Page: 1 1. Identification GHS Product Identifier Product Code Company Name Address Telephone/Fax Number Emergency phone number Recommended use the chemical and restrictions on use Other PALMOLIVE NATURALS - SOAP BAR - SHEA BUTTER B0241416000 Colgate-Palmolive Pty Ltd (ABN 002 792 163) Australia: Level 14, 34 George Street, Sydney NSW 2000 Australia Tel: AUS (02) 9229 600 NZ: 04 76 6700 Fax: AUS (02) 9229 700, NZ: 04 68 883 AUS 1800 638 6, NZ: 0800 764766 Hand and body wash, soap bar. New Zealand Address: Level 4, 4 Knights Road, Lower Hutt. 2. Hazard Identification GHS classification the substance/mixture Not classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia. Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) 3. Composition/information on ingredients Ingredients 4. First-aid measures Inhalation Ingestion Skin Eye contact First Aid Facilities Advice to Doctor Other. Fire-fighting measures Suitable extinguishing media Hazards from Combustion Products Name CAS Proportion Sodium soap 6892-9-4 60-<100 % Glycerin 6-81- <10 % Talc 14807-96-6 <10 % Benzenepropanal, 4-80-4-6 <1 % (1,1-dimethylethyl)-.al pha.-methyl- Sodium chloride 7647-14- <1 % Cyclopentaneacetic 2481-98-7 <1 % acid, 3-oxo-2-pentyl-, methyl ester Ingredients determined not to be hazardous, including water. Balance None required. Do not induce vomiting. Wash out mouth thoroughly with water. If symptoms develop seek medical attention. None required. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed f completely. If irritation develops or continues seek medical attention. Normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Centre (Phone Australia 13 1126) or a doctor at once. Use appropriate fire extinguisher for surrounding environment. Non-combustible, however if involved in a fire it may decompose and release toxic fumes. Print Date: 20/08/2013
Page: 2 Specific hazards arising from the chemical Decomposition Temp. Precautions in connection with Fire Non combustible material. 6. Accidental release measures Emergency Procedures 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities 8. Exposure controls/personal protection Occupational exposure limit values Biological Limit Values Appropriate engineering controls Respiratory Protection Eye Protection Hand Protection Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-exposed containers. Sweep up or collect the material and transfer into suitable labelled containers for subsequent recycling or disposal. Dispose waste according to applicable local and national regulations. The product is bar soap. No special handling precautions. May be slippery when wet. Store in a cool, dry place. Keep away from water during storage. No exposure value assigned for this material by Safe Work, Australia. However, the available exposure limits for ingredients are listed below: Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Glycerin - 10 - - - Talc - 2 (Respirable dust) - TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 1 minute period which should not be exceeded at any time during a normal eight-hour workday. No biological limits allocated. No special engineering controls required. Not normally required. 9. Physical and chemical properties Appearance Odour Decomposition Temperature Melting Point Boiling Point When dealing with large quantities wearing safety glasses with side shields is recommended. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications. Not typically required. When handling large quantities, wear gloves impervious material. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance. Tan coloured bar soap. Print Date: 20/08/2013
Page: 3 Solubility in Water Solubility in Organic Solvents Specific Gravity ph Vapour Pressure Vapour Density (Air=1) Evaporation Rate Odour Threshold Viscosity Partition Coefficient: n-octanol/water Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper Soluble 10. Stability and reactivity Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization 11. Toxicological Toxicology Ingestion Inhalation Skin Eye Respiratory sensitisation Skin Sensitisation Germ cell mutagenicity Carcinogenicity Reproductive Toxicity Non-flammable Reacts with incompatibles. Stable under normal conditions handling and storage. Extremes temperature and direct sunlight. Keep dry in storage. Strong oxidising agents. Thermal decomposition may result in the release toxic and/or irritating fumes. Will not occur. No toxicity data are available for this material. May cause irritation to the mouth, oesophagus and stomach. Symptoms can include nausea, vomiting, diarrhoea and possible gastric irritation. Not considered a likely source exposure. The product is designed for skin contact. However, it may cause irritation in individuals with very sensitive skin. May be irritating to eyes. The symptoms may include redness, itching and tearing. Not expected to be a respiratory sensitiser. Not expected to be a skin sensitiser. Not considered to be a mutagenic hazard. Not considered to be a carcinogenic hazard. Not considered to be toxic to reproduction. Print Date: 20/08/2013
Page: 4 STOT-single exposure STOT-repeated exposure Aspiration Hazard Not expected to cause toxicity to a specific target organ. Not expected to cause toxicity to a specific target organ through prolonged or repeated exposure. Not expected to be an aspiration hazard. 12. Ecological information Ecotoxicity Persistence and degradability Mobility Bioaccumulative Potential Environmental Protection 13. Disposal considerations Disposal Considerations 14. Transport information Transport IMDG Marine pollutant 1. Regulatory information Regulatory Poisons Schedule AICS (Australia) 16. Other Date preparation or last revision SDS Literature References Contact Person/Point No ecological data are available for this material. Prevent this material entering waterways, drains and sewers. The disposal the spilled or waste material must be done in accordance with applicable local and national regulations. Road and Rail Transport: Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. No Not classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled All components this product are listed on the Australian Inventory Chemical Substances (AICS) or exempted. SDS Reviewed: August 2013 Supersedes: September 2010 Preparation Safety Data Sheets for Hazardous Chemicals Code Practice. Standard for the Uniform Scheduling Medicines and Poisons. Australian Code for the Transport Dangerous Goods by Road & Rail. Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals. Workplace exposure standards for airborne contaminants, Safe work Australia. American Conference Industrial Hygienists (ACGIH). Globally Harmonised System classification and labelling chemicals. 24Hr Emergency Response Australia- 1800 638 6 New Zealand- 0800 764 766...End Of MSDS... Print Date: 20/08/2013
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