Revision date: 10/30/2013 Supersedes:07/08/2013 Version: 1.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Product code : Mixtures : STOPA R134a Leak Stop Aerosol : STOPA 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number : Stops small leaks in R-134a air conditioning system rubber hoses, o-rings and seals. Emergency number : USA:1-800-373-7542, INT L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL Contract No. DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable Full text of H-phrases: see section 16 3.2. Mixtures : Contains gas under pressure; may burst if heated. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 30/10/2013 EN (English US) 1/5
5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials Storage temperature 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Do not store above 120 F. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : < 49 C Do not store in passenger compartment of automobiles. 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : The use of gloves impervious to the specific material handled is advised to prevent skin contact. Suggested protective material: Nitrile, 4.5 mil thickness, tested at 3.5 ml and above with no breakthrough time after 240 minutes. : Chemical goggles or safety glasses. : Normally not required. Where there is potential for airborne exposure above the exposure limit an approved air purifying respirator equipped with Type R or P95 particle filters may be used. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Color : Green-Yellow Tint. Odor : Characteristic. Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point 30/10/2013 EN (English US) 2/5
Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : (Not expected to cause cancer. This oil meets the IP-346 criteria of less than 3 percent PAH's and is not considered a carcinogen by the International Agency for Research on Cancer.). SECTION 12: Ecological information 12.1. Toxicity 30/10/2013 EN (English US) 3/5
12.2. Persistence and degradability STOPA R134a Leak Stop Aerosol Persistence and degradability 12.3. Bioaccumulative potential STOPA R134a Leak Stop Aerosol Bioaccumulative potential 12.4. Mobility in soil 12.5. Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA 14.1. UN number UN-No.(DOT) : 1950 14.2. UN proper shipping name DOT Proper Shipping Name Department of Transportation (DOT) Hazard Classes Hazard labels (DOT) : Aerosols LTD QTY : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 : Limited Quantity 14.3. Additional information : No supplementary information available. Overland transport Transport by sea Air transport SECTION 15: Regulatory information 15.1. US Federal regulations 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 30/10/2013 EN (English US) 4/5
15.2.2. National regulations 15.3. US State regulations STOPA R134a Leak Stop Aerosol() U.S. - California - Proposition 65 - Developmental Toxicity State or local regulations Yes This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. SECTION 16: NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data. 30/10/2013 EN (English US) 5/5