulations to confirm that it is the appropriate one. Customers may ask for a connection outlet that is inappropriate for the gas or gas mixture that they will use. Page 7 of 8

Remember: it is the gas supplier s responsibility as expert to verify that only the correct valve is used. 3. Discourage the use of adaptors. Where this is unavoidable, check for material compatibility, pressure range and appropriate outlets. 4. Be sure to follow ALL recommendations applicable within a given standard. Example 1: if asked for a CGA valve that requires a Safety Device to be on it, be sure to use the proper valve/safety device combination. Pressure relief devices should be marked with their activation pressure. Example 2: for pin-indexed vales, use only yoke connections with the proper pins in place. Never use yokes from which the pins have been removed. Example 3A: if asked for a high pressure gas with CGA valves, be sure that the valve standard is authorized for the pressure in question. A good example would be that the CGA 580 outlet is authorized for pressures up to 3000 psig, whereas a CGA 680 valve is required for the same gas(es) between 3000 and 4500 psig, and yet another valve outlet, CGA 677, is required for pressures above 4500 psig. 5. Example 3B : if asked for a high pressure gas with BS valves, be sure that the valve is rated and stamped for the requested pressure. A good example would be that a BS3 valve installed on a cylinder rated for 300 bar service should also be rated for and marked for 300 bar. Do not use a valve stamped 200 bar, for example, on a 300 bar cylinder. 6. Lubricants of any kind, including PTFE tape, are not to be used on cylinder valve outlets. 7. Where a valve specifications requires a washer to be used, be sure that a washer, of the proper material for the intended gas service, is used. 5. REFERENCES 1. European Pharmacopeia 2. US Pharmacopeia 3. German Institute for Standardization (DIN) 4. CGA standards V-1 and V-7 5. BS standard for Cylinder Valve Outlets & Connectors Page 8 of 8