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Transcription:

SAFETY DATA SHEET PROSOCO, Inc. Issue Date 04-Oct-2017 Revision Date 04-Oct-2017 Version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Enviro Klean DriKlean Other means of identification Product Code 41047 Recommended use of the chemical and restrictions on use Recommended Use Restricted to professional users. Uses advised against Details of the supplier of the safety data sheet Manufacturer Address PROSOCO, Inc. 3741 Greenway Circle Lawrence, Kansas 66046 Emergency telephone number 8:00AM 5:00PM CSTMonday-Friday 785-865-4200 NON-BUSINESS HOURS (INFOTRAC) 800-535-5053 Classification 2. HAZARDS IDENTIFICATION Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Warning Emergency Overview Hazard statements Causes skin irritation Causes serious eye irritation May cause respiratory irritation Appearance cream Physical state Liquid Odor Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Page 1 / 7

Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information 4.17639% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Weight-% Trade Secret Water 7732-18-5 40-70 * Polymer Proprietary 10-30 * Triethyleneglycol bis (2-ethylhexanoate) 94-28-0 5-10 * Proprietary Polymer Undisclosed 1-5 * Synthetic Amorphous Silica 112926-00-8 1-5 * First aid measures * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Eye contact Skin Contact Inhalation Ingestion Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Remove to fresh air. Clean mouth with water and drink afterwards plenty of water. Call a physician. Most important symptoms and effects, both acute and delayed Symptoms Irritating to eyes and skin. May cause respiratory irritation. Indication of any immediate medical attention and special treatment needed te to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Page 2 / 7

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Avoid contact with eyes and skin. Avoid breathing vapors or mists. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep containers tightly closed in a dry, cool and well-ventilated place. ne known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Synthetic Amorphous Silica 112926-00-8 (vacated) TWA: 6 mg/m 3 TWA: 20 mppcf : (80)/(% SiO2) mg/m 3 TWA NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Page 3 / 7

Engineering Controls ne under normal use conditions. Individual protection measures, such as personal protective equipment Eye/face protection Skin and body protection Respiratory protection General Hygiene Considerations Wear safety glasses with side shields (or goggles). Wear protective nitrile rubber gloves. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Liquid Appearance cream Odor Color Off-white Odor threshold Property Values Remarks Method ph 9 Melting point/freezing point 0 C / 32 F Boiling point/boiling range Flash point C / F t Applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limits Lower flammability limit Vapor pressure Vapor density Specific Gravity 0.99 Water solubility Soluble in water Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Reactivity data available 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials Page 4 / 7

ne known based on information supplied. Hazardous Decomposition Products ne known based on information supplied. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye contact Skin Contact Ingestion data available Avoid breathing vapors or mists. May cause irritation of respiratory tract. Avoid contact with eyes. Causes serious eye irritation. Avoid contact with skin. Irritating to skin. Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water > 90 ml/kg ( Rat ) 7732-18-5 Triethyleneglycol bis (2-ethylhexanoate) 94-28-0 = 31 g/kg ( Rat ) = 14100 µl/kg ( Rabbit ) Information on toxicological effects Symptoms Irritating to eyes and skin. May cause respiratory irritation. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Respiratory system. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 4.17639% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 333333 mg/kg ATEmix (dermal) 151158 mg/kg mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulation Page 5 / 7

Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT t Regulated for all modes of transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Page 6 / 7

US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Ammonium hydroxide X X X 1336-21-6 16. OTHER INFORMATION NFPA Health hazards 2 Flammability 0 Instability 0 Physical and Chemical Properties - HMIS Health hazards 2 Flammability 0 Physical hazards 0 Personal protection X Prepared By Regulatory Department Issue Date 04-Oct-2017 Revision Date 04-Oct-2017 Revision te SDS sections updated 3 8 11 Disclaimer The information contained on the Safety Data Sheet has been compiled from data considered accurate. This data is believed to be reliable, but it must be pointed out that values for certain properties are known to vary from source to source. PROSOCO, Inc. expressly disclaims any warranty express or implied as well as any liability for any injury or loss arising from the use of this information or the materials described. This data is not to be construed as absolutely complete since additional data may be desirable when particular conditions or circumstances exist. It is the responsibility of the user to determine the best precautions necessary for the safe handling and use of this product for his unique application. This data relates only to the specific material designated and is not to be used in combination with any other material. Many federal and state regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. It is the purchaser's responsibility to familiarize himself with all applicable regulations. End of Safety Data Sheet Page 7 / 7