Sikaflex -552 AT Patiki Road Avondale Auckland AKL 1026 : H319 Causes serious eye irritation. H351 Suspected of causing cancer.

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Transcription:

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product code : 100000000750 Type of product : liquid Recommended use of the chemical and restrictions on use Product use : Sealant/adhesive Manufacturer or supplier's details Company : Sika (NZ) Ltd. 85-91 Patiki Road Avondale Auckland AKL 1026 Telephone : +64 9 820 2900 Emergency telephone number : 0800 734 607 Telefax : +64 9 828 4091 E-mail address : info@nz.sika.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification 3.1 Flammable Liquids : Category D 6.4 Eye irritation : Category A 6.7 Carcinogenicity : Category B GHS label elements Hazard pictograms : Signal word Hazard statements Precautionary statements : Warning : H227 Combustible liquid. H319 Causes serious eye irritation. H351 Suspected of causing cancer. : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. 1 / 7

No smoking. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (%) Hydrocarbons, C13-C23, n-alkanes, isoalkanes, 64742-46-7 >= 1 - < 10 cyclics, < 0.03% aromatics Polypropylene glycol 25322-69-4 >= 1 - < 10 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed : No hazards which require special first aid measures. : Move to fresh air. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. : Flush eyes with water as a precaution. Remove contact lenses. Keep eye wide open while rinsing. : Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. : No known significant effects or hazards. See Section 11 for more detailed information on health effects and symptoms. 2 / 7

Causes serious eye irritation. Suspected of causing cancer. Notes to physician : Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Hazardous combustion products Specific extinguishing methods Special protective equipment for firefighters : Carbon dioxide (CO2) : Water : No hazardous combustion products are known : Standard procedure for chemical fires. : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Methods and materials for containment and cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : For personal protection see section 8. Follow standard hygiene measures when handling chemical products Hygiene measures Conditions for safe storage : Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. : Store in original container. Keep in a well-ventilated place. Observe label precautions. Store in accordance with local regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Personal protective equipment 3 / 7

Respiratory protection Hand protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Eye protection Skin and body protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary. : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold ph Melting point/range / Freezing point Boiling point/boiling range Flash point Evaporation rate Flammability : paste : various : characteristic : 73.5 C (164.3 F) Method: closed cup Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : 0.01 hpa (0.01 mmhg) Density : ca. 1.49 g/cm3 (20 C (68 F) ()) 4 / 7

Solubility(ies) Water solubility Partition coefficient: n- octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity, dynamic Viscosity, kinematic Explosive properties Molecular weight : insoluble : Not applicable : Not applicable SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials : No dangerous reaction known under conditions of normal use. : The product is chemically stable. : Stable under recommended storage conditions. Hazardous decomposition products : No decomposition if stored and applied as directed. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitisation Skin sensitisation: Respiratory sensitisation: 5 / 7

Chronic toxicity Germ cell mutagenicity Carcinogenicity Suspected of causing cancer. Reproductive toxicity STOT - single exposure STOT - repeated exposure Aspiration toxicity SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Product: Additional ecological information : There is no data available for this product. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulations 6 / 7

IATA-DGR Not dangerous goods IMDG-Code Not dangerous goods Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations NZS 5433 Not dangerous goods SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture International Chemical Weapons Convention (CWC) Schedules of Toxic Chemicals and Precursors : Not applicable HSNO Approval Number HSR002680 HSNO Controls Certified handler certificate not required. HSNO tracking not required. Refer to EPA user guide to the HSNO control regulations for further information. The components of this product are reported in the following inventories: NZIoC : On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processing. 7 / 7