Product identifier: Adhesion Products AP-102 Product Use Sealant Section 1 - PRODUCT AND COMPANY IDENTIFICATION Company Information Titan 22290 Challenger Drive Elkhart, IN 46514 EMERGENCY TELEPHONE NUMBER 1-800-255-3924 Section 2 - HAZARDS IDENTIFICATION Classification in accordance with 29 CFR 1910.1200. Toxic to reproduction Hazardous to the Aquatic Environment - Acute Hazard, Hazardous to the Aquatic Environment - Chronic Hazard, GHS LABEL ELEMENTS Symbol(s) Signal Word Hazard Statement(s) Precautionary Statement(s) Prevention Use only outdoors or in a well ventilated area. Response IF exposed or concerned: Not a hazardous substance or mixture. Page 1 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
Storage Store at ambient Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS CAS Component Percent 64742-46-7 Distillates (petroleum), hydrotreated middle 20-30 7631-86-9 Amorphous silica 5-10 Section 4 - FIRST AID MEASURES Description of Necessary Measures Inhalation IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. Call a doctor/physician if you feel unwell. Skin Contact IF ON SKIN: Wash with plenty of soap and luke warm water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion If a large amount is swallowed, get immediate medical attention. Most Important Symptoms/Effects Acute Skin irritation and eye irritation. Page 2 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
Delayed Skin or Eye Irritation Indication of Immediate Medical Attention and Special Treatment Needed, If Needed Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES Suitable Extinguishing Media Use carbon dioxide, regular dry chemical, regular foam or water. Unsuitable Extinguishing Media Special Hazards Arising from the Chemical Fire Fighting Measures Move material from fire area if it can be done without risk. Cool containers with water. Avoid inhalation of vapors or combustion by-products. Use extinguishing agents appropriate for surrounding fire. Dike for later disposal. Stay upwind and keep out of low areas. Protective Equipment and Precautions for Firefighters Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. Firefighters should avoid inhaling any combustion products. Section 6 - Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Wear personal protective clothing and equipment, see Section 8. Keep unnecessary people away, isolate hazard area and deny entry. Only personnel trained for the hazards of this material should perform clean up and disposal. Page 3 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
Methods and Materials for Containment and Cleaning Up Observe all personal protection equipment recommendations in Sections 5 & 8. Wipe or scrape up and contain for salvage or disposal. Clean area as appropriated since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 & 15 of this SDS provide information regarding certain federal and state requirements. Section 7 - HANDLING AND STORAGE Precautions for Safe Handling Use adequate ventilation. Product evolves acetic acid when exposed to water or humid air. Provide ventilation during use to control acetic acid within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact Conditions for Safe Storage, including any Incompatibilities Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. This material is its finely divided dorm presents an explosion hazard. Follow NFPA 654 (for chemical dusts) or 484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational Exposure Limits Distillates (petroleum), hydrotreated middle OSHA: 5 mg/m3 ACGIH: 5 mg/m3 STEL: 10 mg/m3 Amorphous Silica OSHA: ACGIH: STEL: 6 mg/m3 10 mg/m3 Not Established Page 4 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
Component Exposure Limits Component: Ethyltriacetoxysilane CAS Number: 17689-77-9 Exposure Limits: See acetic acid comments Component: Methyltriacetoxysilane CAS Number: 4253-34-3 Exposure Limits: See acetic acid comments Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and AGIHTLV: TWA 10 ppm, STEL 15 ppm. Appropriate Engineering Controls Local Ventilation: None should be needed General Ventilation: Recommended Individual Protection Measures, such as Personal Protective Equipment Eyes/Face Protection Wear splash resistant safety goggles. Skin Protection Wear appropriate chemical resistant clothing. Glove Recommendations Wear appropriate chemical resistant gloves. Protective Materials Nitrile Respiratory Protection Use an approved respirator if exposure limits are exceeded or if irritation develops or persists. Comments When heated to temperatures above 150C (300F) in the presence of air, product can form formaldehyde vapors. Physical and health hazard information is readily available on the Material Safety Data Sheet. When heated to temperatures above 150C in the presence of air, product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory sensitizer, and an irritant to the eyes, nose throat, skin and digestive system. Safe handling conditions may be maintained by keeping vapor concentrations within the OSHA Permissible Exposure Limit for formaldehyde. Page 5 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
