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Transcription:

SAFETY DATA SHEET PROSOCO, Inc. Issue Date 21-Oct-2014 Revision Date 21-Oct-2014 Version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Consolideck LSGuard Other means of identification Product Code 46073 Recommended use of the chemical and restrictions on use Recommended Use Restricted to professional users. Uses advised against Details of the supplier of the safety data sheet Manufacturer Address PROSOCO, Inc. 3741 Greenway Circle Lawrence, Kansas 66046 Emergency telephone number 8:00AM 5:00PM CSTMonday-Friday 785-865-4200 NON-BUSINESS HOURS (INFOTRAC) 800-535-5053 Classification 2. HAZARDS IDENTIFICATION Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Label elements Warning Emergency Overview Hazard statements Causes skin irritation Causes serious eye irritation Appearance opaque Physical state Liquid Odor none Page 1 / 8

Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Hazards not otherwise classified (HNOC) Other Information 3.375% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS First aid measures Chemical Name CAS No Weight-% Trade Secret Water 7732-18-5 40-70 * Proprietary Acrylic Polymer Undisclosed 10-30 * Silicic Acid, lithium salt 12627-14-4 5-10 * Alkoxysilane Proprietary 1-5 * Potassium methylsiliconate 31795-24-1 1-5 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES General advice Eye contact Skin Contact Inhalation Ingestion Self-protection of the first aider If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Immediate medical attention is required. Immediate medical attention is required. Keep eye wide open while rinsing. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If symptoms persist, call a physician. Wash off immediately with plenty of water while removing contaminated clothing and shoes. Consult a physician if necessary. Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Call a physician or poison control center immediately. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. Immediate medical attention is required. Never give anything by mouth to an unconscious person. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms Causes eye irritation. Causes skin irritation. Page 2 / 8

Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical The product causes irritation of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. Environmental precautions Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal. Dam up. Cover liquid spill with sand, earth or other non-combustible absorbent material. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. In case of insufficient ventilation, wear suitable respiratory equipment. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep out of the reach of children. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Strong acids. Incompatible with oxidizing agents. Incompatible with strong acids and bases. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 3 / 8

Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Skin and body protection Respiratory protection General Hygiene Considerations Wear safety glasses with side shields (or goggles). Wear protective gloves and protective clothing. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Keep away from food, drink and animal feeding stuffs. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Liquid Appearance opaque Odor none Color white Odor threshold Property Values Remarks Method ph 11 Melting point/freezing point 0 C / 32 F Boiling point/boiling range Flash point Not Applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limits Lower flammability limit Vapor pressure Vapor density Specific Gravity 1.11 Water solubility Soluble in water Solubility in other solvents Partition coefficient Autoignition temperature Page 4 / 8

Decomposition temperature Kinematic viscosity Dynamic viscosity 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Exposure to air or moisture over prolonged periods. Incompatible materials Strong acids. Incompatible with oxidizing agents. Incompatible with strong acids and bases. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye contact Skin Contact Ingestion Avoid contact with skin, eyes and inhalation of vapors Avoid breathing vapors or mists. Harmful by inhalation. Causes eye irritation. Irritating to skin. Do not taste or swallow. Harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water > 90 ml/kg ( Rat ) - - 7732-18-5 Alkoxysilane = 7460 µl/kg ( Rat ) - - Information on toxicological effects Symptoms Causes eye and skin irritation. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure...... Page 5 / 8

Chronic toxicity Aspiration hazard Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. Possible risk of irreversible effects.. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 3.375% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 11844 mg/kg ATEmix (dermal) 8597 mg/kg mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability. Bioaccumulation. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies Page 6 / 8

DSL/NDSL Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes Yes No No No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations 16. OTHER INFORMATION NFPA Health hazards 2 Flammability 0 Instability 0 HMIS Health hazards 2 Flammability 0 Physical hazards 0 Physical and Chemical Properties - Personal protection X Prepared By Regulatory Department Issue Date 21-Oct-2014 Revision Date 21-Oct-2014 Revision Note Disclaimer The information contained on the Material Safety Data Sheet has been compiled from data considered accurate. This data is believed to be reliable, but it must be pointed out that values for certain properties are known to vary from source to source. PROSOCO, Inc. expressly disclaims any warranty express or implied as well as any liability for any injury or loss arising from the use of this information or the materials described. This data is not to be construed as absolutely complete since additional data may be desirable when particular conditions or circumstances exist. It is the responsibility of the user to determine the best precautions necessary for the safe handling and use of this product for his unique application. This data relates only to the specific material designated and is not to be used in combination with any other material. Many federal and state regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. It is the purchaser's responsibility to familiarize himself with all applicable regulations. Page 7 / 8

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