Print date: 21.03.2016 Page 1 of 8 1. Identification Product identifier Details of the supplier of the safety data sheet Manufacturer Company name: Street: Place: LEDERZENTRUM GmbH Raiffeisenstraße 1 D-37124 Rosdorf (Germany) Telephone: +49 (0)551-770730 Telefax:+49 (0)551-7707322 e-mail: info@lederzentrum.de Contact person: Karin Oberdiek Telephone: + 49 (0) 551 770730 e-mail: Internet: Responsible Department: Supplier Company name: Street: Place: ko@lederzentrum.de www.lederzentrum.de +49 (0)551-770 730 Westhill Trading Ltd. 80, Saxon Avenue GB-TW13 5JN Hanworth Telephone: (+44) 203 793 9125 e-mail: Contact person: e-mail: Internet: Responsible Department: Emergency phone number: info@colourlock.com Ram Iyer Telephone: (+44) 7739 579 694 info@colourlock.com https://www.colourlock.com Opening Mo - Fr. 09.00-17.00 CET 0049 (0) 551 770 730 Mo.-Fr. 08:00 am - 03:00 pm CET/MEZ 2. Hazard(s) identification Classification of the chemical Label elements Signal word: Pictograms: Classification refers to the concentrate. Application: Wool 30-40 C. 75 ml to 1 machine. Hazard categories: Serious eye damage/eye irritation: Eye Dam. 1 Hazard Statements: Causes serious eye damage Danger corrosion
Print date: 21.03.2016 Page 2 of 8 Hazard statements Causes serious eye damage Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Wear protective gloves/protective clothing/eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Additional advice on labelling Classification refers to the concentrate. Application: Wool 30-40 C. 75 ml to 1 machine. 3. Composition/information on ingredients Mixtures Hazardous components CAS No Components 69011-36-5 Isotridecanol, ethoxylated 106232-83-1 Alcohols, C12-15, branched and linear, ethoxylated 68439-46-3 Alcohols, C9-11, ethoxylated 2235-54-3 ammonium dodecyl sulphate Quantity 8.5 % 6 % 2.1175 % 1.331 % 4. First-aid measures Description of first aid measures After inhalation Provide fresh air. After contact with skin Wash with plenty of water. Take off contaminated clothing and wash it before reuse. After contact with eyes Call a physician immediately. In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. After ingestion Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. Call a physician immediately. Most important symptoms and effects, both acute and delayed No information available. Indication of any immediate medical attention and special treatment needed Treat symptomatically. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings.
Print date: 21.03.2016 Page 3 of 8 Unsuitable extinguishing media Full water jet Special protective equipment and precautions for fire-fighters In case of fire: Wear self-contained breathing apparatus. Additional information Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use personal protection equipment. Environmental precautions Do not allow to enter into surface water or drains. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 7. Handling and storage Precautions for safe handling Advice on safe handling If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe gas/fumes/vapour/spray. It is recommended to design all work processes always so that the following is excluded: Advice on protection against fire and explosion No special fire protection measures are necessary. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Keep locked up. Store in a place accessible by authorized persons only. Provide adequate ventilation as well as local exhaustion at critical locations. Advice on storage compatibility No special measures are necessary. 8. Exposure controls/personal protection Control parameters Exposure controls
Print date: 21.03.2016 Page 4 of 8 Appropriate engineering controls Avoid contact with skin, eyes and clothes. Protective and hygiene measures Handling larger quantities: Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink. Eye/face protection Handling larger quantities: Suitable eye protection: goggles. Hand protection Handling larger quantities: When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Measures related to consumer uses of the substance (as such or in preparations). rubber gloves. Skin protection Handling larger quantities: Wear suitable protective clothing. 9. Physical and chemical properties Information on basic physical and chemical properties Physical state: Color: Odor: liquid light beige characteristic ph-value (at 20 C): 5 Test method Changes in the physical state Melting point/freezing point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: Lower explosion limits: Upper explosion limits: Auto-ignition temperature Solid: Gas: Decomposition temperature: 100 C 212 F > 120 C 248 F
Print date: 21.03.2016 Page 5 of 8 Oxidizing properties Not oxidizing. Vapor pressure: Density (at 20 C): Water solubility: Solubility in other solvents Partition coefficient: Viscosity / kinematic: (at 20 C) Vapour density: Evaporation rate: Other information Solid content: 0,7 g/cm³ easily soluble 15 mm²/s 10. Stability and reactivity Reactivity No hazardous reaction when handled and stored according to provisions. Chemical stability Stability: Stable The product is stable under storage at normal ambient temperatures. Possibility of hazardous reactions Hazardous reactions: Conditions to avoid none No known hazardous reactions. Will not occur Hazardous decomposition products No known hazardous decomposition products. 11. Toxicological information Information on toxicological effects Acute toxicity
Print date: 21.03.2016 Page 6 of 8 CAS No Components Exposure route 69011-36-5 Isotridecanol, ethoxylated oral Method LD50 106232-83-1 Alcohols, C12-15, branched and linear, ethoxylated oral 68439-46-3 Alcohols, C9-11, ethoxylated oral Dose >5000 mg/kg LD50 500-2000 mg/kg ATE 500 mg/kg Species Rat Rat Source Irritation and corrosivity Causes serious eye damage Skin corrosion/irritation: Sensitizing effects Specific target organ toxicity (STOT) - single exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Carcinogenicity (IARC): Butylated hydroxytoluene (BHT) (CAS 128-37-0) is listed in group 3. Coumarin (CAS 91-64-5) is listed in group 3. Benzyl acetate (CAS 140-11-4) is listed in group 3. d-limonene (CAS 5989-27-5) is listed in group 3. Aspiration hazard Additional information on tests This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. 12. Ecological information Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Persistence and degradability Bioaccumulative potential The product has not been tested. The product has not been tested. Mobility in soil The product has not been tested. Other adverse effects No information available. Further information Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
Print date: 21.03.2016 Page 7 of 8 13. Disposal considerations Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to applicable legislation. Contaminated packaging Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself. 14. Transport information Marine transport (IMDG) Other applicable information No dangerous good in sense of these transport regulations. Air transport (ICAO) Other applicable information No dangerous good in sense of these transport regulations. Special precautions for user No information available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information U.S. Regulations National regulatory information State Regulations SARA Section 311/312 Hazards: Isotridecanol, ethoxylated (69011-36-5): Immediate (acute) health hazard Alcohols, C12-15, branched and linear, ethoxylated (106232-83-1): Immediate (acute) health hazard Alcohols, C9-11, ethoxylated (68439-46-3): Immediate (acute) health hazard ammonium dodecyl sulphate (2235-54-3): Immediate (acute) health hazard Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65, State of California) This product contains no chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Additional information Classification refers to the concentrate. Application: Wool 30-40 C. 75 ml to 1 machine. 16. Other information Hazardous Materials Information Label (HMIS) Health: 3 Flammability: 1 Physical Hazard: 1
Print date: 21.03.2016 Page 8 of 8 NFPA Hazard Ratings Personal Protection: Health: Flammability: Reactivity: Unique Hazard: Revision date: Revision No: B 3 1 1 15.03.2016 2.0 Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Other data The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. 3 1 1 (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)