NOTE These precautions are for room temperature handling. Use oat elevated temperatures or aerosol/spray may require additional precautions. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Paste Appearance: paste Color: various Physical Form: paste Odor: Acetic acid Odor Threshold: Not available ph: Not available Melting Point: Not available Boiling Point: Not available Decomposition: Not available Flash Point: Not applicable Evaporation Rate: Not available OSHA Flammability Not available Vapor Pressure: Not available Class: Vapor Density (air = 1): Not available Density: Not available Specific Gravity (water = 1.007 Water Solubility: Not available 1): Log KOW: Not available Coeff. Water/Oil Dist: Not available KOC: Not available Auto Ignition: Not available Viscosity: Not available VOC: 24 g/l <3% wt Volatility: Not available Molecular Formula: Not available Section 10 - STABILITY AND REACTIVITY Reactivity No reactivity hazard is expected. Chemical Stability Stable at normal temperatures and pressure. Possibility of Hazardous Reactions Will not polymerize. Conditions to Avoid Oxidizing material can cause a reaction. Water, moisture or humid air can cause hazardous vapors to form as described in section 8. Incompatible Materials Strong acids, strong oxidizing materials Page 6 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat condition may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds formaldehyde silicon dioxide Hazardous Decomposition Combustion: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special Hazard Information on Components No none information Section 11 - TOXICOLOGICAL INFORMATION Section 12 - ECOLOGICAL INFORMATION Environmental Fate and Distribution Complete information is not yet available Fate & Effects in Waste Water Treatment Plants Complete information is not yet available Environmental Effects Complete information is not yet available Section 13 - DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a discussion is made to discard this material, as received, is it classified as a hazardous waste NO. State and local laws may impose additional regulatory requirements regarding disposal. Waste Disposal Method We make no guarantee or warranty of any kind that the use or disposal of this product complies with all local, state, or federal laws. It is also the obligation of each user of the product mentioned herein to determine and comply with the requirements of all applicable statutes. Page 7 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
This product is not known to be regulated under RCRA regulations. Disposal of unused portions of this product and process waste containing this product should be done only after a careful evaluation and in compliance with all federal, local and state laws. Section 14 - TRANSPORT INFORMATION UN Number: UN Proper Shipping Name: DOT Classification: Packaging Group: Road Shipment: Ocean Shipment (IMDG) Air Shipment (IATA) Not subject to DOT regulations Not subject to IMDG code Not subject to IATA regulations Section 15 - REGULATORY INFORMATION TSCA Status The contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910. 1200 SARA Title III Section 302 Extremely Hazardous Substances: SARA Title III Section 304 CERCLA Substances dangerous: SARA Title III Section 311/312 Hazard Class Acute: No Chronic: No Fire: No Pressure: No Reactive: No SARA Title III Section 313 Toxic Chemicals None present or none present in regulated quantities Note Chemicals are listed under the 313 toxic chemicals section only if they meet or exceed a reporting threshold. Page 8 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18
CA Prop 65 This product contains the following chemicals listed by the state of California under the safe drinking water and toxic enforcement act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm: NONE NJ Dimethyl siloxane, hydroxy-terminated (70131-67-8) Ethyltriacetoxysilane (17689-77-9) Methyltriacetoxysilane (4253-34-3) Silica, amorphous (7631-86-9) Hydrotreated middle petroleum distillates (64742-46-7) PA Dimethyl siloxane, hydroxy-terminated (70131-67-8) Silica, amorphous (7631-86-9) Hydrotreated middle petroleum distillates (64742-46-7) Summary of Changes New SDS: 1.00 2/2/2016 Section 16 - OTHER INFORMATION Disclaimer The data contained herein is based upon information that Adhesion Products believes to be reliable. Users of this product have the responsibility to determine that suitability of use and to adopt all necessary precautions to ensure the safety and protection of property and persons involved in said use. All statements or suggestions are made without warranty, expressed or implied, regarding the accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. End of Sheet AP-102 Page 9 of 9 Issue Date: 2/22/16 Revision 1.000 Print Date 5/03/18