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Transcription:

SAFETY DATA SHEET E-MAX SILVER Section 1. Chemical product and company identification Product name Recommended use and restrictions E-MAX SILVER Laundry product Use only for the purpose on the product label. Product dilution information Not applicable Supplier's information Code Date of issue Section 2. Hazards identification GHS Classification GHS label elements Ecolab Inc.Textile Care Division 37 N. Wabasha Street St. Paul, MN 5512 1-8-553-8683 913991 16 Dec 213 EMERGENCY HEALTH INFORMATION 1-8-328-26 Outside United States and Canada CALL 1-651-222-5352 (in USA) SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Signal word Symbol Danger Hazard statements Causes serious eye damage. Causes skin irritation. Precautionary statements Prevention Response Storage Disposal Other hazards Wear protective gloves. Wear eye or face protection. Wash hands thoroughly after handling. IF ON SKIN Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs Get medical attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. No other specific measures identified. See section 13 for waste disposal information. None known. Page 1/7

Section 3. Composition/information on ingredients Substance/mixture Mixture Hazardous ingredients Concentration Range (%) CAS number BUTOXYDIGLYCOL 1 112-34-5 alcohols, c12-16, ethoxylated 2-5 68551-12-2 Hazardous ingredients Concentration Range (%) CAS number Section 4. First aid measures Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Skin contact Take off contaminated clothing. Wash with plenty of soap and water. Get medical attention if irritation persists. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation No special measures required. Treat symptomatically. Ingestion Get medical attention if symptoms occur. Protection of firstaiders Notes to physician been ingested or inhaled. See toxicological information (section 11) Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective equipment for fire-fighters No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have Section 5. Fire-fighting measures Specific fire-fighting methods Use water spray, fog or foam. In a fire or if heated, a pressure increase will occur and the container may burst. Decomposition products may include the following materials carbon dioxide carbon monoxide Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page 2/7

Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Handling Storage Initiate company's spill response procedures immediately. Keep people out of area. Put on appropriate personal protective equipment (see section 8). Do not touch or walk through spilled material. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Section 7. Handling and storage Personal protection Eye protection Hand protection Skin protection Respiratory protection Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Use only with adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. Keep container tightly closed. Store between the following temperatures and 5 C Section 8. Exposure controls/personal protection Control parameters Ingredient name Appropriate engineering controls Hygiene measures Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Exposure limits BUTOXYDIGLYCOL ACGIH TLV (United States, 3/212). TWA 1 ppm 8 hours. Form Inhalable fraction and vapor Use chemical splash goggles. For continued or severe exposure wear a face shield over the goggles. Use chemical-resistant, impervious gloves. No protective equipment is needed under normal use conditions. A respirator is not needed under normal and intended conditions of product use. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Page 3/7

Section 9. Physical and chemical properties Physical state Color Odor ph Flash point Explosion limits Flammability (solid, gas) Melting point Boiling point Evaporation rate (butyl acetate = 1) Vapor pressure Vapor density Relative density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Liquid. Colorless to light yellow Pungent 7.5 to 9 (1%) > 1 C Product does not support combustion. >1 C (>212 F).985 to 1.15 (Water = 1) Easily soluble in the following materials cold water and hot water. Decomposition temperature Odor threshold Viscosity Dynamic (room temperature) 25 mpa s (25 cp) Kinematic (room temperature) 2.5456 cm 2 /s (25.456 cst) Section 1. Stability and reactivity Stability Possibility of hazardous reactions Conditions to avoid No specific data. Materials to avoid Hazardous decomposition products Section 11. Toxicological information Route of exposure The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Skin contact, Eye contact, Inhalation, Ingestion Page 4/7

Section 11. Toxicological information Symptoms Eye contact Adverse symptoms may include the following pain watering redness Skin contact Adverse symptoms may include the following irritation redness Inhalation No specific data. Ingestion No specific data. Acute toxicity Eye contact Causes serious eye damage. Skin contact Causes skin irritation. Inhalation Ingestion Toxicity data Product/ingredient name alcohols, c12-16, ethoxylated LD5 Dermal Rabbit >2 mg/kg LD5 Oral Rat 11 mg/kg 2-(2-butoxyethoxy)ethanol LD5 Dermal Rabbit 2764 mg/kg LD5 Oral Rat 336 mg/kg Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Section 12. Ecological information Ecotoxicity This material is toxic to aquatic life. Aquatic and terrestrial toxicity Product/ingredient name Result Species Exposure alcohols, c12-16, ethoxylated Acute LC5 1.5 mg/l Fish 96 hours 2-(2-butoxyethoxy)ethanol Acute LC5 13 mg/l Fish 96 hours Other adverse effects Section 13. Disposal considerations Disposal methods Avoid disposal. Attempt to use product completely in accordance with intended use. Disposal should be in accordance with applicable regional, national and local laws and regulations. Page 5/7

Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification DOT Proper shipping name Class Packing group IMO/IMDG IMO/IMDG Classification IMO/IMDG Proper shipping name Class Packing group Not intended for transport. UN382 Environmentally hazardous substance, liquid, n.o.s. (Alkyl alcohol ethoxylates) 9 III UN382 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkyl alcohol ethoxylates). Marine pollutant 9 III For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 32/34/311/312 extremely hazardous substances No listed substance SARA 32/34 emergency planning and notification No listed substance SARA 313 Product name CAS number Concentration Form R - Reporting requirements California Prop. 65 2-(2-butoxyethoxy)ethanol 112-34-5 9.9 No listed substance Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards 3 National Fire Protection Association (U.S.A.) Page 6/7

Section 16. Other information Flammability Health 3 Instability/Reactivity Special Date of issue Prepared by 16 Dec 213 Regulatory Affairs 1-8-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 7/7