1. PRODUCT AND COMPANY IDENTIFICATION Product name : Odyssey 28 KD Loading Indicator-700 nm Part Number(s) : 926-20004; 926-20014, Odyssey 28 KD Loading Indicator-700 nm Sample pack (not for sale) Brand : LI-COR Identified uses : Laboratory chemicals, Manufacture of substances Supplier : LI-COR, Inc. 4647 Superior Street Lincoln, NE 68504 USA www.licor.com sds@licor.com Telephone Toll Free Number : : (402) 467-0700 (800) 447-3576 Emergency Phone # : 24 Hour Phone (CHEMTREC) +1 703-741-5970 / (800) 424-9300 2. HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards Target Organ Effect, Harmful by ingestion, Toxic by skin absorption, Irritant Target Organs Kidney, Lungs, GHS Classification Skin irritation (Category 3) Eye irritation (Category 2B) GHS Label elements, including precautionary statements Pictogram Signal word Hazard statement(s) H316 H320 Precautionary statement(s) P305 + P351 + P338 HMIS Classification Health hazard: 2 Chronic Health Hazard: * Flammability: 1 Physical hazards: 0 NFPA Rating None Warning Causes mild skin irritation. Causes eye irritation. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Page 1 of 8
Health hazard: 2 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation Skin Eyes Ingestion May be harmful if inhaled. Causes respiratory tract irritation. Toxic if absorbed through skin. Causes skin irritation. Causes eye irritation. Harmful if swallowed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Classification Concentration Glycerol EC-No. 56-81-5 200-289-5 < 55% Sodium dodecyl sulphate EC-No. 151-21-3 205-788-1 Tris hydrochloride (TRIS HCl) 1185-53-1 EC-No. 214-684-5 Flam. Sol. 1; Acute Tox. 4; Acute Tox. 3; Skin Irrit. 2; Eye Dam. 1; STOT SE 3; H228, H302, H311, H315, H318, H335 < 5 % < 2 % For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIREFIGHTING MEASURES Conditions of flammability Not flammable or combustible. Page 2 of 8
Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for firefighters Wear self contained breathing apparatus for firefighting if necessary. Hazardous combustion products Hazardous decomposition products formed under fire conditions. - Oxides of phosphorus, Sodium oxides 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components Value Control Basis parameters Glycerol 56-81-5 TWA 10 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 TWA 5 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 TWA 10 mg/m3 USA. ACGIH Threshold Limit Values (TLV) Remarks Upper Respiratory Tract irritation TWA 15 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 5 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants See Appendix D - Substances with No Established RELs Page 3 of 8
Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Eye protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Color Safety data Liquid Orange ph 6.8 Melting point/freezing point Boiling point Flash point Ignition temperature Autoignition temperature Lower explosion limit Upper explosion limit Vapor pressure Density Water solubility soluble Partition coefficient: n-octanol/water Relative vapor density Odor Odor Threshold Evaporation rate Page 4 of 8
10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Conditions to avoid Materials to avoid Strong bases, Strong oxidizing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Sulphur oxides, Sodium oxides Other decomposition products - 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 Inhalation LC50 Dermal LD50 Other information on acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Eyes: Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: ACGIH: NTP: OSHA: Reproductive toxicity No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Page 5 of 8
Teratogenicity Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Causes respiratory tract irritation. Toxic if swallowed. Toxic if absorbed through skin. Causes skin irritation. Causes eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Additional Information RTECS: Not available 12. ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment Other adverse effects 13. DISPOSAL CONSIDERATIONS Product Dispose of material in accordance with local environmental and health regulations. Contaminated packaging Dispose of as unused product. Page 6 of 8
14. TRANSPORT INFORMATION DOT (US) Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods 15. REGULATORY INFORMATION OSHA Hazards Target Organ Effect, Toxic by ingestion, Toxic by skin absorption, Irritant, Carcinogen SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Reportable Quantity : lowest RQ > 999999 lbs lowest RQ > 999999 lbs Massachusetts Right To Know Components Glycerol 56-81-5 Revision Date 2007-03-01 Pennsylvania Right To Know Components Revision Date Glycerol 56-81-5 2007-03-01 Sodium dodecyl sulphate 2-Amino-2(hydroxymethyl)propane-1,3-diol hydrochloride 151-21-3 1185-53-1 Disodium 7-hydroxy-8-phenylazonapthalene-1,3-disulphonate 1936-15-8 New Jersey Right To Know Components Revision Date Glycerol 56-81-5 2007-03-01 Sodium dodecyl sulphate 151-21-3 2-Amino-2(hydroxymethyl)propane-1,3-diol hydrochloride 1185-53-1 Disodium 7-hydroxy-8-phenylazonapthalene-1,3-disulphonate 1936-15-8 California Prop. 65 Components This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Page 7 of 8
Acute Tox. Eye Dam. Flam. Sol. H228 H302 H311 H315 H318 H335 Skin Irrit. STOT SE Acute toxicity Serious eye damage Flammable solids Flammable solid. Harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Skin irritation Specific target organ toxicity - single exposure Further information See current Revision Date and Version in the header at the top of each page. This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1010.1200. Prepared By LI-COR, Inc. Safety and Compliance Department 4647 Superior Street, Lincoln, NE 68504 (402) 467-0700 Page 8 of 8